专利号:US-2022145179-A1 优先权日:2020-11-12 标题 :Synthesis of aryl 1-(methoxymethyl) vinyl ketones and their use as inhibitors of mild steel corrosion 发明人:MAZUMDER MOHAMMAD ABU JAFAR; ALI SHAIKH ASROF; ODEWUNMI NURUDEEN; ALHARBI BADER; ALJEABAN NORAH; CHEN TAO; BALHARTH SALEM 权利人:SAUDI ARABIAN OIL CO; UNIV KING FAHD PET & MINERALS 摘要:Methods for preparing alkenylphenone corrosion inhibiting compositions may include providing an arylacetone and reacting the arylacetone with formaldehyde in the presence of a strong base catalyst. Corrosion inhibiting compositions may include an alkenylphenone, which may be prepared by a method including providing an arylacetone and reacting the arylacetone with formaldehyde in the presence of a strong base catalyst. Methods of inhibiting corrosion of a steel surface of an oilfield equipment component may include contacting the steel surface with an aqueous solution comprising a corrosion inhibitor. The corrosion inhibitor may include a composition containing an alkenylphenone prepared by reacting an arylacetone with formaldehyde in the presence of a strong base catalyst.
专利号:US-5059709-A 优先权日:1990-11-13 标题 :Process for the synthesis of α-[(dialkylamino)substituted-methylene]-β-oxo-(substituted)propanentriles 发明人:DUSZA JOHN P; CHURCH ROBERT F 权利人:AMERICAN CYANAMID CO 摘要:A novel process for producing α-[(dialkylamino) substituted-methylene]β-oxo-(substituted) propanenitriles of the formula: ##STR1## where R, R 1 and R 2 are defined in the specification by reacting a substituted isoxazole with a diaklylamide dimethylacetal is provided.
专利号:WO-9910310-A1 优先权日:1997-08-29 标 题:Process for producing diphenylethers and esters 发明人:LOURENS GERHARDUS JOHANNES 权利人:DOW CHEMICAL CO 摘要:An improved synthesis of diphenylethers, and in particular, the bacteriostat 2,4,4'-trichloro-2'-hydroxydiphenylether, is described wherein 2'-acetyl-2,4,4'-trichlorodiphenylether is oxidised under Baeyer-Villiger conditions to produce 2'-acetoxy-2,4,4'-trichlorodiphenylether in near quantitative yield. Best oxidative conditions include the use of anhydrous permaleic acid produced in situ. The ester is purified readily by simple recrystallization, as no dibenzofurans and only minor amounts of byproducts are formed in the process. The ester is converted into the desired halogenated phenolic diphenylether, 2,4,4'-trichloro-2'-hydroxydiphenylether, by hydrolysis or transesterification. The final product is purified to a high degree by vacuum distillation and crystallization to meet current purity standards for approved applications.
专利号:KR-20090049001-A 优先权日:2007-11-12 标 题:Synthesis of itrconazole antifungal derivatives and used it by derivatives of p-aminobenzoyl-l-glutamic acids
专利号:WO-2022104049-A1 优先权日:2020-11-12 标题 :Synthesis of aryl 1-(methoxymethyl) vinyl ketones and their use as inhibitors of mild steel corrosion
专利号:RU-2043342-C1 优先权日:1992-01-14 标题:Method of synthesis of 1-[2-(2,4-dichlorophenyl)-2- (2,4- dichlorophenylmethoxy)]- ethylimidazole nitrate
[参考文献]: A Brundin, Et Al. Glutathione-Dependent Reductive Dehalogenation Of 2,2',4'-Trichloroacetophenone To 2',4'-Dichloroacetophenone. Biochem Pharmacol. 1982 Dec 1;31(23):3885-90.
合成参考文献
摘要:Sharma, U.; Kumar, R.; Gupta, S. S.; Chandra, D., Science of Synthesis Knowledge Updates, (2022) 2, 360. 摘要:Podlech, J., Science of Synthesis Knowledge Updates, (2013) 2, 269.