CAS: 2567-83-1; Tetraethylammonium (Perchlorate)

该化合物是四硝基铵盐,其特点是四乙基铵酸和高氯硝酸阴离子,通常是在水和酒精等极地溶剂中溶解的白色晶状固体,技经评估组以其稳定性而著称,但在正常条件下,它可以分解,但在接触热剂或强效消毒剂时可以分解.该化合物经常用于各种用途,包括作为有机合成的试剂和电化学研究中的电解剂.其电离性质有助于其传导性,使其在某些电化学应用中有用.此外,技经评估组还因其高能特性而对其在推进剂配方中的潜在用途进行了研究.然而,处理该化合物需要谨慎小心,因为过氯盐可能是危险的,而且已知是环境污染物.

结构式图片

相似化合物

1923-70-2 56-34-8 10052-47-8

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CAS号71-91-0 四乙基溴化铵 | CAS号56-34-8 四乙基氯化铵 | CAS号112362-30-8 2,6-BIS(1-METHY... | CAS号68-05-3 四乙基碘化铵 | CAS号93-89-0 苯甲酸乙酯 | CAS号1459-20-7 DESYL BENZOATE | CAS号2025-56-1 Ethyl radical | CAS号121-44-8 三乙胺

合成工艺路线路线简述

    四乙基溴化铵置于高氯酸体系中,用 水 用作溶剂,化学反应生成高氯酸四乙基铵
    参考文献:固态铁的tris 1,4-Diimine配合物的金属到配体电荷转移(mlct)状态的分离:X射线晶体结构和epr †
    标题:固态铁的tris 1,4-Diimine配合物的金属到配体电荷转移(mlct)状态的分离:X射线晶体结构和epr †
    摘要:使用5,6-二氢-5,6-环氧-1,10-菲咯啉作为配体l,确定[fel 3 ](clo 4)2 .2H 2 O的x射线晶体结构.它的epr和磁性表明它被fe(III)-l-Type的mlct态捕获.
    Doi:10.1039/c6Nj02874H

    海关参考信息

    专利信息


    专利号:US-6603070-B2
    优先权日:2000-07-21
    标题 :Convergent synthesis of multiporphyrin light-harvesting rods
    发明人:LINDSEY JONATHAN S; LOEWE ROBERT S
    权利人:UNIV NORTH CAROLINA STATE
    摘要:The present invention provides a convergent method for the synthesis of light harvesting rods. The rods are oligomers of the formula A 1 (A b+1 ) b , wherein b is at least 1, A 1 through A b+1 are covalently coupled rod segments, and each rod segment A 1 through A 1+b comprises a compound of the formula X 1 (X m+1 ) m wherein m is at least 1 and X 1 through X m+1 are covalently coupled porphyrinic macrocycles. Light harvesting arrays and solar cells containing such light harvesting rods are also described, along with intermediates useful in such methods and rods produced by such methods.

    专利号:US-6916982-B2
    优先权日:2000-07-21
    标题:Synthesis of perylene-porphyrin building blocks and polymers thereof for the production of light-harvesting arrays
    发明人:LOEWE ROBERT S; TOMIZAKI KIN-YA; LINDSEY JONATHAN S
    权利人:UNIV NORTH CAROLINA STATE
    摘要:The present invention provides methods, compounds, and compositions for the synthesis of light harvesting arrays, such arrays comprising: (a) a first substrate comprising a first electrode; and (b) a layer of light harvesting rods electrically coupled to said first electrode, each of said light harvesting rods comprising a polymer of Formula I:n nX 1 X m+1 ) m   (I)n nwherein m is at least 1; X 1 is a charge separation group, and X 2 through X m+1 are chromophores. At least one of X 2 through X m+1 has at least one perylene group coupled thereto.

    专利号:US-9957622-B2
    优先权日:2009-07-23
    标 题 :Device and method of obtaining diols and other chemicals using decarboxylation
    发明人:MOSBY JAMES; BHAVARAJU SAI; KARANJIKAR MUKUND
    权利人:FIELD UPGRADING LTD
    摘要:A method for converting carboxylic acids (including carboxylic acids derived from biomass) into hydrocarbons. The produced hydrocarbons will generally have at least two oxygen containing substituents (or other substituents). In one example of application, the electrolysis converts alkali salts of carboxylic acids into diols which can then be used as solvents or be dehydrated to produce dienes, which can then be used to produce elastic polymeric materials. This process allows custom synthesis of high value chemicals from renewable feed stocks such as carboxylic acids derived from biomass.

    专利号:US-2025034146-A1
    优先权日:2023-07-13
    标题:Electro-photochemical synthesis of 1,2,4-triazolo-[4,3-a]pyrazine
    发明人:PIERCEY DAVIN GLENN; YOUNT JOSEPH ROBERT
    权利人:PURDUE RESEARCH FOUNDATION
    摘要:A method of preparing a 1,2,4-triazolo-[4,3-a]pyrazine backbone using an electro-photochemical process comprising coupling a compound comprising a 5-substituted tetrazole moiety to a compound comprising an optionally substituted pyrazine moiety electrochemically and subjecting the resulting compound to photochemical excitation with ultraviolet light.

    专利号:US-4402804-A
    优先权日:1982-05-17
    标题 :Electrolytic synthesis of aryl alcohols, aryl aldehydes, and aryl acids
    发明人:JACKSON PATRICIA J
    权利人:PPG INDUSTRIES INC
    摘要:Disclosed is a method of synthesizing compounds chosen from the group consisting of benzyl alcohol, benzaldehyde, benzoic acid, phenoxy benzyl alcohol, phenoxy benzaldehyde, phenoxy benzoic acid, and mixtures thereof by providing a composition of a current carrying component, such as a fluoroborate salt or a tetraethylammonium salt, a solvent, and a methyl aryl compound in contact with an anode and cathode. The solvent is reduced at the cathode and the methyl substituted aryl at the anode whereby to form product. According to an alternative exemplification of the invention, the anode and cathode are separated by a permionic membrane and a source of oxygen is provided in contact with the cathode and the permionic membrane.

    专利号:US-8062756-B2
    优先权日:2005-08-26
    标题:Stepwise growth of oligomeric redox-active molecules on a surface without the use of protecting groups
    发明人:BOCIAN DAVID F; LINDSEY JONATHAN S; JIAO JIEYING
    权利人:BOCIAN DAVID F; LINDSEY JONATHAN S; JIAO JIEYING; REGENTS OFT THE UNIVERSITY OF CALIFORNIA; UNIV NORTH CAROLINA STATE
    摘要:This invention provides a procedure for growing oligomers via a stepwise process. The oligomers can include porphyrins, which have been previously shown to be attractive candidates for molecular-based information storage. The stepwise synthesis procedure requires no protecting groups, thus eliminating protection/deprotection reactions that add complexity to the process.
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    合成参考文献


    摘要:Ruan, Z.; Huang, Z.; Kuciński, K.; Ackermann, L., Science of Synthesis: Special Topics, (2021) 1, 238.
    摘要:Ruan, Z.; Huang, Z.; Kuciński, K.; Ackermann, L., Science of Synthesis: Special Topics, (2021) 1, 208.
    摘要:Ruan, Z.; Huang, Z.; Kuciński, K.; Ackermann, L., Science of Synthesis: Special Topics, (2021) 1, 237.
    摘要:Ruan, Z.; Huang, Z.; Kuciński, K.; Ackermann, L., Science of Synthesis: Special Topics, (2021) 1, 213.
    摘要:Lam, K.; Leech, M. C.; Lennox, A. J. J., Science of Synthesis: Special Topics, (2021) 1, 457.
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