专利号:US-6512081-B1 优先权日:1997-07-21 标题:Synthesis of dithioester chain transfer agents and use of bis(thioacyl) disulfides or dithioesters as chain transfer agents 发明人:RIZZARDO ENZIO; THANG SAN HOA; MOAD GRAEME 权利人:E I DUPONT NEMOURS AND COMPANY; COMMW SCIENT IND RES ORG 摘要:This invention relates to the synthesis of dithiocarboxylic acid esters by reaction of bis(thioacyl) disulphides, thioacetals or vinylidane bis(thioether) with free-radicals (optionally in the presence of monomers). The invention also relates to processes for the synthesis of polymers utilising these dithioesters as polymerisation regulators (chain transfer agents) or to the use of bis(thioacyl) disulphides to generate dithioester chain transfer agents in situ.
专利号:US-2012184653-A1 优先权日:2011-01-18 标 题:Synthesis of linear phosphorus-containing functional fluorocopolymer 发明人:WANG LIANG; WANG VIKTORIA 权利人:WANG LIANG; WANG VIKTORIA 摘要:This invention relates to a synthesis of a linear fluorocopolymer having a plurality of pendant phosphorus-containing functional groups. The synthesized phosphorus-containing fluorocopolymer has chain linearity and narrow molecular weight distributions. It has applications as a lubricant additive that provides friction-reduction, anti-wear, and corrosion protection properties.
专利号:US-6162882-A 优先权日:1996-07-10 标 题:Preparation of novel homo- and copolymers using atom transfer radical polymerization 发明人:MATYJASZEWSKI KRZYSZTOF; COCA SIMION; GAYNOR SCOTT G; NAKAGAWA YOSHIKI; JO SEONG MU 权利人:UNIV CARNEGIE MELLON 摘要:The present invention is directed to a process of atom (or group) transfer radical polymerization for the synthesis of novel homopolymer or a block or graft copolymer, optionally containing at least one polar group, with well defined molecular architecture and narrow polydipersity index, in the presence of an initiating system comprising (i) an initiator having a radically transferrable atom or group, (ii) a transition metal compound, and (iii) a ligand, the present invention is also directed to the synthesis of a macromolecule having at least two halogen groups which can be used as a macroinitiator component (i) to subsequently form a block or graft copolymer by an atom or group transfer radical polymerization process; the present invention is also directed to a process of atom or group transfer radical polymerization for the synthesis of a branched or hyperbranched polymer; in addition, the present invention is directed to a process of atom or group transfer radical polymerization for the synthesis of a macroinitiator which can subsequently be used to produce a block or graft copolymer.
专利号:US-9738793-B2 优先权日:2012-06-21 标题 :Procedure summary of water-based polymer resin doped titanium dioxide nanotubes as application corrosion coating 发明人:MONTESINOS GOMEZ ROSA DEL CARMEN; PLIEGO VENCES LIZBETH; ROMERO HERNANDEZ NANCY; FLORES SANDOVAL CESAR ANDRES; ALVAREZ RAMIREZ FERNANDO; FERRAT TORRES GERARDO; TOLEDO ANTONIO JOSE ANTONIO; VAZQUEZ MORENO FLAVIO SALVADOR 权利人:MEXICANO INST PETROL 摘要:The present invention relates to the application of polymeric resins and TiO2 doped with polymeric resins as coatings for external metal surfaces for industrial use, mainly by selecting the following metals: stainless steel, carbon steel and copper. Focuses specifically on the synthesis of a polymeric resin waterborne corrosion consisting of nano-structured polymer particles formed with two or more acrylic monomers, vinyl or styrenic a functionalizing agent and a crosslinking agent from 1.0 to 20% wt. each. Doping addition is made of the same polymeric resins, which are incorporated in nanotubes of titanium dioxide in concentrations ranging from 50 to 10,000 ppm. The polymeric resin is water based corrosion synthesized by emulsion polymerization techniques and is during the synthesis process is introduced nanotube loading of titanium dioxide (which are synthesized according to U.S. Pat. No. 7,645,439 B2), which allowing the dispersion in the polymer matrix. Polymer dispersions obtained in this way are used as anti-corrosion coatings 100% water based.
