CAS: 61272-76-2; 4-Fluoro-2-Iodoaniline

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CAS号371-40-4 4-氟苯胺 | CAS号80087-71-4 6-氟-2-巯基苯并噻唑 | CAS号75893-82-2 6-氟-3,4-二氢喹啉-2(1H)-酮 | CAS号16626-02-1 (S)-2-氨基-3-(5-氟... | CAS号1629-94-3 Benzothiazole,6... | CAS号391-45-7 3-氟咔唑

4-氟苯胺置于碘,碳酸氢钠体系中,用 水,甲苯 作为反应溶剂,化学反应生成 2-碘-4-氟苯胺
参考文献:通过钯(II)催化的杂环和碳环一键式访问苯并[A]咔唑
标题:通过钯(II)催化的杂环和碳环一键式访问苯并[A]咔唑
摘要:通过炔烃的氨基钯催化,然后分子内亲核加成反应生成的碳-钯键到束缚的氰基/醛基上,已经实现了pd(II)催化的苯并[A]咔唑的直接合成.与文献方法相比,这种合成方法操作简单,使用简单的底物,并提供了快速的分子内组装,可直接合成苯并[A]咔唑,其中不同位置的取代基耐受性广,足以保留足够的余量.多元化的机会.
DOI:10.1021/acs.Joc.6B02022

专利信息

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