CAS: 753-73-1; Dimethyltin Dichloride

该化合物是一种有机锡化合物,广泛用作有机合成和工业应用中的催化剂和中间剂,其主要优点包括聚氨酯泡沫形成,聚氯乙烯稳定化和酯分反应中的高度回活性.该化合物与各种基质的热稳定性和兼容性极强,因此适合专门的化学工艺.二甲基氯也因其在促进选择性反应,减少副产品和提高受控环境中的产量方面的效率而受到重视.适当的处理由于其湿度敏感和回活性而至关重要.它通常作为晶体固体或溶液供应,其纯度符合具体的工业要求.

结构式图片

欧盟法规

统一分类与标签压力设备指令-第1组危险流体REACH注册ECHA物质食品接触材料-禁用CMR物质ECHA物质化妆品禁用物质清单C&L通报工作场所安全标识要求REACH预注册废弃物危险特性清单

上下游产品

CAS号10294-34-5 三氯化硼 | CAS号801-79-6 DIMETHYLBIS(PEN... | CAS号74-87-3 氯甲烷 | CAS号20195-60-2 1,1-dimethyl-2,... | CAS号594-27-4 四甲基锡 | CAS号873-51-8 苯基二氯硼 | CAS号83135-39-1 Bis-(chlorodime... | CAS号7646-78-8 四氯化锡 | CAS号85294-03-7 (3-ethylsulfiny... | CAS号108354-36-5 methyldiethyltin | CAS号1066-45-1 三甲基氯化锡 | CAS号110971-28-3 5-chloro-1,5-di... | CAS号10586-87-5 Stannane,bis[(d... | CAS号19434-15-2 Stannane,dimeth... | CAS号22397-16-6 [diethylcarbamo... | CAS号1802-94-4 10H-Phenoxastan... | CAS号20195-60-2 1,1-dimethyl-2,... | CAS号994-31-0 氯化三乙基锡 | CAS号7440-31-5 锡粉

合成工艺路线路线简述

  • 合成目标产物 Dimethyltin Dichloride 主要起始原料 Chloromethane
  • (文献来源)合成步骤主要原料 Chloromethane
Alkaline Earth Salt Of/the/ Methylsulfuric Acid置于盐酸,Tin(Ll) Chloride体系中,化学反应生成 二甲基二氯化锡
参考文献:Hilpert; Ditmar,Chemische Berichte,1913,Vol. 46,P. 3741
标题:Hilpert; Ditmar,Chemische Berichte,1913,Vol. 46,P. 3741

专利信息


专利号:US-2024368099-A1
优先权日:2022-01-18
标 题:Methods for the synthesis of di(hydroxymethyl)tetrahydrofuran and its application in polyesters and polyurethanes
发明人:SPIEGELBERG BRIAN; BRANDT ADRIAN; BECK HORST; KUX ALEXANDER; TIN SERGEY; DE VRIES JOHANNES GERARDUS
权利人:HENKEL AG & CO KGAA
摘要:The present invention relates to the synthesis of di(hydroxymethyl)tetrahydrofuran (DHMTHF) and the preparation of trans-enriched mixtures of DHMTHF. The invention further refers to polyester polyols which are obtained by reaction of cis/trans DHMTHF mixtures with a dicarboxylic acid. The invention further relates to polyurethanes and compositions containing a polyester polyol comprising DHMTHF, in particular to such polyurethane-containing (adhesive) compositions.

专利号:US-9724673-B2
优先权日:2011-06-30
标 题:Supported alkoxylated organotin reactant, preparation and use for heterogeneous-phase synthesis of tetrazoles
发明人:LE GROGNEC ERWAN; QUINTARD JEAN-PAUL; KERRIC GAELLE; CHRETIEN JEAN-MATHIEU; ZAMMATTIO FRANCOISE
权利人:LE GROGNEC ERWAN; QUINTARD JEAN-PAUL; KERRIC GAELLE; CHRETIEN JEAN-MATHIEU; ZAMMATTIO FRANCOISE; UNIV NANTES; CENTRE NAT RECH SCIENT
摘要:A supported alkoxylated organotin reactant, to the process for preparing same, to the use of such a reactant as a catalyst for heterogeneous-phase organic synthesis, and also to a process for heterogeneous-phase synthesis of 5-substituted or 1,5-disubstituted tetrazoles using such a reactant.

