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CAS号80-62-6 甲基丙烯酸甲酯 | CAS号108-93-0 环己醇 | CAS号78-85-3 2-甲基丙烯醛 | CAS号79-41-4 甲基丙烯酸 | CAS号92-84-2 吩噻嗪 | CAS号594-61-6 2-羟基异丁酸 | CAS号34900-11-3 cyclohexyl 2-hy...合成工艺路线路线简述
- 合成目标产物 Cyclohexyl Methacrylate 主要起始原料 Methyl Methacrylate And Cyclohexanol
- (文献来源)合成步骤主要原料 Methyl Methacrylate 和 Cyclohexanol
吩噻嗪,甲基丙烯酸甲酯置于lithium Hydroxide体系中,用 环己醇 用作溶剂,化学反应生成2-甲基丙烯酸环己酯
参考文献:Process For Producing Methacrylic Acid Esters
标题:Process For Producing Methacrylic Acid Esters
摘要:通过在存在催化剂和聚合抑制剂的情况下,将甲基丙烯酸甲酯和醇进行酯交换反应来生产甲基丙烯酸酯的过程中,可以通过使催化剂,醇和甲基丙烯酸中的总水含量为1000 Ppm或更低来缩短催化剂等的过滤时间,或者通过在醇转化率达到40%或更高时向反应系统中添加起始醇来防止在反应过程中产生大气泡,或者即使使用二元或三元醇作为起始物,也可以获得高催化活性,方法是使用通过加热干燥得到的氢氧化锂一水合物的催化剂,这些效果也可以通过组合各个条件来获得.
专利信息
专利号:WO-2023102600-A1
优先权日:2021-12-06
标题:Synthesis of amphiphilic block copolymers and polymeric nanofibers produced therefrom
发明人:ZETTERLUND PER B; ISHIZUKA FUMI; KIM HYUN JIN; CHATANI SHUNSUKE; NIINO HIROSHI
权利人:NEWSOUTH INNOVATIONS PTY LTD
摘要:The present disclosure relates to the field of synthesis of block copolymers, and polymeric nanofibers having a core-shell morphology produced therefrom. The present disclosure relates to the field of synthesis of block copolymers where one block is more hydrophobic than the other block and is a different composition. The disclosure also relates to uses of these polymeric nanofibers in various applications, such as reinforcing a polymeric matrix and for coatings applications.
专利号:US-2012184653-A1
优先权日:2011-01-18
标 题:Synthesis of linear phosphorus-containing functional fluorocopolymer
发明人:WANG LIANG; WANG VIKTORIA
权利人:WANG LIANG; WANG VIKTORIA
摘要:This invention relates to a synthesis of a linear fluorocopolymer having a plurality of pendant phosphorus-containing functional groups. The synthesized phosphorus-containing fluorocopolymer has chain linearity and narrow molecular weight distributions. It has applications as a lubricant additive that provides friction-reduction, anti-wear, and corrosion protection properties.
专利号:WO-2009135600-A1
优先权日:2008-05-07
标题:Catalysts for the synthesis of polyurethanes
发明人:LINDNER STEFAN; BAHNMUELLER STEFAN; SCHMIDT AXEL; WEIKARD JAN; BUCHMEISER MICHAEL; BANTU BHASKER; FRIEDERICHS WOLFGANG; KRAUSE JENS; REITER STEPHAN
权利人:BAYER MATERIALSCIENCE AG; LINDNER STEFAN; BAHNMUELLER STEFAN; SCHMIDT AXEL; WEIKARD JAN; BUCHMEISER MICHAEL; BANTU BHASKER; FRIEDERICHS WOLFGANG; KRAUSE JENS; REITER STEPHAN
摘要:The invention relates to novel catalysts for the synthesis of polyurethanes, represented by general formula (I) or (II), or compounds obtained by reacting a metal salt of the metals magnesium, calcium, yttrium, lanthanum, titanium, zirconium, manganese, iron, cobalt, zinc, aluminium, tin, comprising an anion from the group fluoride, chloride, bromide, sulphonate, trifluoromethanesulphonate, methanesulphonate, benzolsulphonate, para-toluenesulphonate, carboxy-C1-C10-alkyl, carboxy-C3-C10-cycloalkyl, carboxy- C2-C10-alkenyl, C1-C10-alkoxy, acetylacetonate, trifluoroacetlyacetonate or hexafluoroacetylacetonate, with N-heterocyclic compounds of general structure I; or with N-heterocyclic compounds of general structure II; or with N-heterocyclic compounds of general structure III.
专利号:US-5420237-A
优先权日:1991-08-29
标 题:Enzymatic synthesis of polyaniline
发明人:ZEMEL HAYA; QUINN JOHN F
权利人:ALLIED SIGNAL INC
摘要:This invention relates to a process for the enzymatic synthesis of electrically conductive substituted and unsubstituted polyanilines. Aniline monomer(s), an oxidizing agent, which comprises an enzyme and an electron acceptor, and an acidifying agent are reacted together to form polyanilines.
专利号:US-9512250-B2
优先权日:2012-02-23
标 题 :Manganese catalyzed photopolymerization of fluorinated monomers
发明人:ASANDEI ALEXANDRU D
权利人:UNIV CONNECTICUT
摘要:The disclosure discloses initiating systems for the radical polymerization of alkenes, and especially fluorine substituted alkenes. The polymerization is catalyzed by a metal carbonyl, preferably manganese carbonyl. The polymerization is initiated directly from alkyl halides at room temperature under visible white light. The polymers also allow the synthesis of block copolymers. The process comprises polymerizing at least one alkene monomer in the presence of a halide radical initiator, carbonyl catalyst and a solvent, under reaction conditions and for a time sufficient to polymerize the at least one alkene monomer to form a polymer. The present disclosure provides a method for living polymerization of alkene monomers which provides a high level of macromolecular control over the polymerization process and which leads to uniform and controllable polymeric products. This disclosure also provides a method for activating any halide (Cl, Br, I) chain ends of such polymers for the synthesis of block copolymerizations.
专利号:US-10287302-B2
优先权日:2017-06-12
标题 :Method for synthesis of lithium fluorinated borate salts
发明人:YANG JIN; EITOUNI HANY BASAM
权利人:SEEO INC
摘要:An effective method to synthesize Li borate salt such as Li(RfO)aBFb, in which a and b are integers, and a+b=4, has been disclosed. Using RfO-TMS as the starting material enables a streamlined synthesis scheme and makes purification of the final product simple.