专利号:US-12043553-B2 优先权日:2019-10-31 标题:Quantum material/vanadium oxide heterostructures, methods of making same, and uses thereof 发明人:BANERJEE SARBAJIT; WATSON DAVID F; ANDREWS JUSTIN L; CHO JUNSANG; SUWANDARATNE NUWANTHI; SHENG AARON 权利人:UNIV NEW YORK STATE RES FOUND; TEXAS A & M UNIV SYS 摘要:The subject invention pertains to the synthesis and characterization of V2O5/CdE NW/QD heterostructures. The V2O5/CdE heterostructures are versatile new materials constructs for light harvesting, charge separation, and the photocatalytic production of solar fuels; polymorphism of V2O5 and compositional alloying of both components provides for a substantial design space for tuning of interfacial energy offsets. Also provided are a new class of type-II heterostructures composed of cadmium chalcogenide QDs (CdE where E=S, Se, or Te) and α-V2O5 nanowires (NWs). The synthesis and characterization of V2O5/CdE NW/QD heterostructures, prepared via successive ionic layer adsorption and reaction (SILAR) and linker-assisted assembly (LAA), the characterization of their photoinduced charge-transfer reactivity using transient absorption spectroscopy, and their performance in the photocatalytic reduction of protons to hydrogen are also disclosed.
摘要:Merck Index - O'Neil MJ, Heckelman PE, Dobbelaar PH, Roman KJ (eds). The Merck Index, An Encyclopedia of Chemicals, Drugs, and Biologicals, 15th Ed. Cambridge, UK: The Royal Society of Chemistry, 2013. 摘要:ACGIH - Documentation of the TLVs and BEIs, 7th Ed. Cincinnati: ACGIH Worldwide, 2020. 摘要:Hawley - Lewis RJ. _Hawley's Condensed Chemical Dictionary, _15th Ed. New York: John Wiley & Sons, 2007.