CAS: 1031-07-8; Endosulfan Sulfate

该化合物是一种化学化合物,是硫丹农药的代谢物,其特点是硫丹在环境中的稳定性和持久性,引起人们对硫丹生态影响的关切;该化合物是一种硫酸盐衍生物,由有助于其在水中溶解的磺酸盐组组成;硫丹硫酸盐以其对水生有机物的潜在毒性而闻名,并涉及各种环境和健康问题;该化合物表现出中度至高度的生物累积性,可导致食物链中的不利影响;该化合物通常存在于农业径流中,并可在土壤和水系统中持久存在,因此受到监管审查;该化合物的化学结构包括一个双环系统,负责其杀虫特性;由于其环境持久性和毒性,许多国家限制或禁止在农业实践中使用硫丹及其代谢物,包括硫丹硫酸盐.

英文名称Endosulfan Sulfate
中文名称硫丹硫酸酯
IUPAC名称1,9,10,11,12,12-hexachloro-4,6-dioxa-5λ6-thiatricyclo[7.2.1.02,8]dodec-10-ene 5,5-dioxide
其它别名5-Norbornene-2,3-dimethanol,1,4,5,6,7,7-hexachloro-, cyclic sulfate (7CI,8CI); 1,4,5,6,7,7-Hexachloro-5-norbornene-2,3-dimethanol cyclic sulfate; 6,7,8,9,10,10-Hexachloro-1,5,5a,6,9,9a-hexahydro-6,9-methano-2,4,3-benzodioxathiepin3,6-dioxide; Benzoepin sulfate; Endosulfan III; Endosulfan cyclic sulfate; Endosulfan sulfate; Endosulfate; Thiodan sulfate
CAS编号1031-07-8
MFCD编号:MFCD00151179
EINECS号:623-765-8
FDA UNII编号:8QTV9M19B2
分子式:C9H6Cl6O4S
分子量:422.92
产品CID: 64564
产品分类有机原料 → 无机酸酯

相似结构搜索
InChIKey: AAPVQEMYVNZIOO-UHFFFAOYNA-N
InChI=1/C9H6Cl6O4S/c10-5-6(11)8(13)4-2-19-20(16,17)18-1-3(4)7(5,12)9(8,14)15/h3-4H,1-2H2…
计算化学: 氢键受体数4.0氢键供体数0.0可旋转键数0.0

物理性质

熔点181 °C
沸点480.7±45.0 °C at 760 mmHg
闪点244.5±28.7 °C
密度1.9±0.1 g/cm3
PSA:60.98
LogP:4.3
折射率1.638
蒸汽压0.0±1.2 mmHg at 25°C
溶解性DMSO: Slightly Soluble,Methanol: Slightly Soluble
敏感性ENDOSULFAN SULFATE is an organochlorine and cycloalkene. It is also a sulfate ester. Corrosive to iron. It can be hydrolyzed by aqueous alkali or acid, generating sulfur dioxide. Incompatible with strong oxidizing and reducing agents. Also incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides. As an ester, it will hydrolyze to form sulfur dioxide and diol; reaction is more rapid under basic conditions.
外观形态透明无色液体
储存条件< 4°C
产品应用该化合物用于控制和保护植物和植被的农药.

MSDS等安全信息

GHS象形图
GHS符号GHS06 & GHS09;
注释: Skull and crossbones & Environment
危险类别急性毒性类别2(吸入)
急性毒性类别2(经皮)
急性毒性类别2(经口)
水生急性毒性类别1
水生慢性毒性类别1
警示词Danger(危险)
危险描述H330 |吸入致命.
H310 |皮肤接触致命.
H300 |吞咽致命.
H400 |对水生生物毒性极大.
H410 |对水生生物毒性极大并具有长期持续影响.
防范说明P260-P262-P273-P280-P302+P352+P310-P304+P340+P310
危险等级6.1(a)
UN编号2761.0
危险品标志T+,N,Xn,F,T
包装等级II
安全声明22-24/25-45-60-61-62-36/37-16-7-33-29-9
危险类别码28-50/53-67-65-62-51/53-48/20-38-11-39/23/24/25-23/24/25
WGK Germany3

欧盟法规

[ECHA物质

上下游产品

α-Endosulfan

合成工艺路线路线简述

硫丹反应生成硫丹硫酸酯
参考文献:Naqvi,Syed M.;Newton,Deborah J.,J. Environ. Sci. And Health. B,25,(1990) N,C. 511-526
标题:Naqvi,Syed M.;Newton,Deborah J.,J. Environ. Sci. And Health. B,25,(1990) N,C. 511-526

海关参考信息

2905399002-1,4-丁二醇
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详情请参考：📖 海关编码查询和海关进出口税则

专利信息

专利号:US-9700872-B1
优先权日:2016-07-01
标题:Superpolar chromatographic stationary phases and extraction sorbents and their methods of synthesis
发明人：KABIR ABUZAR; FURTON KENNETH G
权利人:KABIR ABUZAR; FURTON KENNETH G; UNIV FLORIDA INT
摘要:A superpolar sorbent network is a sol-gel network of at least one metal oxide precursor condensed and at least one polyhydroxy molecule. The metal oxide precursor is a silicate precursor, aluminate precursor, titanate precursor, zirconate precursor, germinate precursor, or any combinations thereof, and the polyhydroxy molecule has a multiplicity of hydroxyl groups. The polyhydroxy molecule can be an organic molecule derived from nature. The superpolar sorbent network can be used as a particulate or bulk sorbent for sampling or removal of analytes or contaminants from an environment or can be coated on a tube or particulate substrate for use as a chromatographic stationary phase.

专利号:CN-114196097-B
优先权日:2022-01-29
标题:A kind of regenerated wooden sponge for hydroponic planting and its synthesis method