CAS: 110-05-4; Di-Tert-Butyl Peroxide

上下游产品

tert.-butylhydroperoxide tert-butyl hydrogen sulfate Isobutane tert-butyl alcoholtert-butyl alcoholmethane ethane ethene acetone

叔丁醇置于c74H26F20N6O2S4体系中,化学反应生成二叔丁基过氧化物
参考文献:嵌入二噻吩并吡咯核心的 32 和 34π 八菲林的模板辅助形成:解开质子耦合氧化还原开关和(反)芳香性的新支架
标题:嵌入二噻吩并吡咯核心的 32 和 34π 八菲林的模板辅助形成:解开质子耦合氧化还原开关和(反)芳香性的新支架
摘要:嵌入二噻吩并[3,2-B :2',3'-D ]吡咯的四重内消旋取代的32π反芳香族八菲林1经历容易的质子耦合电子转移(Pcet)至其34π芳香族同系物h21 . 2H + .即使存在弱酸以及醇和胺等小有机分子,这种转化也是有效的.稳定的芳香族游离碱h21表现出近平面构象,可对氟离子和氢氧根阴离子进行比色传感.
Doi:10.1002/chem.202303326

专利信息

专利号:US-12410140-B2
优先权日:2020-06-19
标题:Method for synthesis of roxadustat and intermediate thereof, and intermediate thereof
发明人：ZHANG YONG; WANG GUO; YANG FEI; LIU FENGWEI; ZHOU CHUNDONG; ZHANG ZITONG
权利人:JUMPCAN SHANGHAI MEDICAL TECH CO LTD
摘要:Disclosed are a method for the synthesis of roxadustat and an intermediate thereof, and an intermediate thereof. In particular, disclosed is a method for the synthesis of compound M1, the method comprising the following steps: carrying out a reaction as shown below between compound SM and compound SM-A under the action of an oxidizing agent. The method of the present invention uses cheap and easily available raw materials, has short reaction steps, produces a high yield, has simple and convenient post-treatment procedures, and is suitable for industrial production.

专利号:US-9969823-B1
优先权日:2011-09-01
标题 :Synthesis and polymerization of vinyl triazolium ionic liquids
发明人：LUEBKE DAVID; NULWALA HUNAID; MATYJASZEWSKI KRZYSZTOF; ADZIMA BRIAN
权利人:US ENERGY; THE US DEPARTMENT OF ENERGY
摘要:Herein, we describe polymerized ionic liquids, demonstrate the synthesis of polymerized ionic liquids, and demonstrate the polymerization of triazolium monomers. One embodiment shows the polymeriazation of the triazolium monomers with bis(trifluoromethanesulfonyl)imide anions. In another embodiment we show the feasibility of copolymerizing with commodity monomers such as styrene using free radical polymerization techniques.

专利号:WO-9714703-A1
优先权日:1995-10-16
标 题:Synthesis of polymerisable phosphodiesters
发明人：DRIVER MICHAEL JOHN; RUSSEL JEREMY COLIN; BROWNE JUDITH ELIZABETH; SAMMES PETER G
权利人:BIOCOMPATIBLES LTD; DRIVER MICHAEL JOHN; RUSSEL JEREMY COLIN; BROWNE JUDITH ELIZABETH; SAMMES PETER G
摘要:A mono- or di-functional phosphoramidite phosphitylating agent is used to phosphitylate an ethylenically unsaturated alcohol. The product may be oxidised to form the corresponding phosphate ester which may be reacted in further steps to form phosphoryl choline derivatives. The process is of value in the synthesis of 2-(Methacryloyloxyethyl)-2'-(trimethylammoniumethyl)phosphate, inner salt. It has the advantage over prior art processes in that the starting materials and intermediates are more stable and consequently easier to handle.

专利号:US-9079824-B2
优先权日:2010-07-06
标 题:Method for the synthesis of an amino acetal
发明人：LOH TECK PENG; TIAN JIESHENG
权利人:LOH TECK PENG; TIAN JIESHENG; UNIV NANYANG TECH
摘要:The present invention relates to a method for the synthesis of an α amino acetal, comprising (i) oxidizing a tertiary amine in the presence of a copper catalyst, at least one oxidant and a solvent, or (ii) reacting a secondary amine and an aliphatic aldehyde in the presence of a copper catalyst, at least one oxidant and a solvent.

专利号:US-9394394-B2
优先权日:2013-09-30
标题:Synthesis of chlorotrifluoroethylene-based block copolymers by iodine transfer polymerization
发明人：THENAPPAN ALAGAPPAN; AMEDURI BRUNO; LOPEZ GERALD
权利人:HONEYWELL INT INC
摘要:Methods for the synthesis of CTFE-based block copolymers through iodine transfer polymerization are disclosed. In an exemplary embodiment, a method includes reacting a fluoromonomer “Mâ€? with a chain transfer agent of the formula X—Y or Y—X—Y, wherein X represents a C 1 -C 3 hydrocarbon, a C 1 -C 6 hydrofluorocarbon, C 1 -C 6 hydrochlorofluorocarbon, or C 1 -C 6 fluorocarbon and Y represents iodine or bromine, in the presence of a radical initiator, to form a macro-initiator of the formula: X-poly(M)-Y or Y-poly(M)-X-poly(M)-Y, wherein poly(M) represents a polymer of the fluoromonomer. The method further includes reacting the macro-initiator with chlorotrifluoroethylene (CTFE) in the presence of a radical initiator to form a diblock or a triblock CTFE-based block copolymer of the formula: X-poly(M)-block-poly(CTFE) or PCTFE-block-poly(M)-X-poly(M)-block-PCTFE.

专利号:US-RE48674-E
优先权日:2010-07-07
标题 :Method for the synthesis of 5-amino-1-phenyl-3-cyano-4-trifluoromethyl sulfinyl
发明人：PASTORIO ANDREA; BETTI PAOLO
权利人:PASTORIO ANDREA; BETTI PAOLO; FINCHIMICA SRL
摘要:The present invention relates to a method for the preparation of the 5-amino-1-phenyl-3-cyano-4-trifluoromethyl sulfinyl pyrazole having the described general formula (I), particularly preferred for the synthesis of Fipronil I, through oxidation of a compound having the general formula (II) as follows:wherein R1 and R2 are independently hydrogen or halogen, and wherein the oxidizing agent is dichloroperacetic acid.