CAS: 102-13-6; Phenylacetic Acid Isobutyl Ester

上下游产品

CAS号103-82-2 苯乙酸 | CAS号78-83-1 异丁醇 | CAS号201230-82-2 carbon monoxide | CAS号108-88-3 甲苯 | CAS号101-41-7 苯乙酸甲酯 | CAS号140-29-4 苯乙腈 | CAS号100-39-0 溴化苄 | CAS号122-43-0 苯乙酸丁酯 | CAS号122-45-2 °Ctyl phenyl acetate | CAS号103-82-2 苯乙酸 | CAS号78-83-1 异丁醇 | CAS号124-38-9 二氧化碳 | CAS号7332-98-1 tert-butyl 2-ox... | CAS号100-52-7 苯甲醛 | CAS号67-64-1 丙酮

2-苯乙酸辛酯置于溴苯,Palladium 10% On Activated Carbon体系中,用 乙醇 用作溶剂,55.0~60.0 °C,600.01 Kpa 条件下,反应 8.0H,反应生成苯乙酸-2-甲基丙酯
参考文献:Palladium On Carbon-bromobenzene Mediated Esterification And Transesterification
标题:Palladium On Carbon-bromobenzene Mediated Esterification And Transesterification
摘要:A Series Of Carboxylic Acids Were Converted Into Their Corresponding Esters Using The Pd/c Catalyzed Hydrogenation Conditions In The Presence Of Catalytic Bromobenzene In Alcohols And The Method Could Also Be Applicable For The Transesterification Of Esters. Good To Excellent Yields Were Obtained For Different Aliphatic Or Aromatic Starting Materials. The Success Of This Esterification Relies On The In Situ Generation Of Hydrobromic Acid (Hbr) From Bromobenzene Which Provides A Mild And Acidic Reaction Environment. The Palladium Catalyst Exhibits A Remarkable Activity And Is Reusable For Up-To Three Consecutive Cycles. (C) 2013 Elsevier Ltd. All Rights Reserved.
Doi:10.1016/j.Tetlet.2013.08.009

专利信息

专利号:DE-102012224021-A1
优先权日:2012-05-09
标 题 :A process for the synthesis of phenylacetic acid by carbonylation of toluene

专利号:CN-103145553-A
优先权日:2013-03-06
标 题 :Synthesis and application of 2, 3-alkyl substituted diester succinate

专利号:CN-103145553-B
优先权日:2013-03-06
标 题:Synthesis and application of 2, 3-alkyl substituted diester succinate