重氮甲烷置于四氯化硅,乙醚,铜体系中,化学反应生成(氯甲基)三氯硅烷 参考文献:The Preparation Of Chloromethyl Derivatives Of Germanium And Silicon By The Diazomethane Method 标题:The Preparation Of Chloromethyl Derivatives Of Germanium And Silicon By The Diazomethane Method 摘要: Doi:10.1021/ja01609A031
专利号:US-9416147-B2 优先权日:2014-04-03 标题 :Preparation of silazane compound 发明人:TONOMURA YOICHI; KUBOTA TOHRU 权利人:SHINETSU CHEMICAL CO 摘要:A silazane compound useful as synthesis intermediates for paint additives, polymer modifiers, pharmaceuticals and agricultural chemicals is efficiently prepared by reaction of a halosilane compound with an amino-containing compound in a solvent which is the same silazane compound as the target product.
专利号:DE-4024600-A1 优先权日:1989-08-03 标题 :ELECTROCHEMICAL SYNTHESIS OF ORGANOSILICIUM COMPOUNDS
专利号:HU-210806-B 优先权日:1989-12-01 标 题 :Procedure and connection-arrangement for low temperature synthesis of atran-skeletoned compounds by half-continuous technology
专利号:GB-2234511-A 优先权日:1989-08-03 标 题:Electrochemical synthesis of organosilicon compounds
专利号:CA-2022184-A1 优先权日:1989-08-03 标题:Electrochemical synthesis of organosilicon compounds
专利号:US-10870917-B2 优先权日:2016-07-08 标 题:Functionalized foams 发明人:DARLING SETH B; ELAM JEFFREY W; MANE ANIL U; SNYDER SETH W 权利人:UCHICAGO ARGONNE LLC 摘要:A method of fabricating an foam includes providing a foam comprising a base material. The base material is coated with an inorganic material using at least one of an atomic layer deposition (ALD), a molecular layer deposition (MLD), or sequential infiltration synthesis (SIS) process. The SIS process includes at least one cycle of exposing the foam to a first metal precursor for a first predetermined time and a first partial pressure. The first metal precursor infiltrates at least a portion of the base material and binds with the base material. The foam is exposed to a second co-reactant precursor for a second predetermined time and a second partial pressure. The second co-reactant precursor reacts with the first metal precursor, thereby forming the inorganic material on the base material. The inorganic material infiltrating at least the portion of the base material. The inorganic material is functionalized with a material.
参考标题:Hydrogen/halogen Exchange Of Phosphines For The Rapid Formation Of Cyclopolyphosphines 作者:Adam N. Barrett,Callum R. Woof,Christopher A. Goult,Danila Gasperini,Mary F. Mahon,Ruth L. Webster |发布日期:2021.11.1 摘要:The Hydrogen/halogen Exchange Of Phosphines Has Been Exploited To Establish A Truly Useable Substrate Scope And Straightforward Methodology For The Formation Of Cyclopolyphosphines. Starting From A Single Dichlorophosphine, A Sacrificial Proton "Donor Phosphine" Makes The Rapid, Mild Synthesis Of Cyclopolyphosphines Possible: Reactions Are Complete Within 10 Min At Room Temperature. Novel (Aryl)Cyclopentaphosphines
合成参考文献
摘要:Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Substances. For English translation, see TNICS*., 3(33), 1961 摘要:Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure, Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982, -(37), 1982 摘要:Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Substances. For English translation, see TNICS*., 3(81), 1961 摘要:U.S. Environmental Protection Agency. 1998. Extremely Hazardous Substances (EHS) Chemical Profiles and Emergency First Aid Guides. Washington, D.C.: U.S. Government Printing Office.