专利号:US-10428206-B2
优先权日:2015-07-02
标 题 :Process for the continuous synthesis of a modified diene elastomer
发明人:DORATO MARGARITA; FLESINSKI LIONEL
权利人:MICHELIN & CIE
摘要:A process for the continuous synthesis of a modified diene elastomer includes:n polymerization by n reactors r1 to rn equipped with an internal stirring system, the reactor r1 being fed by an input solution comprising a solvent, one or more monomers, an anionic polymerization initiator and a polar agent, one or more of the reactors being fed by reinjection of a purified solution comprising solvent and/or monomer(s), the number of dead chains in the output stream from the reactor rn is less than 30% of the number of living chains initiated in the reactor r1, the temperature of each reactor varying from 20° C. to 150° C.; and modification of the living diene elastomer obtained in the preceding stage and exhibiting a polydispersity index varying from 1.1 to 2, making it possible to introduce, into the elastomer, a functional group comprising at least one silicon atom directly connected to the elastomer chain.

专利号:US-2024383928-A1
优先权日:2021-07-30
标 题:Production of diorganotin dihalides
发明人:VINCENT ROBERT; ZIMMERMANN JARROD C
权利人:MERCK PATENT GMBH
摘要:The disclosed and claimed subject matter relates to the safe and efficient synthesis of diorganotin dihalide compounds of the formula R2SnX2 that as-synthesized are free of tetraalkyltin (R4Sn), trialkyltin halide (R3SnX) and monoalkyltin trihalide (RSnX3) species and of methods for their synthesis and use.

专利号:US-8329958-B2
优先权日:2004-07-02
标 题:Combinatorial synthesis of PEG oligomer libraries
发明人:RIGGS-SAUTHIER JENNIFER A; EKWURIBE NNOCHIRI N
权利人:RIGGS-SAUTHIER JENNIFER A; EKWURIBE NNOCHIRI N; BIOCON LTD
摘要:A simple chain-extending approach was established for the scale-up of the monoprotected monodisperse PEG diol materials. Reactions of THP-(OCH2CH2)n—OMs (n=4, 8, 12) with a large excess of commercially available H—(OCH2CH2)n—OH (n=1-4) under basic conditions led to THP-(OCH2CH2)n—OH (n=5-15). Similarly, Me-(OCH2CH2)n—OH (n=4-11, 13) were prepared from Me-(OCH2CH2)n—OMs (n=3, 7, 11). For the chain elongation steps, 40-80% yields were achieved through extraction purification. PEG oligomer libraries I and II were generated in 50-95% overall yields by alkylation or acylation of THP-(OCH2CH2)n—OH (n=1-15) followed by deprotection. Alkylation of Me-(OCH2CH2)n—OH (n=1-11, 13) with X—(CH2)m—CO2R (X=Br or OMs) and subsequent hydrolysis led to PEG oligomer library III in 30-60% overall yields. Combinatorial purification techniques were adapted to the larger-scale library synthesis. A total of 498 compounds, each with a weight of 2-5 g and a minimum purity of 90%, were synthesized.

专利号:WO-2023247609-A1
优先权日:2022-06-22
标题 :Process for the preparation of cyclohomogeranates
发明人:SCHELWIES MATHIAS; BRUNNER BERNHARD; PELZER RALF; LIST BENJAMIN; TURBERG MATHIAS; MITSCHKE BENJAMIN; DAS SAYANTANI; DE CHANDRA KANTA
权利人:BASF SE; STUDIENGESELLSCHAFT KOHLE GGMBH
摘要:The present invention relates to a process for the preparation of cyclohomogeranates. The invention relates to the synthesis of cyclohomogeranates from well available esters of homogeranic acid in only one step. The cyclohomogeranates prepared according to the process of the present invention can be used in the fragrance industry as intermediates or the compounds can be used as such as aroma compound.
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合成参考文献


摘要:Tchabanenko, K., Science of Synthesis Knowledge Updates, (2013) 1, 3.
摘要:Ramirez y Medina, I.-M.; Kipke, W.; Makow, J.; Staubitz, A., Science of Synthesis Knowledge Updates, (2020) 2, 43.
摘要:Hlina, J. A., Science of Synthesis Knowledge Updates, (2021) 1, 108.
摘要:Vrána, J.; Růžička, A., Science of Synthesis Knowledge Updates, (2021) 2, 27.
摘要:Hlina, J. A., Science of Synthesis Knowledge Updates, (2021) 1, 103.
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