专利号:US-6291620-B1 优先权日:1994-11-09 标 题:Polymer synthesis 发明人:MOAD GRAEME; MOAD CATHERINE LOUISE; KRSTINA JULIA; RIZZARDO EZIO; DARLING THOMAS ROBERT; BERGE CHARLES THOMAS 权利人:DU PONT; COMMW SCIENT IND RES ORG 摘要:Process for the synthesis of block polymers, homopolymers and copolymers of narrow polydispersity having formula (1) by contacting selected vinyl monomer(s), vinyl-terminated compound(s) and free radicals in which effective control of production of polymer is achieved by controlling the mole ratio of vinyl monomer(s), vinyl-terminated compound(s) and free radicals relative to one another; and polymers produced thereby
专利号:US-2023348707-A1 优先权日:2022-04-28 标题:Random bipolymers of controlled molecular mass based on hydroxyacrylates and their use as destabilizers of water/oil emulsions in crude oils 发明人:SANDOVAL CÉSAR ANDRÉS FLORES; MORENO FLAVIO SALVADOR VÃ?ZQUEZ; OLIVARES GERARDO ZAVALA; RAMÃ?REZ FERNANDO Ã?LVAREZ; SANTIAGO JESSICA VALERIA FUENTES; ZAMORA GUERRERO EDGAR BENEDICTO; MAYA ENRIQUE CEVADA 权利人:MEXICANO INST PETROL 摘要:The present disclosure provide bipolymers, based on alkyl acrylate and hydroxyalkyl acrylate, with high randomness and controlled molecular mass, that are useful as demulsifying and dehydrating agents for crude oil. The synthesis of these bipolymers is carried out in a single stage by emulsion polymerization, a process that, in addition to having moderate reaction conditions, allows the control of the homogeneity of the chain size, the molecular mass, and the demulsifying efficiency. These random bipolymers are soluble in organic phase; therefore, these cannot be carried away by the removed water, and are eliminated in the atmospheric distillation stage. An additional advantage is the superior demulsifying and clarifying efficiency of these random bipolymers compared with the polyether formulations widely used at industrial level. In addition, these random bipolymers provide single molecule that performs three functions: breaker, coalescer and clarifier, in contrast to formulations based on at least three different polyethers.
[参考文献]: A H Shojaei, Et Al. Evaluation Of Poly(Acrylic Acid-Co-Ethylhexyl Acrylate) Films For Mucoadhesive Transbuccal Drug Delivery: Factors Affecting The Force Of Mucoadhesion. J Control Release. 2000 Jul 3;67(2-3):223-32. [参考文献]: Ana Rita C Duarte, Et Al. Impregnation Of An Intraocular Lens For Ophthalmic Drug Delivery. Curr Drug Deliv. 2008 Apr;5(2):102-7. [参考文献]: Daniele Torchia, Et Al. Allergic Contact Dermatitis From 2-Ethylhexyl Acrylate Contained In A Wig-Fixing Adhesive Tape And Its 'Incidental' Therapeutic Effect On Alopecia Areata. Contact Dermatitis. 2008 Mar;58(3):170-1. [参考文献]: Fumio Tokumura, Et Al. The Potential Dermal Irritating Effect Of Residual (Meth)Acrylic Monomers In Pressure Sensitive Adhesive Tapes. Drug Chem Toxicol. 2010;33(1):1-7. [参考文献]: Iu G Piskarev, Et Al. [参考文献]: Gig Sanit. 1991 Dec:(12):19-21.
合成参考文献
摘要:Haufe, G., Science of Synthesis Knowledge Updates, (2019) 3, 213. 摘要:Torborg, C.; Samojłowicz, C.; Grela, K., Science of Synthesis: Water in Organic Synthesis, (2012) 1, 237. 摘要:Andersson, C.-M.; Andersson, M., Science of Synthesis: Cross Coupling and Heck-Type Reactions, (2012) 3, 50. 摘要:Dornan, P. K.; Dong, V. M., Science of Synthesis: Catalytic Transformations via CH Activation, (2015) 1, 156. 摘要:Gigiena i Sanitariya. For English translation, see HYSAAV., 56(12)(19), 1991