CAS: 1309-56-4; Molybdenum(Iv) Sulfide

该化合物是一种自然产生的矿物,是素的重要来源,在六边层结构中结晶,由于范德华的气力在硫化层之间较弱,其润滑性极佳,在高温和高压环境中作为固体润滑剂具有价值.Molybdenite 也表现出一种适合电子应用的带状物的半导体行为,包括晶体管和光检测器.其高热稳定性和化学惰性进一步提高了其在工业涂层和催化中的效用.此外,molybdenite是聚苯金属和化合物的一种前体,广泛用于合金和化学工艺.

结构式图片

欧盟法规

ECHA物质C&L通报REACH预注册

合成工艺路线路线简述

    Sodium Molybdate Dihydrate,硫脲 以 水 用作溶剂,化学反应 18.5H,反应生成二硫化钼
    参考文献:Nickel Oxide Decorated Mos2Nanosheet-Based Non-Enzymatic Sensor For The Selective Detection Of Glucose
    标题:Nickel Oxide Decorated Mos2Nanosheet-Based Non-Enzymatic Sensor For The Selective Detection Of Glucose
    摘要:这项研究报告称,基于nio/mos2的纳米复合材料可以作为电催化材料在血清中高选择性地检测葡萄糖.
    Doi:10.1039/c9Ra09318D

    专利信息


    专利号:US-2023174386-A1
    优先权日:2020-05-07
    标 题 :Scalable synthesis of semi-conducting chevrel phase compounds via selfpropagating high temperature synthesis
    发明人:GOUMA PELAGIA-IREN; PAWAR MILIND MANSING
    权利人:OHIO STATE INNOVATION FOUNDATION
    摘要:Methods for the scalable and systematic synthesis of semiconducting Chevrel phase compounds via self-propagating high temperature synthesis (SHS) are provided. The provided methods utilize elemental precursors not utilized by typical synthesis methods. The precursors may include molybdenum (Mo), molybdenum disulfide (MoS 2 ), and a ternary cation. In various aspects, the ternary cation may be copper (Cu), iron (Fe), or nickel (Ni). The utilization of the provided precursors and SHS decreases the time it takes to synthesize Chevrel phase compounds as compared to typical heat treatment methods.

    专利号:US-2024263349-A1
    优先权日:2023-02-02
    标 题 :Phase-controllable synthesis of transition metal dichalcogenide monolayer crystals
    发明人:ZHANG HUA; ZHAI WEI; WANG YONGJI
    权利人:UNIV CITY HONG KONG
    摘要:The present invention provides a general salt-assisted chemical vapour deposition method for phase-controllable synthesis of 1T′ and 2H-phase transition metal dichalcogenide (TMD) monolayer crystals. The method comprises: mixing a transition metal compound powder and a salt powder to form a precursor; placing a substrate on top of the precursor; placing the precursor and the substrate at a center position in a chemical vapour deposition (CVD) furnace; placing a chalcogen powder at an upstream position relative to the precursor along a gas-flow direction in the CVD furnace; heating up the CVD furnace to a growth temperature within the heat-up time; keeping the CVD furnace at the growth temperature for a growth time under a mixed gas flow of H2 and Ar. The optical and electrical characterizations reveal the phase-dependent in-plane isotropy and anisotropy of the as-synthesized 2H and 1T′-phase crystals. The 1T′-TMD monolayer crystals demonstrate much-improved phase transition temperatures.

    专利号:US-2023279562-A1
    优先权日:2021-12-30
    标题 :Process for the Electrochemical Synthesis of Ammonia (NH3) and the Ammonia Produced Thereby
    发明人:GHORAI UTTAM KUMAR; PAUL SOURAV; ADALDER ASHADUL; SARKAR SOUGATA
    权利人:GHORAI UTTAM KUMAR; RAMAKRISHNA MISSION VIDYAMANDIRA
    摘要:This invention relates to a process for the electrochemical synthesis of ammonia (NH3) and the ammonia produced thereby. Ammonia is synthesized by the electrochemical reduction of nitrogenous materials such as nitrogen or nitrates (NO3-) using metal phthalocyanine such as iron phthalocyanine (FePc) or β-cobalt phthalocyanine (CoPc) or iron phthalocyanine-molybdenum disulfide (FePc-MoS2) or cobalt phthalocyanine- carbon nitride (CoPc-C3N4) catalyst at very low pressure and room temperature by applying low potential.

    专利号:US-4769497-A
    优先权日:1986-07-04
    标题:Process for the synthesis of 2,2-dialkoxy-propanes
    发明人:MESSINA GIUSEPPE; MORETTI MARIO D; SANNA GAVINO; SANNA SALVATORE R; SOMA GIOVANNI
    权利人:ENICHEM ANIC SPA
    摘要:A new method of synthesis of a 2,2-dialkoxy-propane e.g. 2,2-dimethoxy-propane, is described through reaction of a cyclic ketal, e.g. 2,2-dimethyl-(1,3)-dioxolane, with a boric acid alkyl ester, e.g. boric acid trimethyl ester, in the presence of an acidic catalyst. The reaction may be carried out either in liquid or in vapour phase. In the latter case, heating of the thus obtained intermediate mixture to the reflux temperature should follow the catalytic step.

    专利号:US-8815963-B1
    优先权日:2013-11-04
    标 题:Catalyst composition formulated for synthesis of alcohols and method of preparing the same
    发明人:CARAM HUGO S; SAHOO RANJAN K; HERMAN RICHARD G; ACHARYA DIVYANSHU R
    权利人:AUXILIUM GREEN LLC; UNIV LEHIGH
    摘要:A catalyst composition includes an active material having a molybdenum- and sulfur-containing substance impregnated with an effective amount of cesium sufficient to promote synthesis of an alcohol, optionally carried on an inert support, wherein the active material is at least substantially free of a transition metal. The present invention is further directed to methods of preparing and using the same.

    专利号:US-11607677-B2
    优先权日:2017-10-30
    标 题:Homogeneous and reusable superacid polymer catalyst useful for the synthesis of 5-hydroxymethylfurfural from glucose
    发明人:ALBA RUBIO ANA C; COLEMAN MARIA R; KALIDINDI SUBHASH; JOSHI ANUP S; OMODOLOR IBEH S
    权利人:UNIV TOLEDO; TJIE UNIV OF TOLEDO
    摘要:A superacid polymeric catalyst having both Lewis acidity and Brønsted acidity is described, along with methods of making and methods of using the same.
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    合成参考文献


    摘要:Aitken, R. A.; Aitken, K. M., Science of Synthesis, (2010) 47, 1028.
    摘要:USEPA/Office of Water; Federal-State Toxicology and Risk Analysis Committee (FSTRAC). Summary of State and Federal Drinking Water Standards and Guidelines (11/93) To Present
    摘要:Mackison, F. W., R. S. Stricoff, and L. J. Partridge, Jr. (eds.). NIOSH/OSHA - Occupational Health Guidelines for Chemical Hazards. DHHS(NIOSH) Publication No. 81-123 (3 VOLS). Washington, DC: U.S. Government Printing Office, Jan. 1981., p. 1
    摘要:Franson MA (Ed); Standard Methods for the Examination of Water and Wastewater p.154 (1985)
    摘要:American Conference of Governmental Industrial Hygienists TLVs and BEIs. Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices. Cincinnati, OH, 2008, p. 42
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