CAS: 106-98-9; But-1-Ene

该化合物是分子式C4H8的烷,在室温中是一种无色气体,有略微甜味的气味.作为丁烯异构体家族的成员,一丁苯在线性链中第一和第二碳原子之间具有双重联系,使其成为一种不饱和的碳氢化合物.这种双重联系是反应性的,允许一丁参与各种化学反应,包括聚合,氢化和添加反应.主要用于生产聚乙烯和其他化学品.1-丁在有机溶剂中溶解,但在水中溶解性较低.它易燃,如果吸入或浸入,则构成危险,需要妥善处理和储存.化合物还被用于合成各种工业化学品,并用作某些塑料的生产中的共聚物.

结构式图片

物理性质

欧盟法规

统一分类与标签压力设备指令-第1组危险流体REACH注册ECHA物质欧盟气雾剂指令-标签制度ECHA物质工作场所安全标识要求C&L通报REACH预注册废弃物危险特性清单

上下游产品

CAS号135-98-8 仲丁基苯 | CAS号6565-55-5 1,3,5-Tris(1-me... | CAS号1014-41-1 1,4-Di-sec-buty... | CAS号1079-96-5 1,3-Di-sec-buty... | CAS号1013-03-2 1,2-di-s-butylb... | CAS号61064-05-9 1,2,4-tri(butan... | CAS号79504-01-1 2-bromo-1-chlor... | CAS号108200-18-6 1-溴-2-氯丁烷 | CAS号616-21-7 1,2-二氯丁烷 | CAS号533-98-2 1,2-二溴丁烷

合成工艺路线路线简述

  • 合成目标产物 1-Butene 主要起始原料 Ethylene
  • (文献来源)合成步骤主要原料 1,2-Epoxybutane
乙酸仲丁酯置于氮体系中,化学反应生成丁烯
参考文献:Houtman; Van Steenis; Heertjes,Recueil Des Travaux Chimiques Des Pays-Bas,1946,Vol. 65,P. 786
标题:Houtman; Van Steenis; Heertjes,Recueil Des Travaux Chimiques Des Pays-Bas,1946,Vol. 65,P. 786

海关参考信息

专利信息


专利号:US-7247752-B2
优先权日:2004-10-01
标 题 :Methods for the synthesis of astaxanthin
发明人:LOCKWOOD SAMUEL F; TANG PENG CHO; NADOLSKI GEOFF; JACKSON HENRY L; FANG ZHIQIANG; DU YISHU; YANG MIN; GEISS WILLIAM; WILLIAMS RICHARD; BURDICK DAVID
权利人:CARDAX PHARMACEUTICALS INC
摘要:A method used for synthesizing intermediates for use in the synthesis of carotenoids and carotenoid analogs, and/or carotenoid derivatives. In some embodiments, the invention includes methods for synthesizing optically active intermediates useful for the synthesis of optically active carotenoids. Synthesis of optically active carotenoids, in one embodiment, may be accomplished by forming an optically active dihydroxy intermediate from ketoisopherone. The optically active dihydroxy intermediate may be converted into optically active astaxanthin derivatives.

专利号:US-9353057-B2
优先权日:2003-12-30
标 题:Synthesis of acyloxyalkyl carbamate prodrugs and intermediates thereof
发明人:GALLOP MARK A; DAI XUEDONG; SCHEUERMAN RANDALL A; RAILLARD STEPHEN P; MANTHATI SURESH K; YAO FENMEI; PHAN THU; LUDWIKOW MARIA; PENG GE; BHAT SEEMA
权利人:XENOPORT INC
摘要:Methods for synthesis of 1-(acyloxy)-alkyl carbamates, particularly, the synthesis of 1-(acyloxy)-alkyl carbamate prodrugs of primary or secondary amine-containing drugs are described. Also described are methods for synthesis of 1-(acyloxy)-alkyl N-hydroxysuccinimidyl carbonates which are useful intermediates in the synthesis of 1-(acyloxy)-alkyl carbamates are also described.

