CAS: 55-97-0; N1,N1,N1,N6,N6,N6-Hexamethylhexane-1,6-Diaminium Bromide

该化合物是一种四硝基铵化合物,其特征是用作药理学中的混合阻塞剂;它是在水中溶解的白的,白的,脱白的晶状的粉末,由于存在溴离子,表现出强烈的离子性;该化合物的主要作用是抑制...

⚠️《化妆品禁用原料目录》
英文名称N1,N1,N1,N6,N6,N6-Hexamethylhexane-1,6-Diaminium Bromide
中文名称溴化六甲铵
IUPAC名称N1,N1,N1,N6,N6,N6-hexamethylhexane-1,6-diaminium bromide
其它别名六甲溴铵; 溴化六烃季铵; 溴化己烷双铵; 溴化六甲铵; 溴化六甲双铵
CAS编号55-97-0
MFCD编号:MFCD00011787
EINECS号:200-249-7
FDA UNII编号:8J77X3S603
分子式:C12H30Br2N2
分子量:362.19
产品CID: 1531868
同类组份化合物CAS60-26-4 (cation)55-97-0 (bromide)5187-74-6 (bromide dihydrate)60-25-3 (chloride)16986-49-5 (chloride dihydrate)815-76-9 (monotartrate)2079-78-9 (tartrate)
产品分类有机原料→通用试剂→各类元素及其盐→铵盐

相似结构搜索
InChIKey: FAPSXSAPXXJTOU-UHFFFAOYSA-L
InChI=1S/C12H30N2.2BrH/c1-13(2,3)11-9-7-8-10-12-14(4,5)6;;/h7-12H2,1-6H3;2*1H/q+2;;/p-2…
计算化学: 氢键受体数0.0氢键供体数0.0可旋转键数7.0

相似化合物

541-22-0 2650-53-5 1120-02-1

物理性质

熔点-285 °C
沸点-285 °C
PH:pH (20g/l, 25°C) : 4.5～6.5
PSA:0.0
LogP:-4.0328
溶解性Water (Slightly)
外观形态白色结晶粉末和附聚物
储存条件2-8°C, sealed storage, away from moisture
产品应用该化合物用作乙酰碱酶活性弱抑制剂.

MSDS等安全信息

GHS象形图
GHS符号GHS08;
注释: Health hazard
危险类别特定目标器官毒性-单次接触类别1
警示词Danger(危险)
危险描述H370 |损害器官.
防范说明P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501
UN编号NONH for all modes of transport
危险品标志Xn
安全声明S22-S24/25
WGK Germany2

欧盟法规

REACH注册ECHA物质ECHA物质化妆品禁用物质清单C&L通报REACH预注册

上下游产品

合成工艺路线路线简述

1,6-二溴己烷,三甲胺置于乙酸乙酯,乙醚体系中,用乙醇作为反应溶剂,化学反应 60.0H,反应生成溴化六甲铵
参考文献:Porous Crystalline Material (Zeolite Itq-24),Preparation Method Thereof And Use Of Same In The Catalytic Conversion Of Organic Compounds
标题:Porous Crystalline Material (Zeolite Itq-24),Preparation Method Thereof And Use Of Same In The Catalytic Conversion Of Organic Compounds
摘要:该发明涉及一种多孔晶体材料(itq-24),其制备方法以及在有机化合物催化转化中的应用.更具体地说,该发明涉及一种合成的多孔晶体材料,其特点在于由四面体配位的原子通过氧相互连接而成.该材料包含一个单元晶胞,其中包含56个四面体配位的原子,被称为itq-24.此外,在煅烧无水状态下,该材料的化学式为nm1/pxo2:Yo2,其中:X至少是一种三价元素,Y至少是一种四价元素,N在0至0.2之间,M是至少一种在氧化态p下的电荷补偿阳离子.

