CAS: 16090-14-5; 1,1,2,2-Tetrafluoro-2-((1,1,1,2,3,3-Hexafluoro-3-((1,2,2-Trifluorovinyl)Oxy)Propan-2-yl)Oxy)Ethane-1-Sulfonyl Fluoride

该化合物是一个含氟有机化合物,其独特结构包括一个氟化氟功能组和一个全氟碳链,该化合物因其高热和化学稳定性而显著,这是全氟化合物的一个常见特征,其分子结构具有疏水和疏脂特性,使其在各种应用中有用,包括作为一种表面活性剂和生产特殊化学品.氟化磺组的存在表明,它具有潜在的再活动性,特别是在核循环替代反应中,可以在合成化学中加以利用.此外,由于其氟化性质,它可能表现出较低的表面紧张和对降解的高度耐受性,从而导致环境持久性.然而,这些化合物对环境和健康的影响是正在进行的研究的主题,特别是其潜在的生物累积性和毒性.

结构式图片

相似化合物

26654-97-7 4089-58-1 4628-44-8

欧盟法规

REACH注册ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

Hexafluoropropene oxide fluorosulfonyldifluoroacetyl fluoride 8-fluorosulfonyl-2,5-bis(trifluoromethyl)°Ctafluoro-3,6-dioxa°Ctanoyl fluoride 1,1,2,2-tetrafluoro-2-[1,1,1,2,3,3-hexafluoro-3-(1,2,2-trifluoroethenoxy)propan-2-yl] oxyethanesulfonic acid

合成工艺路线路线简述

  • 合成目标产物 Perfluoro(4-Methyl-3,6-Dioxaoct-7-Ene)Sulfonyl Fluoride 主要起始原料 Hexafluoropropylene Oxide And Tetrafluoroethane Beta-Sultone
  • (文献来源)合成步骤主要原料 Hexafluoropropylene Oxide 和 Tetrafluoroethane Beta-Sultone
Perfluoro-3,6-Dioxa-4-Methyl-7-octene-1-Sulfonic Acid Sodium Salt置于四乙二醇二甲醚,N,N-二乙基-1,1,2,3,3,3-六氟丙胺体系中,化学反应 4.0H,以83%的收率获得全氟(4-甲基-3,6-二氧杂-7-辛烯)磺酰氟
参考文献:全氟乙烯基醚磺酰氟的制备方法
标题:全氟乙烯基醚磺酰氟的制备方法
摘要:本发明属于全氟树脂技术领域,具体的涉及一种全氟乙烯基醚磺酰氟的制备方法.以全氟乙烯基醚磺酸盐cf2=cf(ocf2Cfx)Mo(Cf2)Nso2Om为原料,在氟化试剂chclfcf2N(C2H5)2,Cf3Chfcf2N(C2H5)2的作用下,直接一步反应生成cf2=cf(ocf2Cfx)Mo(Cf2)Nso2F产品.该制备方法过程简单,容易操作,试剂成本低廉,避免废酸气,废液产生以及多步损耗和副产物增多;缩减反应步骤,同时避免采用高毒高危险性试剂;收率能够达到80%以上.

海关参考信息

专利信息


专利号:US-2007144897-A1
优先权日:2003-03-31
标 题:Method for the electrolytic synthesis of peracetic acid and sterilizing-cleaning method and apparatus
发明人:OHSAKA TAKEO; SAHA MADHU S; UNO MASAHARU; NISHIKI YOSHINORI; FURUTA TSUNETO
权利人:PERMELEC ELECTRODE LTD
摘要:Simple and economic electrolytic synthesis of peracetic acid is performed, and cold drink containers, etc., are sterilized/cleaned with an aqueous solution of peracetic acid thus obtained. Peracetic acid is electrolytically synthesized from acetic acid and/or acetate and an oxygen-containing gas as starting materials in the presence of a solid acid catalyst in an electrolytic cell. An object to be cleaned is sterilized/cleaned with an aqueous solution of peracetic acid thus obtained. Peracetic acid can be simply obtained at a reduced cost. The sterilizing/cleaning of an object to be cleaned with peracetic acid can be conducted efficiently.

专利号:US-2005087449-A1
优先权日:2002-03-04
标题:Electrochemical synthesis of ammonia
发明人:DENVIR ADRIAN; MURPHY OLIVER J; CISAR ALAN; ROBERTSON PRISCILLA; USELTON KYLE
摘要:A method for electrochemical synthesis of ammonia gas comprising providing an electrolyte between an anode and a cathode, providing hydrogen gas to the anode, oxidizing negatively charged nitrogen-containing species present in the electrolyte at the anode to form an adsorbed nitrogen species, and reacting the hydrogen with the adsorbed nitrogen species to form ammonia. Preferably, the hydrogen gas is provided to the anode by passing the hydrogen gas through a porous anode substrate. It is also preferred to produce the negatively charged nitrogen-containing species in the electrolyte by reducing nitrogen gas at the cathode. However, the negatively charged nitrogen-containing species may also be provided by supplying a nitrogen-containing salt, such as lithium nitride, into the molten salt electrolyte mixture in a sufficient amount to provide some or all of the nitrogen consumed in the production of ammonia.

