CAS: 3724-55-8; Methyl But-3-Enoate

该化合物是分子式C5H8O2的不饱和酯,其特点是反应终端双联结,使其成为有机合成的多用途中间体,特别是在聚合物化学和特殊化学品的生产方面.该化合物的酯功能允许进一步衍生,而其高温合金组则能够参与添加或聚合反应.甲基但-3-基因组通常用于合成共聚物,粘合剂和涂层,因为其能够增强灵活性和交叉联系.其低粘度和中度波动性有利于工业应用的处理.建议在惰性条件下储存防止过早聚合.

结构式图片

相似化合物

625-38-7 627-27-0 818-57-5

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

CAS号35466-83-2 烯丙基甲基碳酸酯 | CAS号67-56-1 甲醇 | CAS号625-35-4 巴豆酰氯 | CAS号625-38-7 乙烯基乙酸 | CAS号74-88-4 碘甲烷 | CAS号201230-82-2 carbon monoxide | CAS号623-43-8 巴豆酸甲酯 | CAS号107-05-1 氯丙烯 | CAS号1117-71-1 4-溴巴豆酸甲酯 | CAS号1093085-14-3 methyl (E)-4-(1... | CAS号1093085-45-0 methyl (E)-4-(1... | CAS号95-20-5 2-甲基吲哚 | CAS号4509-09-5 Methyl 3,4-epox... | CAS号535-80-8 间氯苯甲酸 | CAS号826-34-6 顺-1,2-环丙烷二羧酸二甲酯 | CAS号6654-36-0 6-氧代己酸甲酯 | CAS号40630-06-6 Methyl 4-methyl... | CAS号127379-24-2 methyl 8-methyl... | CAS号126554-35-6 2-diazonio-1-me...

合成工艺路线路线简述

  • 合成目标产物 Methyl 3-Butenoate 主要起始原料 Allyl Methyl Carbonate
  • (文献来源)合成步骤主要原料 Allyl Methyl Carbonate
烯丙基甲基碳酸酯置于palladium Diacetate 一氧化碳,三苯基膦体系中,用100%的收率获得3-丁烯酸甲酯
参考文献:Preparation Of Esters
标题:Preparation Of Esters
摘要:.Beta.,.Gamma.不饱和酯是通过在第viii族金属催化剂的存在下,将相应的.Beta.,.Gamma.-不饱和碳酸酯与一氧化碳反应制备的.

海关参考信息

专利信息


专利号:US-10011580-B2
优先权日:2016-04-21
标题:Diastereoselective synthesis of (±)-epianastrephin, (±)-anastrephin and analogs thereof
发明人:WALSE SPENCER S; KUZMICH DANIEL
权利人:US AGRICULTURE
摘要:A process for the synthesis of trans-fused γ-lactones having Formula (IV) from substituted cyclic ketones having Formula (I). A diastereoselective synthesis of (±)-epianastrephin (1) (wherein: R 1 is ethenyl, R 2 and R 3 is methyl, and n is 1), (±)-anastrephin (2) (wherein: R 2 is ethenyl, R 1 and R 3 is methyl and n is 1), and analogs thereof (wherein: R 1 is H, C 1-5 alkyl, C 2-6 alkenyl or C 2-6 alkynyl, R 2 is H, C 1-5 alkyl, C 2-6 alkenyl or C 2-6 alkynyl, R 1 and R 2 together with the carbon atom they are attached form a C 3-6 cycloalkyl ring, R 3 is C 1-5 alkyl and n is 0-2):

专利号:US-5859268-A
优先权日:1996-04-09
标 题:Process for the synthesis of α, β-unsaturated esters
发明人:ANGELICI ROBERT J; SHIH KUO-CHEN
权利人:UNIV IOWA STATE RES FOUND INC
摘要:The present invention provides a process for the synthesis of an α,β-unsaturated ester from a mono-olefin-ester using Fe(CO) 5 .

专利号:US-2023174477-A1
优先权日:2021-12-03
标题:Methods for synthesis of the tricyclic prostaglandin d2 metabolite methyl ester
发明人:DAI MINGJI; SIMS HUNTER
权利人:PURDUE RESEARCH FOUNDATION
摘要:Methods for the synthesis of a tricyclic-prostaglandin D 2 metabolite methyl ester or a pharmaceutically acceptable salt thereof.