专利号:US-2024051918-A1
优先权日:2022-08-10
标 题 :Sequential and independent synthesis of mercaptans and asymmetrical sulfides in a single reactor
发明人:LASSEN KENNETH M; NWAGWU UGOCHUKWU; HASENBERG DANIEL M
权利人:CHEVRON PHILLIPS CHEMICAL CO LP
摘要:The present disclosure generally relates to processes to produce a mercaptan and an asymmetrical sulfide utilize stacked bed catalyst systems containing CoMo and NiMo, and these processes demonstrate a synergistic reduction in the amount of ethylene, methyl mercaptan, ethyl mercaptan, and H2S in product mixtures. In aspects, the conversion of limiting reactants in the synthesis of asymmetrical sulfides unexpectedly remain high under increased flow rates through the catalyst bed, and under reduced temperatures and pressures. In further aspects, reactor systems configured for the independent synthesis of mercaptans and asymmetrical sulfides in a single fixed bed catalyst vessel are also disclosed as a simplification of existing reactor systems employing separate reactors for separate mercaptan and sulfide syntheses.

专利号:US-2004152905-A1
优先权日:2003-01-31
标题:Universal building blocks and support media for synthesis of oligonucleotides and their analogs
发明人:GUZAEV ANDREI P; MANOHARAN MUTHIAH
摘要:Compounds for the synthesis of oligomeric compounds, particularly oligonucleotides and chemically modified oligonucleotide analogs, are provided. In addition, methods for functionalization of a support medium with a first monomeric subunit and methods for the synthesis of oligomeric compounds utilizing the novel compounds bound to support media are provided.

专利号:US-2004242897-A1
优先权日:2002-07-31
标题 :Universal support media for synthesis of oligomeric compounds
发明人:GUZAEV ANDREI P; MANOHARAN MUTHIAH
摘要:Compounds for the synthesis of oligomeric compounds, particularly oligonucleotides and oligonucleotide mimetics, are provided. In addition, methods for functionalizing a support medium with a first monomeric subunit and methods for the synthesis of oligomeric compounds utilizing the novel compounds bound to support media are provided.

专利号:US-2004018598-A1
优先权日:2000-05-30
标题 :Bio-intermediates for use in the chemical synthesis of polyketides
发明人:SANTI DANIEL; ASHLEY GARY; MYLES DAVID C
摘要:The present invention relates to compounds made by a subset of modules from one or more polyketide synthase (“PKSâ€?) genes that are used as starting material in the chemical synthesis of novel molecules, particularly naturally occurring polyketides or derivatives thereof. The biologically derived intermediates (“bio-intermediatesâ€?) generally represent particularly difficult compounds to synthesize using traditional chemical approaches due to one or more stereocenters. In one aspect of the invention, an intermediate in the synthesis of epothilone is provided that feeds into the synthetic protocol of Danishefsky and co-workers. In another aspect of the invention, intermediates in the synthesis of discodermolide are provided that feed into the synthetic protocol of Smith and co-workers. By taking advantage of the inherent stereochemical specificity of biological processes, the syntheses of key intermediates and thus the overall syntheses of compounds like epothilone and discodermolide are greaty simplified.
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合成参考文献


摘要:Chiu, P.; Lam, S. K., Science of Synthesis, (2010) 47, 743.
摘要:Kostikov, R. R.; Khlebnikov, A. F.; Sokolov, V. V., Science of Synthesis, (2010) 47, 816.
摘要:Kostikov, R. R.; Khlebnikov, A. F.; Sokolov, V. V., Science of Synthesis, (2010) 47, 795.
摘要:Michalak, M.; Gulajski, L.; Grela, K., Science of Synthesis, (2010) 47, 392.
摘要:Kostikov, R. R.; Khlebnikov, A. F.; Sokolov, V. V., Science of Synthesis, (2010) 47, 788.
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