CAS: 28229-69-8; 3-Bromophenethyl Alcohol

上下游产品

3-溴苯乙酸 3-Bromophenylacetic Acid 1878-67-7
3-溴苯乙醛 2-(3-Bromophenyl)Acetaldehyde 109347-40-2
2-(3-溴苯基)乙酸甲酯 Methyl 2-(3-Bromophenyl)Acetatee 150529-73-0
3-溴氰苄 (3-Bromophenyl)Acetonitrile 31938-07-5
3-溴苯乙酸乙酯 Ethyl 2-(3-Bromophenyl)Acetate 14062-30-7
2-(3-溴苯基)乙酰氯 2-(3-Bromophenyl)Acetyl Chloride 98288-51-8

3-溴苯乙烯置于d-葡萄糖,氧气体系中,用 Aq. Phosphate Buffer 用作溶剂,化学反应 8.0H,反应生成3-溴苯乙醇
参考文献:生物催化形式的反马尔科夫尼科夫加氢胺化和芳烃的水合
标题:生物催化形式的反马尔科夫尼科夫加氢胺化和芳烃的水合
摘要:基于涉及酶级联反应的两个概念,实现了生物催化抗马尔科夫尼科夫烯烃的水合和水合反应:环氧化-异构化-水合胺化和环氧化-异构化-水合还原.的大肠杆菌菌株共表达苯乙烯单加氧酶(smo),苯乙烯氧化物异构酶(soi),ω转氨酶(cvta)和丙氨酸脱氢酶(aladh)催化的12个的芳烯烃加氢胺化,得到高的转化率相应的有价值末端胺(许多>=86%)和专有的抗马尔可夫尼科夫选择性(> 99:1).另一株大肠杆菌共表达smo,Soi和苯乙醛还原酶(par)的菌株以高转化率(许多>=80%)和非常高的抗马尔科夫尼科夫选择性(> 99:1)催化12种芳基烯烃水合为相应的有用末端醇.重要的是,发现soi可将手性环氧化物立体选择性异构化为手性醛,从而为酶法环氧化物重排提供了一些见识.利用这种立体选择性重排,高对映选择性的抗马尔科夫尼科夫水合和水合反应可将α-甲基苯乙烯以84-81%的转化率(97-92%ee)转化为相应的(S)-胺和(S)-醇.,
Doi:10.1021/acscatal.7B01464

专利信息

专利号:WO-2012152438-A1
优先权日:2011-05-11
标题 :Process for the preparation of nitrate acid ester of organic compounds
发明人：BONFANTI ANNALISA; STORONI LAURA; RONSIN GAEL
权利人:NICOX SA; BONFANTI ANNALISA; STORONI LAURA; RONSIN GAEL
摘要:The present invention relates to a one-step process for the synthesis of nitric acid esters or 15 N isotopically labeled nitrate esters of organic compounds starting from the correspondent alcohols. Formula (I).

专利号:US-8513465-B2
优先权日:2008-02-04
标题:Potassium organotrifluoroborate derivative and a production method therefor
发明人：KANG HEONJOONG; HAM JUNGYEOB; AHN HONG RYUL; PARK YOUNG HEE
权利人:KANG HEONJOONG; HAM JUNGYEOB; AHN HONG RYUL; PARK YOUNG HEE; SNU R&DB FOUNDATION
摘要:Provided are a production method for a potassium organotrifluoroborate compound having a hydroxyl group, and a novel potassium organotrifluoroborate compound having a hydroxyl group. The production method is advantageous in that a potassium organotrifluoroborate compound can be produced in a single reaction without recourse to a process of isolating and purifying an intermediate. The novel potassium organotrifluoroborate compound having a hydroxyl group is useful as a reactant which is widely used in the total synthesis of physiologically active natural products and diverse organic synthesis reactions including halogen substitution reactions, 1,2- and 1,4-addition reactions using a rhodium (Rh) catalyst, and Suzuki coupling reactions using a palladium (Pd) catalyst.

专利号:CN-114634432-A
优先权日:2022-04-26
标 题 :A kind of efficient synthesis method of alkyl aryl sulfide compounds

专利号:US-7825149-B2
优先权日:2006-01-19
标 题 :Substituted imidazoles
发明人：CHUBB NATHAN ANTHONY LOGAN; COX MARK ROGER; DAUVERGNE JEROME SEBASTIEN; EWIN RICHARD ANDREW; LAURET CHRISTELLE
权利人:PFIZER LTD
摘要:This invention relates to a range of alpha substituted 2-benzyl substituted imidazole compounds and pharmaceutically acceptable salts and solvates thereof, to compositions comprising such compounds, processes for their synthesis and their use as parasiticides.

专利号:CN-114716296-A
优先权日:2022-03-25
标题:A kind of efficient halogenation synthesis method of alkyl halide

专利号:CN-113198528-A
优先权日:2021-04-26
标题:A kind of SAPO-11 supported composite nano-platinum-aluminum catalyst for bisphenol F synthesis and alcohol oxidation and preparation method