专利号:US-9567293-B2
优先权日:2013-02-08
标题 :Combined synthesis of a nitrile-ester/acid and of a diester/diacid
发明人:DUBOIS JEAN-LUC; COUTURIER JEAN-LUC; BRANDHORST MARKUS
权利人:ARKEMA FRANCE
摘要:A method for the combined synthesis of a mono-unsaturated nitrile-ester(acid) and of a bi-functional carbonyl compound, wherein it includes a step including the cross metathesis mc1 of an unsaturated fatty acid/ester compound with an unsaturated nitrile compound, in which mc1 is performed with partial conversion such as to obtain and recover, separately, at least the following products: a mono-unsaturated nitrile-ester/acid and a symmetrical compound, diester or diacid respectively including a double bond located in the middle of the molecular chain of compound, and subsequently a step including the oxidation cleavage cp2 of the double bond of compound, such as to form a single type of carbonyl compound having formula R2-(CH2)n-COR′, in which R′ is H or OH, depending on the operating conditions selected for the oxidation cleavage cp2. Also, the production of monomers for the polymer industry.

专利号:US-2013172553-A1
优先权日:2009-11-25
标题 :Chiral synthesis of isoxazolines, isoxazoline compounds, and uses thereof
发明人:SIELECKI-DZURDZ THAIS; PRUITT JAMES
权利人:SIELECKI-DZURDZ THAIS; PRUITT JAMES; CPSI STOCKHOLDER TRUST
摘要:Processes for the chiral syntheses of isoxazolines and intermediates are described. Compounds prepared thereby, and methods of using the compounds are also described.

专利号:US-6022977-A
优先权日:1997-03-26
标 题 :Dynamic resolution of isoxazoline thioesters to isoxazoline carboxylic acids
发明人:ZHANG LIN-HUA; ANZALONE LUIGI; PESTI JAAN A; YIN JIANGUO
权利人:DU PONT PHARM CO
摘要:The present invention relates generally to a novel method for preparation of substituted isoxazolin-5-yl acetic acid in high optical purity from a stereoisomeric mixture of an esterified substituted isoxazolin-5-yl acetate. The products are useful in the synthesis of compounds for pharmaceuticals, especially the treatment of thrombolytic disorders, and agricultural products.
杭州言鼎生物医药科技有限公司
⚠️ 未注册 · 未认证企业
⚠️ 该商家尚未完成注册及企业认证,请用户仔细辨别,谨慎交易。
数据来源于公开网络搜索,平台未作核实,请自行辨别。
🏢敬请 企业认领
🏬开设公司展台
📢获取免费会员权益
🎖️点亮专属注册企业标签
📇展现公司完整信息 样本查看立即注册认领 →
网址: http://www.yandingbio.com
企业联系电话:86-18989469219👤
📞杭州言鼎生物医药科技有限公司 ⚠️参考联系方式
联系人:蔡先生
电话:86-18989469219
手机:18989469219

邮箱:sales@yandingbio.com
通信地址: 杭州钱塘新区下沙金隅金座1-813
邮编: 310018
🆔 联系时候可告知是从"百琢研"平台获取的信息.
⚠️ 声明: 该企业未认证、未认领,请自行辨别信息的真实性和可靠性。咨询或交易时请注意风险评估与信息核实,百琢研不参与任何交易。企业认领注册入口→

地址:杭州钱塘新区下沙金隅金座1-813
⚠️ 未注册 · 未认证企业
注册入口 备注: 📌 数据来源说明:本展台内容基于各搜索引擎等公开数据整理,仅作展示用途。请用户自行辨别
✉️ 若企业需抹除展台内容或有异议, 请通过页面底部联系方式告知我们,我们会尽快处理。
第 1 / 1 页
现货

供应商参考报价(招募中)

品牌试剂参考报价(招募中)

📌 第三方产品分析报告

✅ COA系统入驻 | 共享模式

主要参考文献

参考标题:Mno2 As A Terminal Oxidant In Wacker Oxidation Of Homoallyl Alcohols And Terminal Olefins
作者:Rodney A. Fernandes,Gujjula V. Ramakrishna,Venkati Bethi
摘要:Pdcl2/cro3/hcl Produced α,β-Unsaturated Ketones From Homoallyl Alcohols, The Present Method Provided Orthogonally The β-Hydroxy-Methyl Ketones. No Overoxidation Or Elimination Of Benzylic And/or β-Hydroxy Groups Was Observed. The Method Could Be Extended To The Oxidation Of Simple Terminal Olefins As Well, To Methyl Ketones, Displaying Its Versatility. An Application To The Regioselective Synthesis Of Gingerol Is

合成参考文献


摘要:Michalak, M.; Gulajski, L.; Grela, K., Science of Synthesis, (2010) 47, 340.
摘要:Li, Y.; Xie, W.; Jiang, X., Science of Synthesis Knowledge Updates, (2016) 2, 48.
摘要:Okamoto, K.; Ohe, K., Science of Synthesis Knowledge Updates, (2020) 1, 37.
摘要:Haufe, G., Science of Synthesis Knowledge Updates, (2019) 3, 221.
摘要:Mika, L. T.; Horváth, I. T., Science of Synthesis: Water in Organic Synthesis, (2012) 1, 139.
📝 需求与反馈
尽可能描述清楚需求与问题信息
×

通知