专利号:US-6712950-B2
优先权日:2002-03-04
标 题 :Electrochemical synthesis of ammonia
发明人:DENVIR ADRIAN; MURPHY OLIVER J; CISAR ALAN; ROBERTSON PRISCILLA; USELTON KYLE
权利人:LYNNTECH INC
摘要:A method for electrochemical synthesis of ammonia gas comprising providing an electrolyte between an anode and a cathode, providing hydrogen gas to the anode, oxidizing negatively charged nitrogen-containing species present in the electrolyte at the anode to form an adsorbed nitrogen species, and reacting the hydrogen with the adsorbed nitrogen species to form ammonia. Preferably, the hydrogen gas is provided to the anode by passing the hydrogen gas through a porous anode substrate. It is also preferred to produce the negatively charged nitrogen-containing species in the electrolyte by reducing nitrogen gas at the cathode. However, the negatively charged nitrogen-containing species may also be provided by supplying a nitrogen-containing salt, such as lithium nitride, into the molten salt electrolyte mixture in a sufficient amount to provide some or all of the nitrogen consumed in the production of ammonia.

专利号:US-6881308-B2
优先权日:2002-03-04
标 题 :Electrochemical synthesis of ammonia
发明人:DENVIR ADRIAN J; MURPHY OLIVER J; CISAR ALAN J; ROBERTSON PRISCILLA; USELTON KYLE
权利人:LYNNTECH INC
摘要:A method for electrochemical synthesis of ammonia gas comprising providing an electrolyte between an anode and a cathode, providing hydrogen gas to the anode, oxidizing negatively charged nitrogen-containing species present in the electrolyte at the anode to form an adsorbed nitrogen species, and reacting the hydrogen with the adsorbed nitrogen species to form ammonia. Preferably, the hydrogen gas is provided to the anode by passing the hydrogen gas through a porous anode substrate. It is also preferred to produce the negatively charged nitrogen-containing species in the electrolyte by reducing nitrogen gas at the cathode. However, the negatively charged nitrogen-containing species may also be provided by supplying a nitrogen-containing salt, such as lithium nitride, into the molten salt electrolyte mixture in a sufficient amount to provide some or all of the nitrogen consumed in the production of ammonia.

专利号:EP-1252205-B1
优先权日:1999-12-29
标题:Fluorosulphonated elastomers with low glass transition based of vinylidene fluoride
发明人:AMEDURI BRUNO MICHEL; ARMAND MICHEL; BOUCHER MARIO; MANSERI ABDELLATIF
权利人:HYDRO QUEBEC
摘要:The present invention describes the synthesis of new sulforated fluorinated elastomers having very low glass transition temperatures (Tg), a good resistance to bases, oils and fuels and good properties of workability. These elastomers contain, by way of example, from 80 to 60 mole % of vinylidene fluoride (VDF) and 20 to 40 mole % of perfluoro(4-methyl-3,6-dioxaoct-7-ene) sulfonyl fluoride (PFSO2F). In this case, they are prepared by radical copolymerisation of VDF and PFSO2F in the presence of different organic initiators, for example, peroxides, peresters or diazo compounds.

专利号:US-4176215-A
优先权日:1978-03-13
标题 :Ion-exchange structures of copolymer blends useful in electrolytic cells
发明人:MOLNAR CHARLES J; PRICE EDWARD H; RESNICK PAUL R
权利人:DU PONT
摘要:Ion-exchange films, membranes and laminar structures incorporating a layer of a blend of a first fluorinated polymer which contains sulfonyl groups in ionizable form and a second fluorinated polymer which contains carboxylic acid functional groups, when used to separate the anode and cathode compartments of an electrolysis cell, permit operation at high current efficiency and low power consumption. They can be made by synthesis of precursor polymers in melt-fabricable form, blending, fabrication of the film, membrane or laminar structure, and hydrolysis of the functional groups to ionizable form, such as the free acid form or alkali metal salt thereof.
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合成参考文献


摘要:Ameduri, B., Science of Synthesis Knowledge Updates, (2014) 3, 332.
摘要:National Technical Information Service., OTS0554032
摘要:S25 | OECDPFAS | List of PFAS from the OECD | DOI:10.5281/zenodo.2648775
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