专利号:US-9901901-B2 优先权日:2012-05-21 标 题 :Selective extraction of anions from solution 发明人:MEZEI GELLERT 权利人:WESTERN MICHIGAN UNIV RESEARCH FOUNDATION; THE BOARD OF TRUSTEES OF WESTERN MICHIGAN UNIV 摘要:A method of selectively extracting anions from an aqueous solution using an anion encapsulating aggregate formed upon the addition of a solvent, a copper contributor, a hydroxide contributor, a counterion contributor, and pyrazole to an aqueous solution containing the anions, or upon the addition of a solvent, a polymeric chain of [Cu II (μ-OH)(μ-pz)] ∞ and a counterion contributor to the aqueous solution. The aggregates include compounds of the formula cis Cu II x (OR 1 ) y (R 2 pz) z , where R 1 is H or an alkyl group, R 2 is H, or an alkyl group or a charged group, pz is pyrazolate and each of x, y, and z is an integer between about 1 and about 40. In addition, ligand-containing anion encapsulating aggregates can be formed by synthesis with a lig-and-bound pyrazole or by substituting the ligand-bound pyrazole for the pyrazole incorporated in the aggregate.
专利号:US-10087197-B2 优先权日:2012-05-21 标 题:Selective extraction of anions from solution 发明人:MEZEI GELLERT 权利人:WESTERN MICHIGAN UNIV RESEARCH FOUNDATION 摘要:A method of selectively extracting anions from an aqueous solution using an anion encapsulating aggregate formed upon the addition of a solvent, a copper contributor, a hydroxide contributor, an optional counterion contributor, and at least one encapsulating anion to an aqueous solution containing the anions, or upon the addition of a solvent, a polymeric chain of [CuII(μ-OH)(μ-ea)]∞ and optionally, a counterion contributor to the aqueous solution. The aggregates include compounds of the formula cis-CuIIx(OR1)y(R2ea)z, where R1 is H or an alkyl group, R2 is H, or an alkyl group or a charged group, ea is an encapsulating anion, and each of x, y, and z is equal to an integer between about 1 and 40, inclusive. In addition, anion encapsulating aggregates can be formed by synthesis with alternate encapsulating anions by substituting alternate encapsulating anions for the encapsulating anion incorporated in the aggregate.
专利号:CN-114149372-B 优先权日:2021-11-30 标题:A kind of nitropyrazole energetic compound and its synthesis method
专利号:CN-114149372-A 优先权日:2021-11-30 标 题 :A kind of nitropyrazole energetic compound and its synthesis method
专利号:RU-2118318-C1 优先权日:1993-02-05 标题:Derivatives of 2-[4-(4-azolylbutyl)-1-piperazinyl]-pyrimidine or their physiologically acceptable salts, method of their synthesis and pharmaceutical composition based on thereof
专利号:CN-111233769-A 优先权日:2020-01-22 标题 :Industrial synthesis method of 4-chloropyrazole
摘要:Galczynski, J.; Huang, H.; Lambert, T. H., Science of Synthesis: Special Topics, (2021) 1, 329. 摘要:Archives Internationales de Pharmacodynamie et de Therapie., 121(443), 1959 [] 摘要:J. Elguero, E. Gonzalez and R. Jacquier. Bull. Soc. Chim. France 1968, 5009.