CAS: 82-38-2; 1-(Methylamino)Anthracene-9,10-Dione

• 英文名称1-(Methylamino)Anthracene-9,10-Dione
• 中文名称1-(甲氨基)蒽醌
• IUPAC名称1-(methylamino)anthracene-9,10-dione
• 其它别名溶剂红 111; Transparent Red Gs
• CAS编号82-38-2
• MFCD编号:MFCD00001197
• EINECS号:201-417-2
• FDA UNII编号:5O1807MLL1
• 分子式:C15H11NO2
• 分子量:237.26
• 产品CID: 1814680
• 产品分类有机原料→分子砌块→芳环类化合物→苯类化合物

• 相似结构搜索
• 产品信息参考;;;;
• InChIKey: SVTDYSXXLJYUTM-UHFFFAOYSA-N
• InChI=1S/C15H11NO2/c1-16-12-8-4-7-11-13(12)15(18)10-6-3-2-5-9(10)14(11)17/h2-8,16H,1H3…
• 计算化学: 氢键受体数3.0氢键供体数1.0可旋转键数1.0

物理性质

• 熔点170-172 °C
• 沸点379.79 °C at 760 mmHg
• 闪点195.3±25.8 °C
• 密度1.3±0.1 g/cm3
• pKa:2.27±0.20(预测)
• PSA:46.17
• LogP:2.5037
• 折射率1.691
• 蒸汽压0.0±1.1 mmHg at 25°C
• 溶解性73.55Ug/l(25 °c)
• 外观形态橙色至棕色粉末
• 储存条件室温
• 产品应用聚氯乙烯及醋酸纤维的染色.
• 性质描述橙色针状结晶.熔点172°C.

MSDS等安全信息

• GHS象形图
• GHS符号GHS07;
  注释: Exclamation mark
• 危险类别特定目标器官毒性 - 单次接触 类别3
  皮肤腐蚀/刺激 类别2
  严重眼刺激 类别2
  水生慢性毒性 类别4
  严重眼刺激 类别2A
• 警示词Warning(警告)
• 危险描述H335 |可能引起呼吸道刺激.
  H315 |造成皮肤刺激.
  H319 |造成严重眼刺激.
  H413 |可能对水生生物造成长期有害影响.
• 防范说明P261-P264-P271-P280-P302+P352-P304+P340-P362+P364-P405-P501
• UN编号NONH for all modes of transport
• 危险品标志Xi
• 安全声明26-37/39
• 危险类别码36/37/38
• WGK Germany3

欧盟法规

上下游产品

合成工艺路线路线简述

• 合成目标产物 Disperse Red 9 主要起始原料 Tetrabutylammonium Bromide And 1-Aminoanthraquinone And Dimethyl Sulfate
• 82-34-8 = 82-38-2
  反应条件:1.1 Reagents: Urea,Calcium Hydroxide Solvents: Xylene,Water; Rt -> 120 °C; 4 H,0.24 Mpa,120 °C1.2 Reagents: Hydrochloric Acid,Ammonium Chloride Solvents: Water
  标题:Synthesis Of 1-Methylaminoanthraquinone
  作者:Yu,Hong-Xia; Et Al
  参考文献:Ranliao Yu Ranse 日期:2003 卷标:40(1)]
  
  82-44-0 = 82-38-2
  反应条件:1.1 Reagents: Copper Solvents: Pyridine,Water
  标题:Latest Tests In Control Of Tomato Anthracnose
  作者:Runnells,H. A.; Et Al
  参考文献:Farm & Home Research 日期:1949 卷标:34 页码:67-70]
  
  82-44-0 = 82-38-2
  反应条件:1.1 Reagents: Cuprous Chloride
  标题:Copper-Catalyzed Amination Of α-Substituted Anthraquinones
  作者:Yoshida,Katsuhira; Et Al
  参考文献:Chemistry Letters 日期:1978 卷标:(7) 页码:765-8]
  
  82-45-1 = 82-38-2
  反应条件:1.1 Solvents: 1-Propyl-3-Methylimidazolium Bromide; 6 H,120 °C
  标题:Ionic Liquids As Novel And Recyclable Reaction Media For N-Alkylation Of Amino-9,10-Anthraquinones By Trialkyl Phosphites
  作者:Yavari,Issa; Et Al
  参考文献:Tetrahedron Letters 日期:2007 卷标:48(21) 页码:3753-3756]
  
  680-31-9 + 82-44-0 = 82-38-2 [标题:Reaction Conditions
  标题:Reactions Of 1,5-Dichloroanthraquinone With Nucleophiles
  作者:Ruediger,Edward H.; Et Al
  参考文献:Journal Of Organic Chemistry 日期:1980 卷标:45(10) 页码:1974-8]
  
  84-65-1 = 82-38-2 [标题:Reaction Conditions
  标题:Photoamination Reaction Of 9,10-Anthraquinone
  作者:Loskutov,V. A.; Et Al
  参考文献:Izvestiya Sibirskogo Otdeleniya Akademii Nauk Sssr 日期:1978 卷标:(4) 页码:135-7]
  
  82-44-0 + 123-39-7 = 82-38-2
  反应条件:1.1 Catalysts: Ethanolamine
  标题:Anomalous Halogen To Dimethylamino Replacement With N,N-Dimethylformamide Catalyzed By Ethylenediamine Or 2-Aminoethanol
  作者:Yamamoto,Hiroshi
  参考文献:Bulletin Of The Chemical Society Of Japan 日期:1982 卷标:55(8) 页码:2685-6]
  