海关参考信息

2921199090-其他无环单胺
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专利信息

专利号:US-6723300-B2
优先权日:2002-03-15
标题 :Synthesis of porous crystalline materials in fluoride media
发明人：SCHMITT KIRK D; CASMER STEPHEN G
权利人:EXXONMOBIL RES & ENG CO
摘要:In a process for synthesizing a porous crystalline material, a mixture capable of forming said material is prepared wherein the mixture comprises sources of water, an oxide of a tetravalent element Y, preferably silicon, an oxide of a trivalent element X, wherein X is selected from the group consisting of aluminum, boron, gallium, iron, and indium, fluoride ions, and an organonitrogen cation RN capable of directing the synthesis of said material, wherein the molar ratio of fluoride ions to organonitrogen cations RN in said mixture is greater than 1.15 m but less than 2.5 m. The mixture is maintained under crystallization conditions until crystals of said material are formed and the resultant crystalline material is recovered.

专利号:US-10301185-B2
优先权日:2014-10-15
标题:Solidothermal synthesis of zeolitic materials and zeolites obtained therefrom
发明人：MAURER STEFAN; MÃ¼ller Ulrich; XIAO FENG-SHOU; MENG XIANGJU; WU QINMING
权利人:BASF SE
摘要:The present invention relates to a process for the preparation of a zeolitic material comprising YO 2 in its framework structure, wherein Y stands for a tetravalent element, wherein said process comprises the steps of:n (1) providing a mixture comprising one or more sources for YO 2 , one or more fluoride containing compounds, and one or more structure directing agents; (2) crystallizing the mixture obtained in step (1) for obtaining a zeolitic material comprising YO 2 in its framework structure;n nwherein the mixture provided in step (1) and crystallized in step (2) contains 35 wt.-% or less of H 2 O based on 100 wt.-% of YO 2 contained in the mixture provided in step (1) and crystallized in step (2), as well as to a zeolitic material comprising YO 2 in its framework structure obtainable and/or obtained according to said process, and to a zeolitic material per se comprising SiO 2 in its framework structure, wherein in the 29 Si MAS NMR spectrum of the as-synthesized zeolitic material the ratio of the total integration value of the peaks associated to Q3 signals to the total integration value of the peaks associated to Q4 signals is in the range of from 0:100 to 20:80, including the use of the aforementioned zeolitic materials.

专利号:US-12434975-B2
优先权日:2023-01-11
标题 :Method for manufacture of pure silica zeolites in the presence of ODSO
发明人：HODGKINS ROBERT PETER; KOSEOGLU OMER REFA; MARTINEZ JAVIER RUIZ; ZAAROUR MOUSSA
权利人:SAUDI ARABIAN OIL CO
摘要:The present disclosure is directed to a method to synthesize pure silica zeolites. This is accomplished by using an improved sol-gel formulation including a water-soluble fraction of ODSO as an additional component together with precursors and reagents effective for synthesis of pure silica zeolite.

专利号:US-6616910-B2
优先权日:2000-05-05
标题 :Process for preparation of an EUO-structural-type zeolite, the zeolite that is obtained and its use as catalyst for isomerization of C8-aromatic compounds
发明人：ROULEAU LOIC; KOLENDA FREDERIC; MERLEN ELISABETH; ALARIO FABIO
权利人:INST FRANCAIS DU PETROLE
摘要:This invention relates to a process for synthesis of an EUO-structural-type zeolite that comprises at least one element X that is selected from among silicon and germanium and at least one element T that is selected from among aluminum, iron, gallium, boron, titanium, vanadium, zirconium, molybdenum, arsenic, antimony, chromium and manganese, whereby said process is carried out in the presence of an organic structuring agent that is derived from dibenzyldimethylammonium (DBDMA) or its precursors and in the presence of nuclei of at least one zeolitic material of the same structure as the zeolite that is to be synthesized. The zeolite that is thus obtained has an X/T ratio of between 5 and 50. It is used in particular as a catalyst, for example in a process for isomerization of aromatic compounds with 8 carbon atoms per molecule.

