合成目标产物 Methyl Eugenol 主要起始原料 Eugenol And Iodomethane
2859-78-1 = 93-15-2 反应条件:1.1 Catalysts: Dichlorobis(Triphenylphosphine)Palladium Solvents: Tetrahydrofuran; 12 H,60 °C 标题:Pd-Catalyzed Cross-Coupling Of Haloarenes And Chloroarene-Cr(Co)3 Complexes With Stabilized Vinyl- And Allylaluminium Reagents 作者:Schumann,Herbert; Kaufmann,Jens; Schmalz,Hans-Guenther; Boettcher,Andreas; Gotov,Battsengel 参考文献:Synlett 日期:2003 卷标:(12) 页码:1783-1788]
= 93-15-2 反应条件:1.1 Reagents: Potassium Carbonate Solvents: Dimethylformamide; 40 °C1.2 17 H,40 °C 标题:Catalyst-Free Ligin Valorization By Acetoacetylation. Structural Elucidation By Comparison With Model Compounds 作者:Krall,Eric M.; Serum,Eric M.; Sibi,Mukund P.; Webster,Dean C. 参考文献:Green Chemistry 日期:2018 卷标:20(13) 页码:2959-2966]
= 93-15-2 反应条件:1.1 Catalysts: Potassium Fluoride; 3 H,0.25 Mpa,200 °C 标题:Method For Preparing Methyleugenol Via Methylation Of Eugenol With Dimethyl Carbonate 参考文献:China]
= 93-15-2 反应条件:1.1 Reagents: Sodium Hydroxide 标题:Synthesis And Functionality Of Eugenol-Based Polyacetylenes 作者:Rahim,E. A.; Sanda,F. 参考文献:Journal Of Physics: Conference Series 日期:2019 卷标:1242]
= 93-15-2 反应条件:1.1 Catalysts: Potassium Carbonate; Rt -> 155 °C1.2 5.5 H,155 °C; 0.5 H,155 °C 标题:Synthesis Of Methyleugenol With Dimethyl Carbonate As Methylating Agent 作者:Sun,Li-Yuan; Zhu,Kai 参考文献:Linchan Huaxue Yu Gongye 日期:2013 卷标:33(2) 页码:139-143]
= 93-15-2 反应条件:1.1 Reagents: Potassium Carbonate Solvents: Acetone; 12 H,Reflux 标题:Stereoselective Synthesis Of 1-Arylpropan-2-Amines From Allylbenzenes Through A Wacker-Tsuji Oxidation-Biotransamination Sequential Process 作者:Gonzalez-Martinez,Daniel; Gotor,Vicente; Gotor-Fernandez,Vicente 参考文献:Advanced Synthesis & Catalysis 日期:2019 卷标:361(11) 页码:2582-2593]
= 93-15-2 反应条件:1.1 Reagents: Sodium Hydroxide Solvents: Water; 20 Min,Rt; Overnight,Rt1.2 1.5 H,Rt; 3 H,110 - 120 °C 标题:Synthesis 3,4-Dimethoxybenzyl-2,4-Dihydroxyphenyl Ketone From Eugenol 作者:Matsjeh,S.; Anwar,C.; Sholikhah,E. N.; Alimuddin,A. A. 参考文献:International Journal Of Chemical Engineering And Applications 日期:2015 卷标:6(1) 页码:61-65]
= 93-15-2 反应条件:1.1 Reagents: Sodium Hydroxide Solvents: Water; 15 Min1.2 30 Min; 1 H,103 °C 标题:Synthesis Of New Fused Ring Sultone From Eugenol And Its Derivatives 作者:Sudarma,I. M.; Hidayati,R.; Darmayanti,M. G. 参考文献:Rasayan Journal Of Chemistry 日期:2020 卷标:13(2) 页码:1193-1198]
= 93-15-2 反应条件:1.1 Reagents: Potassium Carbonate Solvents: Diglyme; 4 H,150 - 155 °C 标题:Synthesis Of Aryl Alkyl Ethers By Alkylation Of Phenols With Quaternary Ammonium Salts 作者:Maras,Nenad; Polanc,Slovenko; Kocevar,Marijan 参考文献:Acta Chimica Slovenica 日期:2010 卷标:57(1) 页码:29-36]
= 93-15-2 反应条件:1.1 Reagents: Potassium Hydroxide Solvents: Water 标题:Total Synthesis Of (+/-)-Codeine Through 1,3-Dipolar Cycloaddition 作者:Erhard,Thomas 参考文献:2011]
= 93-15-2 反应条件:1.1 Catalysts: 1H-Imidazolium,2-Carboxy-1,3-Dimethyl-,Inner Salt Solvents: Acetonitrile; 80 Min,160 °C 标题:Masked N-Heterocyclic Carbene-Catalyzed Alkylation Of Phenols With Organic Carbonates 作者:Lui,Matthew Y.; Yuen,Alexander K. L.; Masters,Anthony F.; Maschmeyer,Thomas 参考文献:Chemsuschem 日期:2016 卷标:9(17) 页码:2312-2316]
= 93-15-2 反应条件:1.1 Reagents: Sodium Hydroxide Solvents: Water; Rt1.2 1 H,20 °C; 1 H,20 °C; 1 H,20 °C -> 40 °C 标题:Process For Preparation Of Eugenol Methyl Ether 参考文献:China]
= 93-15-2 反应条件:1.1 Catalysts: Potassium Carbonate Solvents: Dimethyl Sulfoxide,Dimethylformamide; 5 H,160 °C 标题:An Example Of Using Dimethyl Carbonate As An Environmentally Benign Methylating Reagent 作者:Phan,Thanh Binh; Le,Ngoc Thuc; Nguyen,Thi Thu Trang; Nguyen,Viet Tu; Nguyen,Thi Ngat 参考文献:Tap Chi Hoa Hoc 日期:2011 卷标:49(6) 页码:680-684]
