CAS: 1303-52-2; Gold(Iii)Hydroxide

该化合物是一种化学化合物,主要用于催化,材料科学和金纳米粒子合成,它作为生产金基催化剂的前体,由于金的稳定性和反应性高,在有机转化和电子化学应用方面很有价值;该化合物还用于制备用于电子和光学应用的金胶片和薄膜;其受控分解产生高纯金,在专门冶金工艺中有用;Gold(III) 氢氧化物必须谨慎处理,因为它对光和水分敏感,要求在惰性条件下储存以保持稳定性.

结构式图片

欧盟法规

ECHA物质C&L通报REACH预注册

合成工艺路线路线简述

    氢氧化钾 反应生成氢氧化金
    参考文献:Agafonov,G. V.;Poshkus,D. P.,Issled. V Obl. Osazhdeniya Met.,Vilnyus,(1988) S. 93-98
    标题:Agafonov,G. V.;Poshkus,D. P.,Issled. V Obl. Osazhdeniya Met.,Vilnyus,(1988) S. 93-98

    专利信息


    专利号:US-2023286918-A1
    优先权日:2020-07-02
    标 题:Manufacturing process for 3,5-dichloropicolinonitrile for synthesis of vadadustat
    发明人:JURKAUSKAS VALDAS; JUNG YOUNG CHUN; KWON TAESOO; KANNAN ARUNACHALAM; GONDI VIJAYA BHASKER
    权利人:AKEBIA THERAPEUTICS INC
    摘要:Disclosed herein are methods and processes of preparing vadadustat or a pharmaceutically acceptable salts thereof, and intermediates (e.g., a compound of Formula (I), (I-F), (II), or (IV), or a pharmaceutically acceptable salts thereof) useful for the synthesis of vadadustat.

    专利号:US-9487399-B2
    优先权日:2010-08-17
    标题 :Method for the synthesis of metallic nano products
    发明人:GHANAVI JALALEDIN; MOSTAFAVI MEHRNAZ; GHANAVI ZOHRE
    权利人:GHANAVI JALALEDIN; MOSTAFAVI MEHRNAZ; GHANAVI ZOHRE
    摘要:The embodiments herein provide a method of synthesis for metallic nano-products such as metallic nano-antennas, metallic nano-rods, metallic nano-wires, metallic nano-prolate spheroids and metallic nano-oblate spheroids using saturated and unsaturated carboxylic acids. The method involves preparing a reaction mixture by mixing a polar protic solvent, a polar aprotic solvent or a non-polar solvent, a saturated fatty acid or an unsaturated fatty acid and a metallic salt. Then a mixture of reducing agents is prepared by mixing a polar protic solvent, a polar aprotic solvent or a non-polar solvent and a saturated fatty acid or an unsaturated fatty acid. The reaction mixture and the mixture of reducing agents are combined and heated solvo-thermally for a pre-determined period of time at a pre-determined temperature.

    专利号:US-9822053-B2
    优先权日:2016-01-28
    标题:Single step conversion of N-butyraldehyde to 2-ethylhexanal
    发明人:BOPPANA Venkata Bharat; HAMPTON JR KENNETH WAYNE; LIU ZHUFANG; SUMNER JR CHARLES EDWAN; TUSTIN GERALD C; STEINMETZ GUY RALPH; STEFFEY MELISSA PAGE
    权利人:EASTMAN CHEM CO
    摘要:Disclosed is a method of making and using a titania supported palladium catalyst for the single step synthesis of 2-ethylhexanal from a feed of n-butyraldehyde. This titania supported palladium catalyst demonstrates high n-butyraldehyde conversion but also produces 2-ethylhexanal in an appreciable yield with maintained activity between runs. This method provides a single step synthesis of 2-ethylhexanal from n-butyraldehyde with a catalyst that can be regenerated that provides cleaner downstream separations relative to the traditional caustic route.

    专利号:US-6011171-A
    优先权日:1996-08-14
    标 题 :Process for synthesis of tertiary carboxylic acids and the esters thereof
    发明人:XU QIANG; SOUMA YOSHIE
    权利人:JIRO HIRAISHI DIRECTOR GENERAL
    摘要:The present invention provides a process for synthesizing tertiary carboxylic acids or the esters thereof having one or two more carbon atoms than the raw material has, comprising reacting in a strong acid (e.g., sulfuric acid, sulfuric acid-phosphoric acid, hydrogen fluoride, fluorosulfuric acid, boron trifluoride.water complex and trifluoromethanesulfonic acid) a raw material compound (i.e., olefin, alcohol, diene, diol or saturated hydrocarbon) with carbon monoxide in the presence of a specific metal carbonyl catalyst (i.e., platinum carbonyl catalyst, palladium carbonyl catalyst and gold dicarbonyl catalyst). The metal carbonyl catalyst is formed by reacting in a strong acid at least one specific metal compounds (e.g., platinum compound such as platinum (II, IV) oxide, platinum (II, IV) hydroxide, a platinum powder, etc.; palladium compound such as palladium (II, III, IV) oxide, palladium (II) hydroxide, palladium (II) sulfate, palladium (II) carboxylate, a palladium powder, etc.; and gold compound such as gold (I, III) oxide, gold (I, III) hydroxide, a gold powder, etc.) with carbon monoxide.

    专利号:US-2009088319-A1
    优先权日:2007-09-28
    标题:Synthesis of Gold Metal Oxide Catalysts for Catalytic Oxidation of Carbon Monoxide by Vapor Deposition of Ammonia
    发明人:HARINATH ARVIND VYAS; BANERJEE CHANDRA K; SANKAR JAGANNATHAN
    权利人:NORTH CAROLINA AGRICULTURAL AN
    摘要:The present invention provides processes for synthesizing gold metal oxide catalysts and gold metal oxide catalysts synthesized according to the processes described herein. Methods of using the gold metal catalysts are also provided.

    专利号:US-11629137-B2
    优先权日:2017-04-24
    标 题:Methods of manufacturing of niraparib
    发明人:STEWART ALISTAIR; TOTO ANTHONY JOSEPH; CHEN FRANK XING; WU GEORGE
    权利人:TESARO INC
    摘要:Disclosed herein are methods and processes of preparing niraparib and pharmaceutically acceptable salts thereof, and intermediates and their salts useful for the synthesis of niraparib.
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    合成参考文献


    参考文献:10.1007/s10751-024-01884-3
    摘要:kobayashi Y, Ohashi H, Kurokuzu M, Seto M. Recoilless fraction on 197Au Mössbauer spectroscopy. Interactions. 2024 Mar 14;245(1). doi: 10.1007/s10751-024-01884-3.
    参考文献:10.1007/s13738-024-03039-1
    摘要:Boruah SK, Das H, Boruah PK. Optical and electrochemical investigation on one-step three electron reduction of [AuIII(Salen)]Cl to Au(0): a comprehensive analysis. J IRAN CHEM SOC. 2024 May 22;21(7):1937–45. doi: 10.1007/s13738-024-03039-1.
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