CAS: 6224-91-5; Trimethyl(Prop-1-Yn-1-yl)Silane

该化合物是有机硅化合物,其特点是有附于丙基乙烯组的硅基化合物;该化合物的特点是三甲基组和三甲基组的硅原子结合物,以及丙基乙烯组,这是一个烷基环,第一个和第二个碳原子之间有三重结合物;该烷基体的出现具有独特的再活动性,使其在各种有机合成应用中有用,特别是在形成碳-碳联结方面. 三甲基-1-丙基-1-硅烷通常是无色液体,具有低沸点,表明其挥发性.该化合物一般在标准条件下稳定,但可能与强力氧化剂发生反应.该化合物经常用于材料科学和有机化学领域,特别是以硅基聚合物合成,并作为交叉反应的试剂.由于易燃性以及与硅化合物相关的潜在健康危害,适当的处理和储存是必不可少的.

英文名称Trimethyl(Prop-1-Yn-1-yl)Silane
中文名称三甲基(丙-1-炔-1-基)硅烷
IUPAC名称trimethyl(prop-1-yn-1-yl)silane
其它别名三甲基硅丙炔; Trimethyl-Prop-1-Ynylsilane
CAS编号6224-91-5
MFCD编号:MFCD00009271
EINECS号:228-314-5
FDA UNII编号:ZQA6VF7W9R
分子式:C6H12Si
分子量:112.24
产品CID: 1604612
产品分类有机原料→分子砌块→脂肪链类化合物

相似结构搜索
产品信息参考
InChIKey: DCGLONGLPGISNX-UHFFFAOYSA-N
InChI=1S/C6H12Si/c1-5-6-7(2,3)4/h1-4H3…
计算化学: 氢键受体数0.0氢键供体数0可旋转键数0

相似化合物

4526-07-2 1066-54-2 2975-46-4

MSDS等安全信息

GHS象形图
GHS符号GHS02 & GHS07;
注释: Flame & Exclamation mark
危险类别易燃液体类别2
特定目标器官毒性 - 单次接触类别3
皮肤腐蚀/刺激类别2
严重眼刺激类别2
严重眼刺激类别2A
警示词Danger(危险)
危险描述H225 |高度易燃液体和蒸气.
H335 |可能引起呼吸道刺激.
H315 |造成皮肤刺激.
H319 |造成严重眼刺激.
防范说明P210-P233-P240-P241-P242-P243-P280-P370+P378-P501
危险等级3
UN编号1993.0
危险品标志F,Xi
包装等级Ⅱ
安全声明16-26-36-37/39
危险类别码11-36/37/38
WGK Germany3

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

合成工艺路线路线简述

合成目标产物 1-(Trimethylsilyl)-1-Propyne 主要起始原料 3-Trimethylsilyl-2-Propyn-1-Ol
6224-91-5 = 6224-91-5
反应条件:1.1 Reagents: Tantalum Pentachloride Solvents: Toluene; 3 H,80 °C1.2 Solvents: Methanol
标题:Chlorination Of Poly[(1-Trimethylsilyl)-1-Propyne] Membrane
作者:Nisoli,Elisabetta; Braglia,Roberto; Castiglioni,Chiara; Meroni,Elvira; Pegoraro,Mario; Et Al
参考文献:Macromolecules 日期:1999 卷标:32(21) 页码:7263-7268]

6224-91-5 = 6224-91-5
反应条件:1.1 Reagents: Tantalum Pentachloride Solvents: Toluene; 24 H,80 °C1.2 Reagents: Methanol,Toluene
标题:Role Of Local Dynamics In The Gas Permeability Of Glassy Substituted Polyacetylenes. A Quasielastic Neutron Scattering Study
作者:Kanaya,Toshiji; Tsukushi,Itaru; Kaji,Keisuke; Sakaguchi,Toshikazu; Kwak,Giseop; Et Al
参考文献:Macromolecules 日期:2002 卷标:35(14) 页码:5559-5564]