= 93-15-2 反应条件:1.1 Reagents: Potassium Carbonate Solvents: Acetone; 3 H,Reflux 标题:Synthesis Of Novel Isoxazolines Via 1,3-Dipolar Cycloaddition And Evaluation Of Anti-Stress Activity 作者:Maurya,Rakesh; Ahmad,Ausaf; Gupta,Prasoon; Chand,Kailash; Kumar,Manmeet; Et Al 参考文献:Medicinal Chemistry Research 日期:2011 卷标:20(2) 页码:139-145]
= 93-15-2 反应条件:1.1 Reagents: Potassium Carbonate; 6 H,170 °C 标题:Dimethyl Carbonate And Phenols To Alkyl Aryl Ethers Via Clean Synthesis 作者:Ouk,Samedy; Thiebaud,Sophie; Borredon,Elisabeth; Le Gars,Pierre 参考文献:Green Chemistry 日期:2002 卷标:4(5) 页码:431-435]
= 93-15-2 反应条件:1.1 Solvents: Acetone; 24 H,60 °C 标题:Preparation Of Dihydronaphthalene Derivatives As Efflux Pump Inhibitors For Treatment Of Infection 参考文献:India]
专利号:US-2020030462-A1 优先权日:2018-07-24 标 题 :GREEN SYNTHESIS OF BIOCOMPATIBLE AND NEAR INFRARED ACTIVE EUGENATE (4-allyl-2-methoxyphenolate) CAPPED IRON OXIDE NANOPARTICLES FOR DEEP TISSUE IMAGING AND THERAPY 发明人:SHARAD GUPTA; PRASHANT KHAREY 权利人:INDIAN INSTITUTE OF TECH INDORE 摘要:NIR active, biocompatible and multifunctional (magnetic, photo-acoustic, and photo-thermal agent) E-capped iron oxide nanoparticles for deep tissue imaging and cancer therapy, are synthesized by a simple, rapid, non-toxic, low-cost and efficient completely green synthesis technique using extract made from the leaves of a medicinal aromatic plant, Pimenta dioica.
专利号:WO-2020255049-A1 优先权日:2019-06-20 标题:Process for the preparation and identification of deuterated eugenol 发明人:ORUGANTI SRINIVAS; AMRUTAPU SRAVANTH KUMAR; SAMPATH MAGESH; SEN SAIKAT 权利人:DR REDDY’S INST OF LIFE SCIENCES 摘要:The present invention provides a novel, simple, unique and viable processes for the synthesis of deuterium incorporated eugenols, such as deuterated eugenol (II), regioisomeric deuterated eugenol (III), and deuterated variant of methyl eugenol (V).
专利号:WO-2024130393-A1 优先权日:2022-12-21 标 题 :Nanoparticle and method of synthesis thereof 发明人:MOSKOVCHENKO SVITLANA 权利人:MOSKOVCHENKO SVITLANA 摘要:The present technology relates to nanoparticles, compositions comprising said nanoparticles, and methods of synthesis of said nanoparticles; wherein the nanoparticles comprise a metal nanoparticle core, a first coating of amphiphilic molecules, and a second coating of essential oil, essential oil primary constituent, or both, which combine the antimicrobial properties of metal nanoparticles, amphiphilic molecules, and essential oil or essential oil primary constituents.
专利号:US-2021206711-A1 优先权日:2020-01-03 标 题:Synthesis of the Grape Mealybug Pheromone trans-alpha-Necrodyl Isobutyrate 发明人:CHEBNY VINCENT JAMES 权利人:TRECE INC 摘要:Methods are provided for synthesizing the grape mealybug pheromone, trans-α-necrodyl isobutyrate, starting with essential plant oils that contain trans-α-necrodyl acetate. The synthesis method, in two steps, converts the trans-α-necrodyl acetate to trans-α-necrodol and then converts the trans-α-necrodol to the desired trans-α-necrodyl isobutyrate. The first step can be achieved by either of a hydrolysis reaction or a reduction reaction. In the hydrolysis reaction, the essential oil is mixed in an alcohol solvent with a hydroxide base, or by mixing the essential oil in an aqueous acid. A reduction reaction can instead by performed in an organic solvent in the presence of a reducing agent. The trans-α-necrodol is converted to the desired trans-α-necrodyl isobutyrate by an esterification reaction with a carboxylic acid, an acyl halide, or an acid anhydride.
