CAS: 188-94-3; Diindeno[1,2,3-Cd:1',2',3'-Lm]Perylene

上下游产品

CAS号206-44-0 荧蒽 | CAS号198-55-0 苝 | CAS号71-43-2 苯

荧蒽置于sodium Amide体系中,用 N,N-二甲基乙酰胺 用作溶剂,化学反应 10.0H,以46.7%的收率获得二茚并
参考文献:一种二茚并苝的合成方法
标题:一种二茚并苝的合成方法
摘要:本发明公开了一种二茚并苝的合成方法,包括如下步骤:将荧蒽,氨基钠和有机溶剂加入反应容器中,向反应容器中充入惰性气体,然后加热以进行合成反应得到含二茚并苝的混合溶液;将含二茚并苝的混合溶液冷却后,滴加无水乙醇,再滴加水,过滤得到二茚并苝粗品.本发明与现有技术相比,具有如下有益效果:本发明的反应路线原料易得,成本低,收率高,工艺要求低,操作简单,反应过程及后处理安全,而且易于纯化,利于工业化生产.

专利信息

专利号:US-11744150-B2
优先权日:2012-01-20
标 题:Synthesis of aza-acenes as novel n-type materials for organic electronics
发明人：THOMPSON MARK E; SOMMER JONATHAN R; BARTYNSKI ANDREW
权利人:UNIV SOUTHERN CALIFORNIA
摘要:Acenes, such as aza-acenes are attractive materials for organic semiconductors, specifically for n-type materials. There are disclosed new derivatives of acenes that are fabricated using novel synthesis. For example, the disclosed fabrication strategies have allowed for the first time new aza-tetracene and aza-pentacene derivatives. The HOMO and LUMO energy levels of these materials are tunable through appropriate substitution and as predicted, deepened. There are also disclosed organic photosensitive devices comprising at least one aza-acene such as aza-tetracene and aza-pentacene.

专利号:US-7368624-B2
优先权日:2004-03-30
标 题 :Synthesis for polycyclic aromatic hydrocarbon compounds
发明人：BROWN CHRISTOPHER T; SHUKLA DEEPAK; DOCKERY KEVIN P; LENHARD JEROME R; MATZ JAMES R
权利人:EASTMAN KODAK CO
摘要:A process for forming an aryl-aryl bond comprises the step of reacting an arene hydrocarbon compound with either (1) an organic oxidant selected from the group consisting of a quinone, a quinone imine, a quinone diimine, and a nitroarene, or (2) an oxidizing salt selected from the group consisting of a triarylaminium salt, an oxonium salt, and a nitrosium salt, or (3) a hypervalent iodine compound, each in the presence of a Brönsted or Lewis acid.

专利号:US-7732652-B2
优先权日:2001-07-04
标题 :Perylene derivative synthesis process, perylene derivative and organic EL device
发明人：FUJITA TETSUJI; ARA KENSUKE; INOUE TETSUSHI
权利人:TDK CORP
摘要:The invention aims to provide a perylene derivative preparation process featuring satisfactory yields and improved preparation efficiency, a perylene derivative obtained by the process, and an organic EL device using the same. The object is achieved by a perylene derivative preparation process comprising subjecting to coupling reaction a 1,8-dihalogenated naphthalene derivative of the formula (1): n nwherein X is Cl, Br or I, R 1 to R 4 , R 11 and R 12 each are hydrogen, alkyl, alkoxy, alkylthio, alkenyl, alkenyloxy, alkenylthio, aralkyl, aralkyloxy, aralkylthio, aryl, aryloxy, and arylthio radicals which may be substituted, amino radical, cyano radical, hydroxyl radical, —COOM 1 radical (wherein M 1 is hydrogen, alkyl, alkenyl, aralkyl or aryl), —COM 2 radical (wherein M 2 is hydrogen, alkyl, alkenyl, aralkyl, aryl or amino), or —OCOM 3 radical (wherein M 3 is alkyl, alkenyl, aralkyl or aryl), and at least two adjoining radicals selected from among R 1 to R 4 , R 11 and R 12 may bond or fuse together to form a substituted or unsubstituted carbocyclic aliphatic ring, aromatic ring or fused aromatic ring with the carbon atoms on which they substitute, with the proviso that when the carbocyclic aliphatic ring, aromatic ring or fused aromatic ring has substituent radicals, the substituent radicals are the same as R 1 to R 4 , R 11 and R 12 , to thereby synthesize a perylene derivative of the formula (2):n n nwherein R 1 ′ to R 4 ′, R 11 ′ and R 12 ′ are as defined for R 1 to R 4 , R 11 and R 12 in formula (1), and R 1 to R 4 , R 11 and R 12 and R 1 ′ to R 4 ′, R 11 ′ and R 12 ′ may be the same or different.

专利号:CN-104364925-A
优先权日:2012-01-20
标 题:Synthesis of aza-acenes as novel N-type materials for organic electronics

专利号:CA-2860919-A1
优先权日:2012-01-20
标题 :Synthesis of aza-acenes as novel n-type materials for organic electronics

专利号:US-2021313517-A1
优先权日:2012-01-20
标题:Synthesis of aza-acenes as novel n-type materials for organic electronics