1321-74-0 = 6224-91-5
反应条件:1.1 Solvents: Toluene; 15 Min,80 °C1.2 Catalysts: Niobium Pentachloride Solvents: Toluene; 15 Min,80 °C1.3 1 - 1.5 H,80 °C
标题:The Effect Of Chemical Modification On The Chromatographic Properties Of Polymeric Adsorbents Polysorb-1 And Hisep Q And The Diatomite Carrier Chromosorb P Naw
作者:Yakovleva,E. Yu.; Belotserkovskaya,V. Yu.; Fadeeva,V. P.; Litvak,G. S.; Paukshtis,E. A.; Et Al
参考文献:Russian Journal Of Physical Chemistry A 日期:2009 卷标:83(5) 页码:849-853]

6224-91-5 = 6224-91-5
反应条件:1.1 Catalysts: Triisobutylaluminum,Tantalum Pentachloride; 25 °C
标题:Stabilization Of Gas Transport Properties Of Ptmsp With Porous Aromatic Framework: Effect Of Annealing
作者:Volkov,A. V.; Bakhtin,D. S.; Kulikov,L. A.; Terenina,M. V.; Golubev,G. S.; Et Al
参考文献:Journal Of Membrane Science 日期:2016 卷标:517 页码:80-90]

6224-91-5 = 6224-91-5
反应条件:1.1 Catalysts: Triisobutylaluminum,Tantalum Pentachloride Solvents: Toluene; 24 H,25 °C
标题:Phase Equilibrium And Rheology Of Poly(1-Trimethylsilyl-1-Propyne) Solutions
作者:Ilyin,S. O.; Makarova,V. V.; Arinina,M. P.; Litvinova,E. G.; Khotimskii,V. S.; Et Al
参考文献:Polymer Science 日期:2017 卷标:59(1) 页码:1-11]

6224-91-5 = 6224-91-5
反应条件:1.1 Catalysts: Triisobutylaluminum,Tantalum Pentachloride Solvents: Toluene
标题:Improvement Of Mwco Determination By Using Branched Pegs And Maldi Method
作者:Yushkin,Alexey; Borisov,Roman; Volkov,Vladimir; Volkov,Alexey
参考文献:Separation And Purification Technology 日期:2019 卷标:211 页码:108-116]

6224-91-5 = 6224-91-5
反应条件:1.1 Catalysts: Triisobutylaluminum,Tantalum Pentachloride
标题:Synthesis And Properties Of Poly(1-Trimethylsilyl-1-Propyne) Containing Quaternary Ammonium Salts With Methyl And Ethyl Substituents
作者:Polevaya,V. G.; Geiger,V. Yu.; Matson,S. M.; Shandryuk,G. A.; Shishatskii,S. M.; Et Al
参考文献:Polymer Science 日期:2019 卷标:61(5) 页码:613-621]

6224-91-5 = 6224-91-5
反应条件:1.1 Catalysts: Triisobutylaluminum,Tantalum Pentachloride Solvents: Toluene
标题:Aging Of Thin-Film Composite Membranes Based On Crosslinked Ptmsp/pei Loaded With Highly Porous Carbon Nanoparticles Of Infrared Pyrolyzed Polyacrylonitrile
作者:Bakhtin,Danila; Bazhenov,Stepan; Polevaya,Victoria; Grushevenko,Evgenia; Makaev,Sergey; Et Al
参考文献:Membranes (Basel 日期:2020 卷标:10(12)]

6224-91-5 = 6224-91-5
反应条件:1.1 Reagents: Benzoyl Peroxide,N-Bromosuccinimide Solvents: Carbon Tetrachloride; Reflux
标题:Synthesis And Characterization Of Poly[(1-Trimethylsilyl-1-Propyne)-Co-(1-(4-Azidobutyldimethylsilyl)-1-Propyne)] Copolymers
作者:Ruud,Cory J.; Jia,Jingpin; Baker,Gregory L.
参考文献:Macromolecules 日期:2000 卷标:33(22) 页码:8184-8191]

6224-91-5 = 6224-91-5
反应条件:1.1 Catalysts: Tantalum Pentachloride Solvents: Toluene; Reflux
标题:New Sensitive Moisture Getter System By Using Aluminum Complex And Polyacetylene Containing Silyl Group For Display
作者:Kim,Sae-Rom; Kim,Soo-Kang; Ryu,Dong-Wan; Park,Ho-Cheol; Lee,Jae-Hoon; Et Al
参考文献:Journal Of Nanoscience And Nanotechnology 日期:2009 卷标:9(12) 页码:7150-7154]