专利号:US-2018317484-A1 优先权日:2017-05-07 标题:Composition for inhibiting synthesis of mycotoxin without affecting the growth of the fungi 发明人:MEHTA ALKA; BOGA RAMESHBABU; P DHANAMJAYULU 权利人:VIT UNIV; BogaR Laboratories 摘要:A composition for inhibiting the growth of mycotoxins without affecting the growth of fungi is provided. The mycotoxin is an Aflatoxin and the fungus is an Aspergillus . The anti-aflatoxin composition comprises benzimidazole derivatives of Formula, n n n n n n n n n n where the A is hydrogen or C1-C6 alkyl or C6-C14 aryl; B is C1-C10 alkyl or C6-C14 aryl or oxygen, sulfur, nitrogen containing heteroaryl; C and D are hydrogen or C1-C6 alkyl or C1-C6 alkoxyl or C6-C14 aryl; E is hydrogen or nitro or cyano or carboxyl or acetamidoxime or amidoxime or C1-C6 alkyl or C1-C6 alkoxyl or C6-C14 aryl or oxygen, sulfur, and nitrogen containing heteroaryl; F is hydrogen or C1-C6 alkyl or C1-C6 alkoxyl or C6-C14 aryl or oxygen, sulfur, and nitrogen containing heteroaryl, and mixture thereof with corresponding salts.
专利号:US-10266503-B1 优先权日:2016-05-24 标 题 :Sulfoxide ligand metal catalyzed oxidation of olefins 发明人:WHITE M CHRISTINA; AMMANN STEPHEN E; LIU WEI; MA RULIN 权利人:UNIV ILLINOIS 摘要:The enantioselective synthesis of isochroman motifs has been accomplished via Pd(II)-catalyzed allylic C—H oxidation from terminal olefin precursors. Critical to the success of this goal was the development and utilization of a novel chiral aryl sulfoxide-oxazoline (ArSOX) ligand. The allylic C—H oxidation reaction proceeds with the broadest scope and highest levels asymmetric induction reported to date (avg. 92% ee, 13 examples ≥90% ee). Additionally, C(sp 3 )-N fragment coupling reaction between abundant terminal olefins and N-triflyl protected aliphatic and aromatic amines via Pd(II)/sulfoxide (SOX) catalyzed intermolecular allylic C—H amination is disclosed. A range of 52 allylic amines are furnished in good yields (avg. 76%) and excellent regio- and stereoselectivity (avg. >20:1 linear:branched, >20:1 E:Z). For the first time, a variety of singly activated aromatic and aliphatic nitrogen nucleophiles, including ones with stereochemical elements, can be used in fragment coupling stiochiometries for intermolecular C—H amination reactions.
参考文献:10.1007/s00436-011-2525-y 摘要:Kovendan K, Murugan K, Vincent S. Evaluation of larvicidal activity of Acalypha alnifolia Klein ex Willd. (Euphorbiaceae) leaf extract against the malarial vector, Anopheles stephensi, dengue vector, Aedes aegypti and Bancroftian filariasis vector, Culex quinquefasciatus (Diptera: Culicidae). Parasitol Res. 2012 Feb;110(2):571–81. doi: 10.1007/s00436-011-2525-y. 参考文献:10.3791/2901|10.3791/2901-v 摘要:Manoukis N, Geib S, Seo D, McKenney M, Vargas R, Jang E. An optimized protocol for rearing Fopius arisanus, a parasitoid of Tephritid fruit flies. J Vis Exp. 2011 Jul 02;(53). 参考文献:10.1007/s00436-011-2540-z 摘要:Kovendan K, Murugan K, Naresh Kumar A, Vincent S, Hwang JS. Bioefficacy of larvicdial and pupicidal properties of Carica papaya (Caricaceae) leaf extract and bacterial insecticide, spinosad, against chikungunya vector, Aedes aegypti (Diptera: Culicidae). Parasitol Res. 2012 Feb;110(2):669–78. doi: 10.1007/s00436-011-2540-z. 参考文献:10.1080/14786419.2010.531478 摘要:Ramos C, Teixeira B, Batista I, Matos O, Serrano C, Neng NR, Nogueira JMF, Nunes ML, Marques A. Antioxidant and antibacterial activity of essential oil and extracts of bay laurelLaurus nobilisLinnaeus (Lauraceae) from Portugal. Natural Product Research. 2012 Mar;26(6):518–29. doi: 10.1080/14786419.2010.531478. 参考文献:10.6026/97320630006315 摘要:Roy S, Maheshwari N, Chauhan R, Sen NK, Sharma A. Structure prediction and functional characterization of secondary metabolite proteins of Ocimum. Bioinformation. 2011 Jul 06;6(8):315–9. doi: 10.6026/97320630006315.