CAS: 2550-40-5; Dicyclohexyl Disulfide

上下游产品

Cyclohexanethiol 1-methyl-4-nitrosobenzene 3-cyclohexanesulfinyl-propionic acid cyclohexanoneN,N'-bis-benzenesulfonyl-cyclohexanesulfinamidineN,N'-bis-benzenesulfonyl-cyclohexanesulfinamidine Cyclohexanethiol S-cyclohexyl cyclohexane-1-sulfonothioate S-cyclohexyl cyclohexane-1-sulfinothioate

环己醇置于4,4'-偶氮吡啶,三苯基膦,硫氰酸铵体系中,用 乙腈 用作溶剂,化学反应 6.33H,以81%的收率获得二环己基二硫化物
参考文献:杂芳族偶氮化合物可作为有效和可回收的试剂,用于将脂肪醇直接转化为对称的二硫化物
标题:杂芳族偶氮化合物可作为有效和可回收的试剂,用于将脂肪醇直接转化为对称的二硫化物
摘要:4,4'-偶氮吡啶1A和5,5'-二甲基-3,3'-偶氮异恶唑1E用于在mitsunobu条件下与pph结合高效,直接和选择性地将脂肪族醇高产率地转化为其相应的二硫键3和nh 4 Scn.与1A的反应是均匀发生的,而1E的反应则是异质的.在两个反应中,分离出产生的n-氰基肼并容易地将其再氧化为相应的偶氮化合物.
Doi:10.1016/j.Tetlet.2012.10.013

专利信息

专利号:US-6432294-B1
优先权日:2000-12-14
标题 :Electrochemical activation of organic disulfides for electrophilic substitution
发明人：GLASS RICHARD S; JOUIKOV VIATCHESLAV V; BOJKOVA NINA V
权利人:UNIV ARIZONA
摘要:Electrochemical oxidation of organic disulfides is conducted in an electrolytic solution containing an arene (e.g., anthracene, acenaphthylene, phenanthrene), and depending on the arene used and/or the product desired, an organic base (e.g., pyridine) to effect the synthesis of organothiated products in good yields.

专利号:US-6020529-A
优先权日:1998-01-22
标题:Synthesis of organic disulphides and polysulphides
发明人：FREMY GEORGES
权利人:ATOCHEM ELF SA
摘要:A process for the manufacture of organic disulphides and polysulphides using a basic resin catalyst wherein the catalyst is a polystyrene-divinylbenzene resin functionalized with ethylenediamine or a polyethylenepolyamine groups.

专利号:US-12150934-B2
优先权日:2016-11-30
标 题 :Methods of using substituted pyrazole and pyrazole compounds and for treatment of hyperproliferative diseases
发明人：SIDDIQUI ARSHAD M; CIBLAT STEPHANE; CONSTANTINEAU-FORGET LEA; GRAND-MAITRE CHANTAL; GUO XIANGYU; SRIVASTAVA SANJAY; SHIPPS GERALD W; COOPER ALAN B; OZA VIBHA; KOSTURA MATTHEW W; LUTHER MICHAEL; LEVINE JEDD
权利人:BANTAM PHARMACEUTICAL LLC
摘要:Disclosed are methods of treating hyperproliferative disorders such as cancer, methods of arresting the cell cycle in cancer cells, methods of inhibiting glutathione synthesis in cancer cells, and associated compounds for use and uses in medicaments. In certain embodiments, the methods, uses and compounds are provided with reference to compounds of the structural formula (I), in which X1, X2, Z1, Z2, the ring system denoted by “aâ€?, R1, L1, L2, Q, L3, R3, L4, R4, L5, and R5 are as described herein. In certain embodiments, compounds disclosed herein are especially active against cancers having a mutant KRAS gene.

专利号:US-6207838-B1
优先权日:1999-04-30
标 题 :Electrochemically generated organothiating reagents and their use
发明人：GLASS RICHARD S; JOUIKOV VIATCHESLAV V
权利人:UNIV ARIZONA
摘要:Electrolysis of organic disulfides in liquid sulfur dioxide is used to obtain organothiating agents, which can then be reacted with appropriate substrates to effect the synthesis of organothioaromatic compounds efficiently and in high yields. With appropriate phenolic compounds, regioselective substitution occurs in which para substitution greatly exceeds ortho substitution.

专利号:RU-94006681-A
优先权日:1994-02-23
标题:Method of synthesis of n-(cyclohexylthio)-phthalimide

专利号:JP-4426008-B2
优先权日:1998-01-22
标 题:Synthesis of organic disulfides and polysulfides.