CAS: 1073-67-2; 1-Chloro-4-Vinylbenzene

该化合物是一种有机化合物,其特点是存在附于一个乙烯基组的氯化苯基组;一种无色的黄色液体,其芳香味不同;该化合物的特点是一个乙烯基组(Euroh=CH2),该组直接与氯苯环捆绑在一起,特别是在影响其反应性和特性的副位置. 4-Crloostyrene因其能够进行聚合,使其在生产各种聚合物和共聚物方面有用,它在有机溶剂中具有中度溶性,但在水中溶性有限;该化合物还因其在合成制药,农用化学品和特殊化学品方面的潜在用途而得到承认;然而,由于该化合物潜在的健康危害,包括皮肤和呼吸刺激,应当加以谨慎处理;适当的安全措施,包括使用个人防护设备,在实验室或工业环境中与该物质打交道时是必不可少的.

结构式图片

相似化合物

2039-83-0 49678-02-6 2039-85-2

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

CAS号23135-16-2 1-氯-4-(1,2-二溴乙基)苯 | CAS号2788-86-5 2-(对-氯苯基)环氧乙烷 | CAS号637-87-6 对氯碘苯 | CAS号54509-73-8 ethene | CAS号2768-02-7 乙烯基三甲氧基硅烷 | CAS号106-39-8 对氯溴苯 | CAS号2627-95-4 二乙烯基四甲基二硅氧烷 | CAS号50-00-0 甲醛 | CAS号99-91-2 对氯苯乙酮 | CAS号106263-12-1 1-chloro-4-(1-f... | CAS号23135-16-2 1-氯-4-(1,2-二溴乙基)苯 | CAS号2788-86-5 2-(对-氯苯基)环氧乙烷 | CAS号109275-35-6 1-(2-bromo-1-ch... | CAS号5335-87-5 4,4'-二甲氧基二苯二硫醚 | CAS号1370435-75-8 (1-(4-chlorophe... | CAS号169059-34-1 (1-(4-chlorophe... | CAS号3395-81-1 4-氯苯甲醛二甲基缩醛 | CAS号104-88-1 对氯苯甲醛

合成工艺路线路线简述

  • 合成目标产物 4-Chlorostyrene 主要起始原料 Methyltriphenylphosphonium Bromide And 4-Chlorobenzaldehyde
  • (文献来源)合成步骤主要原料 Methyltriphenylphosphonium Bromide 和 4-Chlorobenzaldehyde
对氯肉桂酸 反应 4.0H,以70%的收率获得4-氯苯乙烯
参考文献:取代肉桂酸在低共熔溶剂中的无金属和无碱脱羧
标题:取代肉桂酸在低共熔溶剂中的无金属和无碱脱羧
摘要:摘要置于des 中开发了一种无金属和无碱的策略,通过肉桂酸衍生物的脱羧作用首次合成苯乙烯,这提供了一种可再生且具有成本效益的协议来获取各种苯乙烯,包括具有 4-乙烯基苯酚等官能团的苯乙烯.和1-氯-4-乙烯基苯.图形概要
Doi:10.1080/00397911.2019.1708945

专利信息


专利号:WO-2024181781-A1
优先权日:2023-02-27
标 题:Substrate for synthesis of biological polymers having anti-aggregation function and biological polymer synthesis method using same
发明人:JANG MYOUNG HOON; CHOI JAE SUN
权利人:SP2 TX INC
摘要:The present invention relates to a substrate for the synthesis of biological polymers having an anti-aggregation function, and a biological polymer synthesis method using the substrate. The substrate according to an aspect may have anti-aggregation functionality to enable high-yield and high-purity processes in the synthesis of biological polymers.

专利号:US-7956011-B2
优先权日:2005-05-04
标题:Materials and methods for the photodirected synthesis of oligonucleotide arrays
发明人:SERAFINOWSKI PAWEL JERZY; GARLAND PETER BRYAN
权利人:CANCER RES INST ROYAL
摘要:Materials and methods for photodirected synthesis of oligonucleotide arrays on a solid substrate by photodirected synthesis are disclosed which employ a film formed from (i) a photoacid generator that on photolysis generates acid that is capable of directly removing the protecting group of the linker molecules or oligonucleotides and (ii) a polymer substantially lacking electronegative heteroatoms that are capable of hydrogen bonding with photogenerated acid. Methods of synthesizing an oligomer arrays are also described that use a film that restricts diffusion of reactants and products on the substrate during synthesis of the array and which includes a precursor of a deprotecting reagent. The method involves removing one or more of the non-required products of the deprotection reaction from the reactive array elements at which they are produced during the reaction, in order to displace the deprotection reaction towards completion.