6224-91-5 = 6224-91-5
反应条件:1.1 Solvents: Carbon Tetrachloride; 48 H,25 °C
标题:Synthesis And Co2 Sorption In Poly(1-Trimethylsilyl-1-Propyne) And Polyvinyltrimethylsilane Containing Ethylene Oxide Groups And N-Butylimidazol-Based "Ionic Liquids " Groups
作者:Kiryukhina,Y. V.; Khotimskiy,V. S.; Tepliakov,V. V.; Roizard,D.; Barth,D.
参考文献:Desalination And Water Treatment 日期:2011 卷标:35(1-3) 页码:255-262]

6224-91-5 = 6224-91-5
反应条件:1.1 Catalysts: Triphenylsilane,Niobium Pentachloride Solvents: Cyclohexane; 24 H,25 °C
标题:Synthesis,Characterization,And Properties Of Poly(1-Trimethylsilyl-1-Propyne)-Block-Poly(4-Methyl-2-Pentyne) Block Copolymers
作者:Sultanov,Eldar Yu.; Ezhov,Alexander A.; Shishatskiy,Sergey M.; Buhr,Kristian; Khotimskiy,Valeriy S.
参考文献:Macromolecules (Washington 日期:2012 卷标:45(3) 页码:1222-1229]

6224-91-5 = 6224-91-5
反应条件:1.1 Catalysts: Triphenylbismuth,Tantalum Pentachloride Solvents: Toluene; 24 H,25 °C1.2 Solvents: Methanol
标题:Synthesis And Properties Of Homo- And Copolymers Of Trifluoropropyldimethylsilyl-1-Propyne With Trimethylsilyl-1-Propyne
作者:Kossov,A. A.; Rebrov,A. V.; Dolzhikova,V. D.; Khotimskii,V. S.
参考文献:Polymer Science 日期:2013 卷标:55(5-6) 页码:258-265]

6224-91-5 = 6224-91-5
反应条件:1.1 Catalysts: Triphenylbismuth,Tantalum Pentachloride Solvents: Toluene; 24 H,25 °C
标题:Study Of Accessible Free Volume And Transport Properties Of Tfps-Co-Tmsp Copolymer
作者:Kossov,A. A.; Yushkin,A. A.; Khotimskiy,V. S.; Volkov,A. V.
参考文献:Petroleum Chemistry 日期:2015 卷标:55(10) 页码:783-790]

6224-91-5 = 6224-91-5
反应条件:1.1 Catalysts: Triisobutylaluminum,Tantalum Pentachloride Solvents: Toluene
标题:Gas Permeability Of Homogeneous And Composite Membranes Based On Poly(Trimethylsilylpropyne)/poly(Vinyltrimethylsilane) Blends
作者:Malakhov,A. O.; Dibrov,G. A.; Litvinova,E. G.; Novitsky,E. G.
参考文献:Petroleum Chemistry 日期:2015 卷标:55(10) 页码:803-809]

6224-91-5 = 6224-91-5
反应条件:1.1 Catalysts: Triisobutylaluminum,Tantalum Pentachloride Solvents: Toluene; 16 H,25 °C
标题:A Novel Hybrid Material Based On Polytrimethylsilylpropyne And Hypercrosslinked Polystyrene For Membrane Gas Separation And Thermopervaporation
作者:Golubev,G. S.; Borisov,I. L.; Litvinova,E. G.; Khotimsky,V. S.; Bakhtin,D. S.; Et Al
参考文献:Petroleum Chemistry 日期:2017 卷标:57(6) 页码:498-510]

6224-91-5 = 6224-91-5
反应条件:1.1 Catalysts: Triisobutylaluminum,Tantalum Pentachloride Solvents: Toluene
标题:Carbon Dioxide Desorption From Amine Solution In A Nonporous Membrane Contactor
作者:Malakhov,A. O.; Bazhenov,S. D.
参考文献:Petroleum Chemistry 日期:2018 卷标:58(4) 页码:330-337]

