CAS: 4894-75-1; 4-Phenylcyclohexanone

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CAS号5769-13-1 (1r,4r)-4-苯基环己醇 | CAS号4500-20-3 4-苯基环己酮肟 | CAS号25163-93-3 8-苯基-1,4-二氧杂螺[4,5]癸烷 | CAS号81929-32-0 4-phenylcyclohe... | CAS号108-86-1 溴苯 | CAS号22460-52-2 4-溴环己酮 | CAS号86724-17-6 4-methyl-N'-(4-... | CAS号250293-45-9 4-Phenylcyclohe... | CAS号1064664-58-9 9-phenyl-1,5-di... | CAS号1031336-60-3 ABT-046 | CAS号103012-26-6 3-苯基-9H-咔唑 | CAS号106592-05-6 8-phenyl-1,4-di... | CAS号1079-68-1 2-溴-4-苯基环己酮 | CAS号32228-99-2 N-苯基-4-联苯胺 | CAS号1466-74-6 4-苯基环己烷甲醛 | CAS号147356-80-7 (4-cyclopropyli... | CAS号4994-16-5 4-苯基-1-环己烯 | CAS号92-69-3 4-苯基苯酚 | CAS号827-52-1 环己基苯

苯硼酸频哪醇酯置于tetrakis(Actonitrile)Copper(I) Hexafluorophosphate,2-Phenyl-2-(Triethylsilyldioxy)Propane,三乙胺体系中,用 四氢呋喃,二甲基亚砜 作为反应溶剂,化学反应 2.0H,反应生成 4-苯基环己酮
参考文献:结合卤素原子转移 (Xat) 和铜催化用于烷基碘和有机硼的模块化 Suzuki-Miyaura 型交叉偶联
标题:结合卤素原子转移 (Xat) 和铜催化用于烷基碘和有机硼的模块化 Suzuki-Miyaura 型交叉偶联
摘要:我们在这里报告了一种机制上不同的方法来实现烷基碘和芳基有机硼之间的 Suzuki-Miyaura 型交叉偶联.该过程需要铜催化剂,但与以前基于钯和镍系统的方法相比,它不使用金属来活化烷基亲电试剂.相反,该策略利用 α-氨基烷基自由基的卤素原子转移能力将仲烷基碘转化为相应的烷基自由基,然后与芳基,乙烯基,炔基,苄基和硼酸烯丙酯物质偶联.这些新颖的偶联反应具有简单的设置和条件(室温下 1 小时),并有助于获得制药行业所针对的特权基序.
DOI:10.1021/jacs.1C12649

专利信息

专利号:US-5932743-A
优先权日:1997-08-21
标 题:Methods for the solid phase synthesis of substituted indole compounds
发明人：COLLINI MICHAEL D; ELLINGBOE JOHN W
权利人:AMERICAN HOME PROD
摘要:The present invention relates to novel substituted indole compounds of formula (I) having pharmacological activity, to processes for their preparation, to solid phase methods for preparing libraries of the compounds, to utilizing libraries of the compounds for drug discovery, and to pharmaceutical compositions thereof.

专利号:US-4788367-A
优先权日:1987-11-05
标题 :Synthesis of olefins from ketones using bis(alkylchloroalumino)methane
发明人：PIOTROWSKI ANDRZEJ M; MALPASS DENNIS B
权利人:TEXAS ALKYLS INC
摘要:Ketones are methylenated to form the corresponding olefin by reaction with a bis(alkylchloroalumino)methane, e.g., in the form of its dietherate.

专利号:WO-9909007-A1
优先权日:1997-08-21
标题:Solid phase synthesis of 2,3-disubstituted indole compounds
发明人：COLLINI MICHAEL DAVID; ELLINGBOE JOHN WATSON
权利人:AMERICAN HOME PROD
摘要:The present invention relates to novel substituted indole compounds of formula (I) having pharmacological activity, to processes for their preparation, to a combinatorial library and solid phase methods for preparing libraries of the compounds, to utilizing libraries of the compounds for drug discovery, and to pharmaceutical compositions thereof.

专利号:US-4849574-A
优先权日:1987-11-05
标 题:Synthesis of olefins from ketones or aldehydes using bis(alkylchloroalumino)methane
发明人：PIOTROWSKI ANDRZEJ M; MALPASS DENNIS B
权利人:TEXAS ALKYLS INC
摘要:Ketones or aldehydes are methylenated to form the corresponding olefin by reaction with a bis(alkylchloroalumino)methane, e.g., in the form of its dietherate.

专利号:US-6177594-B1
优先权日:1996-07-03
标题:4-(4-oxocyclohexyl) benzamides as intermediate products for medicaments
发明人：WAECHTLER ANDREAS; STERN MARGIT; REIFFENRATH VOLKER
权利人:MERCK PATENT GMBH
摘要:Benzamides of the formula I:whereinR1 and R2 independently of one another are each alkyl having 1-6 C atoms, orR1 and R2 together are alkylene,and their salts,are suitable as intermediates in the synthesis of drugs.

专利号:US-7687635-B2
优先权日:2002-01-22
标 题:Metal complexes useful in metathesis and other reactions
发明人：VERPOORT FRANCIS WALTER CORNELIUS; DE CLERCQ BOB
权利人:TELENE S A S
摘要:This invention provides metal complexes being useful as catalyst components in metathesis reactions and in reactions involving the transfer of an atom or group to an ethylenically or acetylenically unsaturated compound or another reactive substrate and, with respect to a sub-class thereof, for the polymerisation of α-olefins and optionally conjugated dienes, with high activity at moderate tempera-tures. It also provides methods for obtaining polymers with very narrow molecular weight distribution by means of a living reaction. It also provides methods for making said metal complexes and novel intermediates involved in such methods. It further provides derivatives of said metal complexes which are suitable for covalent bonding to a carrier, the product of such covalent bonding being useful as a supported catalyst for heterogeneous catalytic reactions. It also provides a direct one-step synthesis of pyrrole, furan and thiophene compounds from diallyl compounds.