CAS: 1193-81-3; 1-Cyclohexylethanol

相似化合物

3113-98-2 3113-99-3 823-76-7

上下游产品

CAS号98-86-2 苯乙酮 | CAS号119-61-9 二苯甲酮 | CAS号823-76-7 乙酰基环己烷 | CAS号50-00-0 甲醛 | CAS号110-83-8 环己烯 | CAS号98-85-1 苏合香醇 | CAS号75-24-1 三甲基铝 | CAS号2043-61-0 环己烷甲醛 | CAS号695-12-5 乙烯基环己烷 | CAS号43125-06-0 1-cyclohexyl-3-... | CAS号823-76-7 乙酰基环己烷 | CAS号3113-98-2 (S)-1-cyclohexy... | CAS号3113-99-3 (R)-1-环己基-1-醇 | CAS号140390-59-6 1-cyclohexyleth... | CAS号67-63-0 异丙醇 | CAS号932-66-1 1-乙酰基-1-环己烯 | CAS号27607-65-4 1,3-dicyclohexy... | CAS号86728-93-0 甲基 (S)-4-氯-3-羟基丁酸酯

苯乙酮置于氢气体系中,用 水 用作溶剂,20.0 °C,2.0 Mpa 条件下,反应 6.0H,以100%的收率获得1-环己基乙醇
参考文献:用手性氨基酸接枝的β-环糊精:用于不对称氢化的纳米粒子的有希望的超分子稳定剂吗
标题:用手性氨基酸接枝的β-环糊精:用于不对称氢化的纳米粒子的有希望的超分子稳定剂吗
摘要:通过以下两种方法在水溶液中制备了嫁接有手性氨基酸部分(如1-丙氨酸(ala)和1-亮氨酸(leu))的随机甲基化β-环糊精(ramecd)稳定的水溶性钌纳米颗粒.适当的环糊精存在下一步法还原三氯化钌作为金属源的氢(一锅法)或(II)nabh 4还原金属盐,然后通过添加手性修饰的ramecd(级联法)来稳定钌水溶胶.通过tem和NMR分析研究了配体的性质和合成方法对所得钌胶体的尺寸,分散性和表面性质的影响.球形钌悬浮液包含非常小的粒径分布(0.82-1.00 Nm)的微粒.在各种手性化合物(烯烃,酮和双取代的芳烃)的双相加氢中评估了它们的催化性能,在活性和选择性方面均显示出令人鼓舞的结果.然而,没有观测到明显的对映体过量.
Doi:10.1016/j.Apcata.2013.08.011

专利信息

专利号:US-6951932-B2
优先权日:2001-10-25
标 题:Synthesis of 2-aralkoxyadenosines and 2-alkoxyadenosines
发明人：MOORMAN ALLAN R
权利人:KING PHARMACEUTICALS RES & DEV
摘要:The invention provides new methods for synthesis of 2-aralkyloxyadenosines and 2-alkoxyadenosines. The invention is particularly useful for synthesis of 2-[2-(4-chlorophenyl)ethoxy]adenosine. Preferred methods of the invention include activating a guanosine compound followed by hydrolysis; alkylating the hydrolyzed compound with subsequent animation to provide a 2-aralkyloxyadenosine or a 2-alkoxyadenosine compound.

专利号:US-9365607-B1
优先权日:2012-07-31
标题 :Synthesis of deuterated ribo nucleosides, N-protected phosphoramidites, and oligonucleotides
发明人：SRIVASTAVA SURESH C; YASKO AMY
权利人:ASED LLC
摘要:The present invention is directed towards the synthesis of high purity deuterated sugars, deuterated phosphoramidites, deuterated nucleobases, deuterated nucleosides, deuterated oligonucleotides, and deuterated RNA's of defined sequences which can exhibit biochemically useful and biologically valuable properties, thus having potential for therapeutic uses.

专利号:US-5041637-A
优先权日:1988-07-12
标题:Process for the synthesis of optically active aminoacids
发明人：CANNATA VINCENZO; TAMERLANI GIANCARLO; CALZOLARI CLAUDIO
权利人:PRESIDENZA DEL CONSIGLIO DEL M
摘要:New process for the synthesis of optically active aminoacids of formula ##STR1## by treating compounds of formula ##STR2## which an optically active alcohol of formula n n R.sub.4 --OH (III) n n n d or 1 n n To obtain a pair of diastereoiosmer esters of formula ##STR3## which is resolved in basic medium into the single diastereoisomer esters of formula ##STR4## from which the desired optically active aminoacid of formula (I) is obtained by treatment in acid medium.

专利号:US-7342003-B2
优先权日:2001-10-25
标 题 :Synthesis of 2-aralkyloxyadenosines, 2-alkoxyadenosines, and their analogs
发明人：MOORMAN ALLAN R; SCANNELL MICHAEL; BALASUBRAMANIAN THIAGARAJAN; OUTCALT RUSSELL; LEUNG EDWARD
权利人:KING PHARMACEUTICALS RES & DEV
摘要:Provided is a method for the synthesis of an aralkyloxyadenosine or an alkoxyadenosine. The method includes protecting the hydroxyl sugar groups with a protecting group to produce a protected halogenated adenosine. The protected halogenated adenosine is alkoxylated, and the hydroxyl sugar groups of the protected halogenated adenosine are deprotected to provide the aralkyloxyadenosine or alkoxyadenosine.

专利号:US-8269047-B2
优先权日:2009-07-23
标题 :Synthesis of alpha-halo enones and enals
发明人：ZHANG LIMING; YE LONGWU
权利人:ZHANG LIMING; YE LONGWU; UNIV NEVADA
摘要:A method for preparing an α-halo enal or enone from an unprotected propargyl alcohol and an electrophilic halogen source catalyzed by the combination of a gold catalyst complex and a metal co-catalyst complex is disclosed. The method can be further enhanced by addition of an additive that facilitates suppression of a des-halo derivative.

专利号:US-6448425-B1
优先权日:2002-02-19
标题:Preparation of N-substituted aminoorganosilanes
发明人：GEDON STEVEN C; HALE MELINDA
权利人:CROMPTON CORP
摘要:A process is disclosed for the synthesis of N-cycloalkylaminoalkylsilanes, wherein the process comprises hydrogenating the corresponding N-arylaminoalkylsilanes in the presence of a catalytically effective amount of a supported or unsupported catalyst selected from the group consisting of palladium, platinum, nickel, rhenium, rhodium, ruthenium, copper chromite, and mixtures of the foregoing.