  128-67-6 = 82-38-2 [标题:Reaction Conditions
  标题:1-Methylamino-2,4-Dibromoanthraquinone
  作者:Ufimtsev,V. N.; Et Al
  参考文献:Zhurnal Vsesoyuznogo Khimicheskogo Obshchestva Im. D. I. Mendeleeva 日期:1976 卷标:21(4) 页码:467-8]
  
  73178-74-2 = 82-38-2
  反应条件:1.1 Reagents: Potassium Amide
  标题:Reactions Of 1,5-Dichloroanthraquinone With Nucleophiles
  作者:Ruediger,Edward H.; Et Al
  参考文献:Journal Of Organic Chemistry 日期:1980 卷标:45(10) 页码:1974-8]
  
  82-34-8 = 82-38-2
  反应条件:1.1 Reagents: Methylamine Solvents: Isoamyl Alcohol
  标题:Reaction Of 1-Chloro- And 1-Nitroanthraquinones With 3-(Alkylamino)- And 3-(Dialkylamino)Propionitriles
  作者:Vostrova,V. N.; Et Al
  参考文献:Zhurnal Organicheskoi Khimii 日期:1986 卷标:22(5) 页码:1046-9]
  
  3571-23-1 = 82-38-2
  反应条件:1.1 Reagents: Potassium Carbonate,Sodium Hydroxide,Tetrabutylammonium Hydrogen Sulfate Solvents: Toluene1.2 -
  标题:Facile Synthesis Of Substituted N-Monoalkylaromatic Amines Under Phase-Transfer Catalysis Conditions
  作者:Kalkote,U. R.; Et Al
  参考文献:Synthetic Communications 日期:1991 卷标:21(18-19) 页码:1889-900]
  
  82-44-0 = 82-38-2
  反应条件:1.1 Reagents: Potassium Acetate Solvents: Water
  标题:Manufacture Of 1-(Alkylamino)Anthraquinones For Dyes In High Yield And Purity
  参考文献:Japan]
  
  82-45-1 = 82-38-2
  反应条件:1.1 Reagents: Potassium Carbonate,Sodium Hydroxide Catalysts: Tetrabutylammonium Bromide
  标题:Phase Transfer Catalyzed N-Monoalkylation Of Aminoanthraquinones
  作者:Ramrao,Kalkote Uttam; Et Al
  参考文献:Synthetic Communications 日期:1991 卷标:21(10-11) 页码:1129-35]
  
  82-34-8 + 693-05-0 = 82-38-2
  反应条件:1.1 Solvents: 1-Butanol
  标题:Reaction Of 1-Chloro- And 1-Nitroanthraquinones With 3-(Alkylamino)- And 3-(Dialkylamino)Propionitriles
  作者:Vostrova,V. N.; Et Al
  参考文献:Zhurnal Organicheskoi Khimii 日期:1986 卷标:22(5) 页码:1046-9]
  
  5960-55-4 = 82-38-2 [标题:Reaction Conditions
  标题:Photochemical Substitution Of Amino- And Hydroxyanthraquinones
  作者:Hamilton,Kenneth; Et Al
  参考文献:Journal Of The Chemical Society 日期:1980 卷标:(10) 页码:1544-8]
  
  82-44-0 + 693-05-0 = 82-38-2
  反应条件:1.1 Solvents: Methanol
  标题:Reaction Of 1-Chloro- And 1-Nitroanthraquinones With 3-(Alkylamino)- And 3-(Dialkylamino)Propionitriles
  作者:Vostrova,V. N.; Et Al
  参考文献:Zhurnal Organicheskoi Khimii 日期:1986 卷标:22(5) 页码:1046-9]
  
  52868-88-9 = 82-38-2
  反应条件:1.1 Reagents: Sodium Chlorate
  标题:1-Methylaminoanthraquinone
  作者:Wilson,C. V.; Et Al
  参考文献:Organic Syntheses 日期:1949 卷标:29 页码:66-8]
  
  = 82-38-2 [标题:Reaction Conditions
  标题:Photolysis Of (Nitrosomethylamino)Anthraquinones
  作者:Klimenko,L. S.; Et Al
  参考文献:Izvestiya Akademii Nauk Sssr 日期:1991 卷标:(9) 页码:2098-102]
  
  82-46-2 + 123-39-7 = 82-38-2
  反应条件:1.1 -2.1 Reagents: Potassium Amide
  标题:Reactions Of 1,5-Dichloroanthraquinone With Nucleophiles
  作者:Ruediger,Edward H.; Et Al
  参考文献:Journal Of Organic Chemistry 日期:1980 卷标:45(10) 页码:1974-8]
  
  680-31-9 + 82-46-2 = 82-38-2
  反应条件:1.1 -2.1 Reagents: Potassium Amide
  标题:Reactions Of 1,5-Dichloroanthraquinone With Nucleophiles
  作者:Ruediger,Edward H.; Et Al
  参考文献:Journal Of Organic Chemistry 日期:1980 卷标:45(10) 页码:1974-8

海关参考信息

• 2912110000-甲醛
  2912210000-苯甲醛
  2914610000-蒽醌
  2914190090-其他无环酮
• 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
• 详情请参考：📖 海关编码查询和海关进出口税则

专利信息

其他信息查阅

• ➥ 象形图和危险代码
• ➥ 防范代码详解
• ➥ 危险代码说明
• ➥ Globally Harmonized System
• ➥ REACH监管