CAS: 14808-79-8; Sulfate

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trimethylene sulphide Dimethyldisulphide propylene sulphide peroxomonophosphoric acidhydrogen sulfide sulfuric acid ozone dihydrogen peroxide

二氧化硫置于氧钒酞菁 氧气体系中,用 吡啶 用作溶剂,化学反应生成硫酸酯
参考文献:氧钒钠(iv)塞伦和酞菁与硫化合物和还原剂的反应.与催化脱金属有关
标题:氧钒钠(iv)塞伦和酞菁与硫化合物和还原剂的反应.与催化脱金属有关
摘要:摘要综述了部分石油中钒化合物的性质.提出了氧杂钒(iv)酞菁和氧杂钒(iv)schiff碱配合物作为卟啉和沥青质中钒配位的模型.描述了这些化合物与硫化氢,硫醇和其他有机硫化合物,二氧化硫和三乙基铝的反应.席夫碱络合物易于脱金属,钒被转化为v 2 S 3.酞菁(和卟啉)配合物的脱金属更困难.在存在氮碱的情况下,使用h 2 S和硫醇可以还原vo(酞菁),同时减少末端氧,但不会插入硫.用三乙基铝还原钒,并侵蚀酞菁环系统.Vo(酞菁)催化h 2 S,硫醇和so 2的空中氧化.该结果与催化脱金属问题有关.
Doi:10.1016/s0020-1693(00)83657-9

专利信息

专利号:US-11926589-B2
优先权日:2019-07-09
标 题 :Process for the synthesis of non-racemic cyclohexenes
发明人：REISMAN SARAH; ROMBOLA MICHAEL; LADD CAROLYN L; MCLAUGHLIN MARTIN JOHN; ZUEND STEPHAN; GOETZ ROLAND
权利人:BASF CORP; CALIFORNIA INST OF TECHN
摘要:This invention relates to a process for the synthesis of a non-racemic cyclohexene compound of formula (I) by a Diels-Alder reaction of a compound of formula (II) with a compound of formula (III) wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 and Y have the meanings as defined in the description in the presence of a catalyst comprising at least one m-valent metal cation M m+ wherein the metal M is selected from Scandium (Sc), Yttrium (Y), Lanthanum (La), Cerium (Ce), Praseodymium (Pr), Neodymium (Nd), Promethium (Pm), Samarium (Sm), Europium (Eu), Gadolinium 15 (Gd), Terbium (Tb), Dysprosium (Dy), Holmium (Ho), Erbium (Er), Thulium (Tm), Ytterbium (Yb), Lutetium (Lu), Gallium (Ga) and Indium (In), and m is an integer of 1, 2 or 3, and a chiral ligand of the formula (IV) wherein R 10a , R 10b , R 10c , R 10d , R 10a′ , R 10b′ , R 10c′ , R 10d′ , Z and Z′ have the meanings as defined in the description.

专利号:US-6576447-B2
优先权日:2000-03-21
标 题:Method for synthesis of nucleic acids
发明人：TONOIKE HIROSHI
权利人:SHIMADZU CORP
摘要:An object of the present invention is to provide a novel method for suppressing the action of nucleic acid synthesis inhibitory substances and thereby amplifying a nucleic acid in a sample efficiently.According to the present invention, in a method for synthesis of nucleic acids to amplify an intended nucleic acid in a sample, the sample is brought in advance into contact with an insoluble polymer of a polyanion, a sulfated polymer or a sulfated polysaccharide, to remove nucleic acid synthesis inhibitory substances.

专利号:US-2014194584-A1
优先权日:2013-01-07
标题 :Process for the synthesis of w-Unsaturated nitrile-acid/ester in which two types of cross metathesis are alternated consecutively swing process
发明人：DUBOIS JEAN-LUC; COUTURIER JEAN-LUC
权利人:ARKEMA FRANCE
摘要:The invention relates to a process for the synthesis of a monounsaturated nitrile-ester (acid) by cross metathesis starting from an unsaturated compound I comprising at least one trivalent nitrile, acid or ester functional group, characterized in that it comprises a stage in which two types of cross metathesis are alternated consecutively:n a first type of cross metathesis cm1 with an acrylic compound II chosen from acrylonitrile, acrylic acid or an acrylic ester, one of the compounds I or II comprising a nitrile functional group and the other of these compounds II or I comprising an acid or ester functional group, and a second type of cross metathesis cm2 with a light C 2 to C 4 alkene compound III, preferably with ethylene. nn The invention also relates to a process for the synthesis of an α,ω-amino ester (acid) obtained by a process comprising a stage in which the two types of cross metathesis defined above are alternated consecutively, followed by a hydrogenation stage.

专利号:US-11773112-B2
优先权日:2020-12-05
标题:Synthesis of tetrazolate salts
发明人：PRADHAN BRAJA SUNDAR; SINGH SANJEEV K; MEHTA NEHA H
权利人:PRIMODIA CHEMICALS AND PHARMACEUTICALS PRIVATE LTD
摘要:The present invention relates to a novel method of synthesis of copper (I) 5-nitrotetrazolate. Particularly, for the synthesis of the copper (I) 5-nitrotetrazolate, the present invention uses a suitable salt of 5-aminotetrazole, preferably the sulfate or the nitrate salt as the starting compound. The selection of the said starting chemical not only eliminates any safety issue arising during Sandmeyer reaction conditions to affect the functional group conversion but also greatly improves the ease of executing the synthetic protocol, rendering the process safe to be adopted for commercial manufacture of the copper (I) 5-nitrotetrazolate compound.

专利号:US-2005027142-A1
优先权日:2003-08-01
标题 :Method for synthesis of 2,2,6-trimethylcyclohexan-1-one
发明人：KLEINFELD SUSANNE; FISCHER ACHIM; WILZ FRANK; WECKBECKER CHRISTOPH; HUTHMACHER KLAUS
权利人:DEGUSSA
摘要:The present invention relates to a method for synthesis of 2,2,6-trimethylcyclohexan-1-one (TMCH) by partial reduction of 2,6,6-trimethyl-2-cyclohexen-1,4-dione (ketoisophorone, KIP), the reaction being carried out in the gas phase in the presence of oxide catalysts.

专利号:US-10287242-B2
优先权日:2011-12-28
标 题:Process for the synthesis of highly pure cationic surfactant products
发明人：MEHTA DILIP S; SHASTRI MAYANK
权利人:MEHTA DILIP S; SHASTRI MAYANK; ORGANISTRY LLC
摘要:The present invention is related to synthesis of highly pure cationic surfactant products by eliminating or reducing impurities generation that has beset prior art. This is achieved through the N-acylation of ester of amino acid and its inorganic salts or its organic salts (e.g. amino acid or hydrochloride of amino acid or sulfate of amino acid or acetate of amino acid etc.) in non-hydrolytic or nearly non-hydrolytic reaction conditions involving mono or biphasic reaction system with fatty acid halide (C 4 to C 20 ), under moderate uniform basic condition yielding high purity N-acyl substituted amino acid ester, particularly ethyl lauroyl arginate. The present process achieves pH control through process strategy rather than the measurement and control steps. This ambient temperature process is stable through a range of temperature variation eliminating rigid low temperature control.