6224-91-5 = 6224-91-5
反应条件:1.1 Catalysts: Triisobutylaluminum,Tantalum Pentachloride Solvents: Toluene; 25 °C
标题:Evaluation Of Liquid Transport Properties Of Hydrophobic Polymers Of Intrinsic Microporosity By Electrical Resistance Measurement
作者:Yushkin,Alexey; Vasilevsky,Vladimir; Khotimskiy,Valery; Szymczyk,Anthony; Volkov,Alexey
参考文献:Journal Of Membrane Science 日期:2018 卷标:554 页码:346-356

Trimethyl(3-(4,4,5,5-Tetramethyl-1,3,2-Dioxaborolan-2-yl)Prop-1-Yn-1-yl)Silane置于三氟乙酸体系中,用氘代氯仿作为反应溶剂,化学反应 18.0H,以23%的收率获得产物1-(三甲基硅基)丙炔
参考文献:Regioselective Allene Synthesis And Propargylations With Propargyl Diethanolamine Boronates
标题:Regioselective Allene Synthesis And Propargylations With Propargyl Diethanolamine Boronates
摘要:The Utility Of Propargyl Diethanolamine Boronates As Reagents For The Preparation Of Allenes And Homopropargylic Alcohols Is Presented. Protonolysis With Tfa And Electrophilic Substitution With N-Halosuccinimides Proceeded With Inversion To Provide The Corresponding Allene In High Yield And Regioselectivity. Alternatively,The Propargylation Of Aldehydes Was Achieved With Use Of The In Situ Generated Lithiated Complex.
DOI:10.1021/ol9022529

海关参考信息

2901292000-乙炔
💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
详情请参考：📖 海关编码查询和海关进出口税则

专利信息

专利号:US-2007260076-A1
优先权日:2003-12-05
标题:Practical, Cost-Effective Synthesis of Ubiquinones
发明人：LIPSHUTZ BRUCE H; BERL VOLKER; SHEIN KARIN; WETTERICH FRANK
权利人:LIPSHUTZ BRUCE H; BERL VOLKER; SHEIN KARIN; WETTERICH FRANK
摘要:The present invention provides a convergent method for the synthesis of ubiquinones and ubiquinone analogues. Also provided are precursors of ubiquinones and their analogues that are useful in the methods of the invention. The invention further provides an improved method for the carboalumination of alkyne substrates.

专利号:US-5665598-A
优先权日:1994-04-13
标题:Synthesis of chiral N-protected-Î±-substituted-glycine free acids by zinc-mediated addition of organic halide to glycine cation equivalent
发明人：ABOOD NORMAN A; NOSAL ROGER A
权利人:SEARLE & CO
摘要:A method is described for synthesis of N-Boc-L-propargylglycine, a key intermediate used in the preparation of high-potency, orally-active renin inhibitors. This method involves reaction of an organic halide with a glycine cation equivalent, such as methyl N-Boc-2-acetoxyglycine, in the presence of zinc dust to give Boc-protected amino acid derivatives in high yield. Typically useful organic halides are allylic, benzylic and propargylic halides. Resolution of methyl N-Boc-propargylglycine with alpha -chymotrypsin provides N-Boc-L-propargylglycine in high yield.

专利号:US-2011130567-A1
优先权日:2009-06-03
标题 :Steroselective synthesis of certain trifluoromethyl-substituted alcohols
发明人：FANDRICK DANIEL R; REEVES JONATHAN T; SONG JINHUA J; TAN ZHULIN; QU BO; YEE NATHAN K; RODRIGUEZ SONIA
权利人:BOEHRINGER INGELHEIM INT
摘要:A process for stereoselective synthesis of a compound of Formula (X) n n n n n n n n n n wherein:n R 1 is an aryl group substituted with one to three substituent groups,n wherein each substituent group of R 1 is independently C 1 -C 5 alkyl, aminocarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl, halogen, carboxy, cyano, or trifluoromethyl,n wherein each substituent group of R 1 is optionally independently substituted with one to three substituents selected from C 1 -C 3 alkyl, C 1 -C 3 alkoxy, phenyl, and alkoxyphenyl; n n R 2 and R 3 are each independently C 1 -C 5 alkyl; R 4 is C 1 -C 5 alkyl optionally independently substituted with one to three substituent groups,n wherein each substituent group of R 4 is independently C 1 -C 3 alkyl, hydroxy, halogen, amino, or oxo; and n R 5 is a heteroaryl group substituted with one to three substituent groups,n wherein each substituent group of R 5 is independently C 1 -C 5 alkyl, aminocarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl, alkylsulfonylamino, aminosulfonyl, C 1 -C 5 alkylaminosulfonyl, C 1 -C 5 dialkylaminosulfonyl, halogen, hydroxy, carboxy, cyano, trifluoromethyl, trifluoromethoxy, trifluoromethylthio, or C 1 -C 5 alkylthio wherein the sulfur atom is optionally oxidized to a sulfoxide or sulfone.