专利号:US-2013196019-A1
优先权日:2010-03-18
标 题:Silicon-containing block co-polymers, methods for synthesis and use
发明人:WILLSON C GRANT; BATES CHRISTOPHER M; STRAHAN JEFFREY; ELLISON CHRISTOPHER JOHN; MUELLER BRENNEN
权利人:WILLSON C GRANT; BATES CHRISTOPHER M; STRAHAN JEFFREY; ELLISON CHRISTOPHER JOHN; MUELLER BRENNEN; NAT UNIVERSITY OF SINAPORE
摘要:The present invention describes the synthesis of silicon-containing monomers and copolymers. The synthesis of a monomer, trimethyl-(2-methylenebut-3-enyl)silane (TMSI) and subsequent synthesis of diblock copolymer with styrene, forming polystyrene-block-polytrimethylsilyl isoprene, and synthesis of diblock copolymer Polystyrene-block-polymethacryloxymethyltrimethylsilane or PS-b-P(MTMSMA). These silicon containing diblock copolymers have a variety of uses. One preferred application is as novel imprint template material with sub-100 nm features for lithography.

专利号:US-4923839-A
优先权日:1987-02-05
标题:Low temperature synthesis of condensation polymers
发明人:OGATA NAOYA
权利人:GOODYEAR TIRE & RUBBER
摘要:Condensation polymers of high molecular weight, such as polyesters, polyureas, and polyamides, are usually prepared at temperatures of 200° C. or greater. However, by utilizing the catalyst systems of the present invention, condensation polymers can be synthesized at much lower temperatures. The polycondensation catalyst systems of the present invention are particularly useful for synthesizing aliphatic polyesters, such as polyethylene terephthalate, from dicarboxylic acids and aliphatic glycols. The present invention more specifically discloses a process for the synthesis of an aliphatic polyester comprising polymerizing at least one dicarboxylic acid with at least one aliphatic glycol in the presence of (1) at least one phosphorus containing compound which contains at least one trivalent or pentavalent phosphorus atom which is bonded directly to at least one phenyl group, (2) an acid acceptor, and (3) at least one halogenated organic compound. It is preferred to utilize a polymeric agent having bound acid acceptor groups as the acid acceptor in the process of the present invention.

专利号:US-4843053-A
优先权日:1987-02-05
标 题 :Low temperature synthesis of condensation polymers
发明人:OGATA NAOYA
权利人:GOODYEAR TIRE & RUBBER
摘要:Condensation polymers of high molecular weight, such as polyesters, polyureas, and polyamides, are usually prepared at temperatures of 200° C. or greater. However, by utilizing the catalyst systems of the present invention, condensation polymers can be synthesized at much lower temperatures. The polycondensation catalyst systems of the present invention are particularly useful for synthesizing aliphatic polyesters, such as polyethylene terephthalate, from dicarboxylic acids and aliphatic glycols. The present invention more specifically discloses a process for the synthesis of an aliphatic polyester comprising polymerizing at least one dicarboxylic acid with at least one aliphatic glycol in the presence of (1) at least one phosphorus containing compound which contains at least one trivalent or pentavalent phosphorus atom which is bonded directly to at least one phenyl group, (2) an acid acceptor, and (3) at least one halogenated organic compound. It is preferred to utilize a polymeric agent having bound acid acceptor groups as the acid acceptor in the process of the present invention.

专利号:US-4581416-A
优先权日:1981-01-19
标题 :Process for the synthesis of tertiary phosphine oxides and sulfides, and new tertiary phosphine oxides and sulfides
发明人:BERGERET WILFRID; BOILEAU SYLVIE; GAUTIER JEAN-CLAUDE; RAYNAL SERGE
权利人:POUDRES & EXPLOSIFS STE NALE
摘要:The invention relates to processes for the synthesis of tertiary phosphine oxides and sulfides. The process according to the invention consists, in a first step, of reacting a secondary phosphine oxide or sulfide with an optionally activated alkali metal amide, and, in a second step, of reacting the mixture obtained in the first step with an organic halide containing at least one halogenophenyl radical or one halogenomethyl group. Tertiary phosphine oxides and sulfides are complexing agents of high stability.
上海易盛汇生物医药科技有限公司
⚠️ 未注册 · 未认证企业
⚠️ 该商家尚未完成注册及企业认证,请用户仔细辨别,谨慎交易。
数据来源于公开网络搜索,平台未作核实,请自行辨别。
🏢敬请 企业认领
🏬开设公司展台
📢获取免费会员权益
🎖️点亮专属注册企业标签
📇展现公司完整信息 样本查看立即注册认领 →
网址: http://www.ychemical.com
企业联系电话:021-61453981👤
📞上海易盛汇生物医药科技有限公司 ⚠️参考联系方式
联系人:江小姐
电话:021-61453981
手机:13564731332
传真:021-61453981
邮箱:yishenghui99@126.com
通信地址: 上海市闵行区紫月路1299号2号楼301室
邮编: 200231
🆔 联系时候可告知是从"百琢研"平台获取的信息.
⚠️ 声明: 该企业未认证、未认领,请自行辨别信息的真实性和可靠性。咨询或交易时请注意风险评估与信息核实,百琢研不参与任何交易。企业认领注册入口→

