CAS: 78-42-2; Tris(2-Ethylhexyl) Phosphate

相似化合物

4621-50-5 2528-39-4 2528-38-3

上下游产品

CAS号104-76-7 2-乙基己醇 | CAS号301-13-3 亚磷酸三(2-乙基己基)酯 | CAS号298-07-7 二(2-乙基己基)磷酸酯 | CAS号1070-03-7 磷酸-2-乙基己酯

2-乙基己醇置于bis(Acetylacetonate)Nickel(II),Phosphorus,碱性红 1,Potassium Iodide体系中,用 二氯甲烷,甲苯 作为反应溶剂,以77 %的收率获得产物磷酸三辛酯
参考文献:三元光氧化还原/镍/卤化物催化白磷对醇的磷酸化
标题:三元光氧化还原/镍/卤化物催化白磷对醇的磷酸化
摘要:二烷基亚磷酸酯 (Dapi) 是形成磷-碳键和磷-杂原子键的重要前体,具有重要的工业应用.传统的基于 Pcl 3的程序存在高废物产生和有毒反应条件的问题.将白磷 (P 4) 直接转化为 Dapi 可以通过避免使用 Cl 2和 Pcl 3来避免这些问题.我们提出了一种使用 P 4合成 Dapi 的无废物,环保方法和酒精,利用光氧化还原催化剂,镍催化剂和卤化物阴离子的组合.这种光催化方法能够有效地偶联各种醇.有利地,该方法还适用于磷酸三烷基酯和三硫代磷酸三芳基酯的合成.
DOI:10.1021/acscatal.3C01942

专利信息

专利号:US-6184168-B1
优先权日:1997-09-22
标题:Synthesis of 1,4-trans-polybutadiene using a lanthanide organic acid salt catalyst
发明人：LYNCH THOMAS J
权利人:BRIDGESTONE CORP
摘要:The invention provides a catalyst composition, comprising: (a) an organolithium compound; and, (b) an organic acid salt of lanthanide series element; wherein: (1) only components (a) and (b) are required to promote the synthesis of 1,4-trans-polybutadiene; (2) the ratio of component (a) to component (b) is selected to maximize formation of the trans structure of said 1,4-trans-polybutadiene; and, (3) components (a) and (b) are selected for enabling further diblock synthesis. The invention further contemplates a process for using the catalyst to synthesize 1,4-trans-polybutadiene and other polymers and copolymers having trans configuration in the conjugated diene monomer contributed units.

专利号:US-10173993-B2
优先权日:2015-12-09
标题 :Process for the synthesis of sulfones and sulfonamides
发明人：VON WOLFF NIKLAS; CHAR JOËLLE; CANTAT THIBAULT
权利人:COMMISSARIAT ENERGIE ATOMIQUE
摘要:A one pot single step process is described for the synthesis of a compound, including a labeled compound, containing a sulfonyl functional group comprising the step of mixing together a silane, an SO 2 source, an electrophilic compound, an activating compound and optionally a metal catalyst. A process for producing tracers from a labeled sulfonyl containing compound prepared by the described process is also included.

专利号:US-9401507-B2
优先权日:2012-08-07
标题:Methods for the colloidal synthesis of lithium iron phosphate
发明人：PAOLELLA ANDREA; CHANDRAMOHAN GEORGE; PRATO MIRKO; POVIA MAURO; GENOVESE ALESSANDRO; MANNA LIBERATO; CINGOLANI ROBERTO
权利人:FOND ST ITALIANO TECNOLOGIA
摘要:Methods for producing lithium iron phosphate or lithium manganese phosphate or lithium iron manganese phosphate, by colloidal synthesis are provided. Such methods include the operation of reacting a lithium salt, an iron(II) halide (and/or a manganese(II) halide) and a phosphorus compound, which, under the reaction conditions, is capable of releasing the phosphate ion, in the presence of an organic surfactant or a mixture of organic surfactants including an alkylamine or alkenylamine, in which the surfactant or mixture of surfactants is capable of dissolving the lithium salt and the iron halide (and/or the manganese halide), where used, in an organic solvent, which is liquid at room temperature, in which the surfactant or mixture of surfactants is soluble, the reaction being performed at a temperature not lower than 250° C.

专利号:US-8337804-B2
优先权日:2003-04-28
标 题 :Synthesis of nanoparticles comprising metal (III) vanadate
发明人：HEIDELBERG THORSTEN; MEYER CHRISTIANE; KUEHL IMKE
权利人:HEIDELBERG THORSTEN; MEYER CHRISTIANE; KUEHL IMKE; CT FUR ANGEWANDTE NANOTECHNOLOGIE CAN GMBH
摘要:The present invention relates to a method for the production of nanoparticulate metal(III) vanadates or vanadate/phosophate mixed crystals, comprising the reaction in a reaction medium of a reactive vanadate source and optionally a phosphate source dissolvable or dispersible in the reaction medium and of a reactive metal(III) salt dissolvable or dispersible in the reaction medium under heating, wherein the reaction medium contains water and a polyol in a volume ratio of 20/80 to 90/10, and the particles thereby obtained. The synthesis provides a high yield of metal(III) vanadate or vanadate/phosphate having a narrow particle size distribution. Doped embodiments thereof are distinguished by excellent luminescence properties.

专利号:US-2009061230-A1
优先权日:2004-11-02
标题 :Synthesis of Titanium Dioxide Nanoparticles
发明人：BERKEI MICHAEL; BETTENTRUP HELGA
权利人:NANOGATE AG
摘要:The present invention relates to a process for the production of titanium-containing oxide particles having an average primary particle size of 25 nm or less, which comprises the reaction of a hydrolysable halide-containing titanium compound with water in a reaction mixture comprising a polyol, and the particles obtainable thereby. The claimed method is suitable for an industrial upscale and allows the formation of concentrated stable and transparent dispersions in water without the aid of dispersing agents such as surfactants.

专利号:US-8884051-B2
优先权日:2010-10-20
标题:Synthesis of methylene malonates using rapid recovery in the presence of a heat transfer agent
发明人：MALOFSKY BERNARD M; MALOFSKY ADAM G; DEY TANMOY; SULLIVAN JEFFREY M; CHEN YANGBIN; WOJCIAK STANLEY C; COCKREM MICHAEL C
权利人:MALOFSKY BERNARD M; MALOFSKY ADAM G; DEY TANMOY; SULLIVAN JEFFREY M; CHEN YANGBIN; WOJCIAK STANLEY C; COCKREM MICHAEL C; BIOFORMIX INC
摘要:The present invention provides a method of making a methylene malonate monomer that includes the steps of reacting a malonic acid ester with a source of formaldehyde optionally in the presence of an acidic or basic catalyst and optionally in the presence of an acidic or non-acidic solvent to form reaction complex. The reaction is optionally performed in the presence of or contacted with an energy transfer means such as a heat transfer agent, a heat transfer surface, a source of radiation or a laser such that reaction complex is substantially vaporized to produce a vapor phase comprising methylene malonate monomer which may be isolated. The present invention further provides methylene malonate monomers prepared by the method of the invention, as well as compositions and products formed from the methylene malonate monomers, including monomer-based products (e.g., inks, adhesives, coatings, sealants or reactive molding) and polymer-based products (e.g., fibers, films, sheets, medical polymers, composite polymers and surfactants).