专利号:US-2011130591-A1
优先权日:2009-06-03
标题:Steroselective synthesis of certain trifluoromethyl-substituted alcohols
发明人：FANDRICK DANIEL R; REEVES JONATHAN T; SONG JINHUA J
权利人:BOEHRINGER INGELHEIM INT
摘要:A process for synthesis of a compound of Formula (X) n n n n n n n n n n wherein:n R 1 is an aryl group substituted with one to three substituent groups,n wherein each substituent group of R 1 is independently C 1 -C 5 alkyl, aminocarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl, halogen, carboxy, cyano, or trifluoromethyl,n wherein each substituent group of R 1 is optionally independently substituted with one to three substituents selected from C 1 -C 3 alkyl, C 1 -C 3 alkoxy, phenyl, and alkoxyphenyl; and n n R 2 and R 3 are each independently C 1 -C 5 alkyl.

专利号:WO-9902264-A1
优先权日:1997-07-11
标题:Membrane and method for synthesis of hydrogen peroxide
发明人：MCINTYRE JAMES A; SANDERS EDGAR S JR; MAHONEY ROBERT D; WEBB STEVEN P; MURCHISON CRAIG B; HAYES DAVID A
权利人:DOW CHEMICAL CO; MCINTYRE JAMES A; SANDERS EDGAR S JR; MAHONEY ROBERT D; WEBB STEVEN P; MURCHISON CRAIG B; HAYES DAVID A
摘要:This invention is a membrane which is useful for the synthesis of hydrogen peroxide from hydrogen and oxygen. The membrane has a hydrogen contact side and an oxygen contact side and comprises a porous hydrophobic catalyst layer facing the oxygen contact side and a gas flux control layer facing the hydrogen contact side. The gas flux control layer is positioned between the hydrogen contact side and the porous hydrophobic catalyst layer such that the flux of hydrogen may be controllably delivered to the porous hydrophobic catalyst layer. The membrane and method may be used to controllably synthesize hydrogen peroxide directly from hydrogen and oxygen without the use of organic solvents or complex equipment for ionic and electrical transport.

专利号:US-9556140-B2
优先权日:2013-01-26
标题 :Approach for synthesis of catechins
发明人：DUGAR SUNDEEP; MAHAJAN DINESH; RAI KUMAR SANTOSH; TRIPATHI VINAYAK; PATIL ISHWAR RAKESH
权利人:SPHAERA PHARMA PRIVATE LTD
摘要:A process for synthesis of enatiomerically pure or enatiomerically enriched or racemic mixture of (+ and/or âˆ’) epicatechin and its intermediates, comprising the steps of: (i) obtaining penta-protected quercetin; (ii) reducing the penta-protected quercetin obtained from step (i); (iii) optionally deprotecting the compound of step (ii); (iv) reducing the compound obtained from step (ii) or step (iii) in the presence of a chiral/achiral reducing agent to obtain a chiral intermediate; (v) deprotecting and/or hydrogenation of the chiral intermediate obtained from step (iv) to obtain (âˆ’)-epicatechin; (vi) optionally simultaneously deprotecting and by drogenation of the compound obtained from step (ii) to obtain racemic epicatechin.

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合成参考文献

摘要:Merino, P., Science of Synthesis, (2010) 45, 316.
摘要:Masuda, T.; Shiotsuki, M.; Sanda, F., Science of Synthesis, (2010) 45, 1435.
摘要:Wang, K. K., Science of Synthesis, (2008) 44, 263.
摘要:Micalizio, G. C., Science of Synthesis Knowledge Updates, (2012) 4, 53.
摘要:Masuda, T.; Shiotsuki, M.; Sanda, F., Science of Synthesis, (2010) 45, 1436.

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CAS: 6224-91-5; Trimethyl(Prop-1-Yn-1-yl)Silane

相似化合物

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