专利号:US-2024101435-A1
优先权日:2021-03-03
标题:Method of Synthesizing a Molecular Sieve of MWW Framework Type
发明人：SARTIPI SINA; ANTHONIS MARC H; PETERS AARON W; WEIGEL SCOTT J
权利人:EXXONMOBIL CHEMICAL PATENTS INC
摘要:Disclosed is a method of synthesizing a molecular sieve of MWW framework type, and molecular sieves so synthesized. The method comprises preparing a synthesis mixture for forming a molecular sieve of MWW framework type, said synthesis mixture comprising water, a silicon source, a source of a trivalent element X, a structure directing agent R, a source of alkali or alkaline earth metal cation M, and a source of poly(diallyldimethyl ammonium) cation (PDDA).

专利号:US-2023264965-A1
优先权日:2020-07-16
标题:Method of Synthesizing a Molecular Sieve of MWW Framework Type
发明人：SARTIPI SINA; ANTHONIS MARC H; PETERS AARON W; AKOUCHE MARIAME
权利人:EXXONMOBIL CHEMICAL PATENTS INC
摘要:Disclosed is a method of synthesizing a molecular sieve of MWW framework type, and molecular sieves so synthesized. The method comprises preparing a synthesis mixture for forming a molecular sieve of MWW framework type, said synthesis mixture comprising water, a silicon source, a source of a trivalent element X, a potassium cation source, a structure directing agent R, and a source of another alkali metal cation M.

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主要参考文献

1: AUBERT H, GAVRILESCU S. [Hexamethonium bromide in therapy of some cardiovascular diseases]. Med Interna (Bucur). 1956 Dec;8(8):1182-9. Romanian. doi: 10.1139/cjpp-2013-0413. Epub 2014 Apr 3. Romanian.
8: Bříza T, Králová J, Dolenský B, Rimpelová S, Kejík Z, Ruml T, Hajdúch M, Džubák P, Mikula I, Martásek P, Poučková P, Král V. Striking antitumor activity of a methinium system with incorporated quinoxaline unit obtained by spontaneous cyclization. Chembiochem. 2015 Mar 2;16(4):555-8. doi: 10.1002/cbic.201402662. Epub 2015 Jan 28.
10: STORSTEIN O, TVETEN H. The effect of hexamethonium bromide on the pulmonary circulation. Scand J Clin Lab Invest. 1954;6(3):169-77. Undetermined Language. Lancet. 1952 Nov 22;2(6743):1002-5. Harefuah. 1953 Sep 15;45(6):126-7. doi: 10.1007/s11011-013-9458-3. Epub 2013 Dec 10.

合成参考文献

参考文献:10.1016/j.bbrc.2023.08.050
摘要:Ikeda Y, Davis MI, Sumita K, Zheng Y, Kofuji S, Sasaki M, Hirota Y, Pragani R, Shen M, Boxer MB, Takeuchi K, Senda T, Simeonov A, Sasaki AT. Multimodal action of KRP203 on phosphoinositide kinases in vitro and in cells. Biochemical and Biophysical Research Communications. 2023 Oct;679():116–21. doi: 10.1016/j.bbrc.2023.08.050.

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CAS: 55-97-0; N1,N1,N1,N6,N6,N6-Hexamethylhexane-1,6-Diaminium Bromide

该化合物是一种四硝基铵化合物,其特征是用作药理学中的混合阻塞剂;它是在水中溶解的白的,白的,脱白的晶状的粉末,由于存在溴离子,表现出强烈的离子性;该化合物的主要作用是抑制...

相似化合物

物理性质

MSDS等安全信息

欧盟法规

上下游产品

合成工艺路线路线简述

海关参考信息

专利信息

其他信息查阅

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品牌试剂参考报价(招募中)

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主要参考文献

合成参考文献

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