地址:上海市闵行区紫月路1299号2号楼301室
⚠️ 未注册 · 未认证企业
注册入口 备注: 📌 数据来源说明:本展台内容基于各搜索引擎等公开数据整理,仅作展示用途。请用户自行辨别
✉️ 若企业需抹除展台内容或有异议, 请通过页面底部联系方式告知我们,我们会尽快处理。
上海宝瑞化工有限公司
⚠️ 未注册 · 未认证企业
⚠️ 该商家尚未完成注册及企业认证,请用户仔细辨别,谨慎交易。
数据来源于公开网络搜索,平台未作核实,请自行辨别。
🏢敬请 企业认领
🏬开设公司展台
📢获取免费会员权益
🎖️点亮专属注册企业标签
📇展现公司完整信息 样本查看立即注册认领 →
网址: http://www.shbrchem.com
企业联系电话:13262886496;17625729319👤
📞上海宝瑞化工有限公司 ⚠️参考联系方式
联系人:于先生;郑女士
电话:13262886496;17625729319
手机:13262886496;17625729319
传真:021-62148466
邮箱:2425283046@qq.com
通信地址: 上海市宝山区城银路525号1903室
邮编: 200332
🆔 联系时候可告知是从"百琢研"平台获取的信息.
⚠️ 声明: 该企业未认证、未认领,请自行辨别信息的真实性和可靠性。咨询或交易时请注意风险评估与信息核实,百琢研不参与任何交易。企业认领注册入口→

地址:上海市宝山区城银路525号1903室
⚠️ 未注册 · 未认证企业
注册入口 备注: 📌 数据来源说明:本展台内容基于各搜索引擎等公开数据整理,仅作展示用途。请用户自行辨别
✉️ 若企业需抹除展台内容或有异议, 请通过页面底部联系方式告知我们,我们会尽快处理。
盐城美茵新材料有限公司
⚠️ 未注册 · 未认证企业
⚠️ 该商家尚未完成注册及企业认证,请用户仔细辨别,谨慎交易。
数据来源于公开网络搜索,平台未作核实,请自行辨别。
🏢敬请 企业认领
🏬开设公司展台
📢获取免费会员权益
🎖️点亮专属注册企业标签
📇展现公司完整信息 样本查看立即注册认领 →
网址: http://www.ycmerit.com
企业联系电话:025-86116009;18101596203👤
📞盐城美茵新材料有限公司 ⚠️参考联系方式
联系人:朱总
电话:025-86116009;18101596203
手机:18101596203
传真:0515-87225682
邮箱:sales@ycmerit.com
通信地址: 江苏省盐城市阜宁县阜宁经济开发区协鑫大道15号
邮编: 224400
🆔 联系时候可告知是从"百琢研"平台获取的信息.
⚠️ 声明: 该企业未认证、未认领,请自行辨别信息的真实性和可靠性。咨询或交易时请注意风险评估与信息核实,百琢研不参与任何交易。企业认领注册入口→

地址:江苏省盐城市阜宁县阜宁经济开发区协鑫大道15号
⚠️ 未注册 · 未认证企业
注册入口 备注: 📌 数据来源说明:本展台内容基于各搜索引擎等公开数据整理,仅作展示用途。请用户自行辨别
✉️ 若企业需抹除展台内容或有异议, 请通过页面底部联系方式告知我们,我们会尽快处理。
第 1 / 1 页
现货

供应商参考报价(招募中)

品牌试剂参考报价(招募中)

📌 第三方产品分析报告

✅ COA系统入驻 | 共享模式

主要参考文献

[参考文献]: Guido Pampaloni, Et Al. Synthesis, Characterization And Olefin/co Exchange Reactions Of Pyrazolylborato Complexes Of Copper(I). Dalton Trans. 2006 Aug 7:(29):3576-83.
[参考文献]: Jou-Ku Chung, Et Al. Structure-Toxicity Relationship Study Of Para-Halogenated Styrene Analogues In Cyp2E1 Transgenic Cells. Toxicol Lett. 2012 May 5;210(3):353-9.
[参考文献]: Wei Chen, Et Al. [参考文献]: Zhonghua Lao Dong Wei Sheng Zhi Ye Bing Za Zhi. 2011 Feb;29(2):152-3.

合成参考文献


摘要:Alonso, D. A.; Nájera, C., Science of Synthesis, (2010) 45, 228.
摘要:Black, D. A.; Fagnou, K., Science of Synthesis, (2010) 45, 629.
摘要:Amatore, M.; Aubert, C.; Malacria, M.; Petit, M., Science of Synthesis Knowledge Updates, (2012) 3, 88.
摘要:Li, Y.; Xie, W.; Jiang, X., Science of Synthesis Knowledge Updates, (2016) 2, 16.
摘要:Li, W.; Liu, X. H.; Feng, X. M., Science of Synthesis Knowledge Updates, (2021) 1, 41.
📝 需求与反馈
尽可能描述清楚需求与问题信息
×

通知