CAS: 18746-63-9; Ammonium Hexachlororuthenate(Iv)

该化合物是一种无机化合物,配有配方(NH4)2[RuCl6],其特点是其协调复合结构,其特点是处于+4氧化状态,周围环绕着六氯化离子,环绕在八面形几何中,存在两个离子,有助于其在水中溶解,使其成为各种化学应用中的有用试剂.该化合物通常作为深色固体接触,在标准条件下因其稳定性而闻名.它经常用于催化,特别是在有机合成和电化学过程中,因为具有独特的特性.此外,二六氯环可用作其他基化合物的前体.在处理该物质时,应注意安全防范,因为如果浸入或吸入,可能会对健康造成危害,而且应使用适当的保护设备.

结构式图片

欧盟法规

ECHA物质ECHA物质C&L通报REACH预注册

合成工艺路线路线简述

    专利信息


    专利号:US-4497910-A
    优先权日:1981-07-28
    标题 :Process for methane synthesis by catalytic reduction of carbon monoxide in aqueous phase
    发明人:QUANG DANG V; SUGIER ANDRE; COMMEREUC DOMINIQUE; CHAUVIN YVES
    权利人:INST FRANCAIS DU PETROLE
    摘要:Process for the catalytic synthesis of methane by reaction of carbon oxides with hydrogen in the presence of liquid water, wherein the catalyst is formed of a carrier consisting either of coal or charcoal, preferably of plant origin, or of alumina-silica, on which is deposited ruthenium, for example by impregnation with ruthenium acetylacetonate, said catalyst being preferably used as particles suspended in water.

    专利号:US-5162495-A
    优先权日:1989-11-13
    标 题:Synthesis of quinoline and substituted quinoline copolymers
    发明人:CHIANG LONG Y; SWIRCZEWSKI JOHN W
    权利人:EXXON RESEARCH ENGINEERING CO
    摘要:The present invention is predicated on the discovery that quinoline and substituted quinoline derivatives, having substituents in positions other than the 2 and 6 position, undergo polymerization in the presence of tetrahydroquinoline or substituted tetrahydroquinolines and a transition metal sulfide catalyst to produce polymers that have repeating quinoline and substituted moieties. Thus, in one embodiment of the present invention, there is provided a novel method of preparing polymers having the formula (7) which comprises contacting a tetrahydroquinoline having the formula (8) with a quinoline compound having the formula (9) at elevated temperatures and in the presence of a transition metal sulfide catalyst wherein the metal is selected from Groups VIB, VIIB of the periodic table and mixtures thereof and wherein the Rs (i.e. R3, R4, etc.) and the R's (i.e. R'3, R'4, etc.) may be the same or different and are selected from hydrogen, halogen (especially fluoro-, chloro- and bromo-), -NO2, OH, -NH2, -SH, -CN and organic substituents. In the above polymer, x and y represent the relative proportion of bracketed structural quinoline or substituted moieties, and n is an integer equal to or greater than 2.

    专利号:US-12226754-B2
    优先权日:2020-12-30
    标题:Method to produce high densities of isolated atoms on support substrates
    发明人:SHAKOURI ABOLFAZL; ADABI FIROUZJAIE HORIE; REGALBUTO JOHN R; WILLIAMS CHRISTOPHER T; MUSTAIN WILLIAM E
    权利人:UNIV SOUTH CAROLINA
    摘要:Described herein is a general scalable synthesis method for a high density of single metal atoms in a supported catalyst, supported isolated atoms featuring unique reactivity and the support materials determine the stability, electronic properties, and local environment which can be adjusted for targeted heterogeneous catalysis applications.

    专利号:CN-110467587-B
    优先权日:2019-08-30
    标题 :A method for the synthesis of N-methyl morpholine oxide based on ruthenium/nitrogen-doped porous carbon catalyzed by O2 oxidation

    专利号:EP-0428351-A2
    优先权日:1989-11-13
    标 题:Synthesis of quinoline and substituted quinoline copolymers

    专利号:EP-0428351-B1
    优先权日:1989-11-13
    标 题:Synthesis of quinoline and substituted quinoline copolymers
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