90-15-3 = 575-38-2 + 524-42-5 + 83-56-7 + 130-15-4 + 132-86-5 + 575-44-0 + 569-42-6 反应条件:1.1 Reagents: Water,Potassium Ferricyanide; Rt 标题:Oh Radical As A Probe Of The Spin Polarizability In 1- And 2-Naphthol 作者:Albarran,Guadalupe; Et Al 参考文献:Journal Of Physical Chemistry A 日期:2018 卷标:122(16) 页码:4015-4022
2-氨基-8-萘酚-6-磺酸置于硫酸体系中,化学反应生成 1,7-二羟基萘 参考文献:Leman,Annales De Chimie (Cachan,France),1938,Vol. <11> 9,P. 357,384 标题:Leman,Annales De Chimie (Cachan,France),1938,Vol. <11> 9,P. 357,384
专利号:US-9815809-B2 优先权日:2013-07-05 标题:Formation of chiral 4-chromanones using chiral pyrrolidines in the presence of phenols or thiophenols 发明人:LETINOIS ULLA; NETSCHER THOMAS 权利人:DSM IP ASSETS BV 摘要:The present invention relates to a synthesis of chromanones or chromanes in a stereospecific matter in view of the 2-position in the chromanone or chromane ring. It has been found that this synthesis is particularly possible in the presence of a chiral compound of formula of a specific type and of at least one phenol or thiophenol.
专利号:US-3806522-A 优先权日:1972-12-11 标题 :Process for the preparation of 3-acyloxy-3-(3'-lower carboalkoxy-4'-hydroxy-1'-naphthyl)naphthalide 发明人:FEINGOLD M 权利人:POLAROID CORP 摘要:THIS INVENTION RELATES TO THE SYNTHESIS OF 3-ACYOXYL-3(3''-LOWER CARBOALKOXY-4''-HYDROXY - 1'' - CAPHTHYL)NAPHTHALIDES BY THE REACTION OF A 3-(3''-LOWER CARBOALXY-4''-OXO1''-NAPHTHYLIDENE)NAPHTHALIDE AND AN ORGANIC CARBOXYLIC ACID
专利号:US-3829443-A 优先权日:1973-02-28 标题 :Synthesis of 3-(3'-carboxy-4'-hydroxy-1'-naphthyl)-3-(3'-carboxy-4'-hydroxy-1'-naphthyl)naphthalide 发明人:BADER H; JANUARY S 权利人:POLAROID CORP 摘要:CARBOXY SUBSTITUTED 1-NAPHTHOL NAPHTHALIDE INDICATOR DYES ARE PREPARED BY REACTING A 2-CARBOXY-1-NAPHTHOL AND A 3-ACYLOXY -3-(3''-LOWER CARBOALKOXY-4''-HYDROXY-1''-NAPHTHYL)NAPHTHALIDE IN THE PRESENCE OF A CATALYST HAVEING A HIGH DIPLOE MOMENT TO FORM THE CORRESPONDING DYE PECURSOR WHICH IS THEN HYDROLYZED TO YIELD THE CORRESPONDING INDICATOR DYE PRODUCT.
专利号:US-2007243147-A1 优先权日:2004-07-24 标 题:Skin and/or Hair Composition Containing Compounds for Increasing The Tanning of Skin 发明人:WOLBER RAINER; TOM DIECK KAREN; SCHERNER CATHRIN; SCHLENZ KATHRIN; KRUSE INGE 权利人:BEIERSDORF AG 摘要:The invention relates to agents that are to be applied to the skin or hair and contain compounds for intensifying tanning of the skin and increasing melanin synthesis in skin or hair. The invention particularly relates to cosmetic or dermatological preparations. Using said preparations results in inducing and intensifying the tanning mechanisms of the skin, intensifying the hair color, and thus also increasing intrinsic protection of the skin or hair.
专利号:US-2007189984-A1 优先权日:2003-09-08 标题:Agents for use on skin and/or hair containing quadruply substituted cyclohexene compounds 发明人:WOLBER RAINER; SCHERNER CATHRIN; TOM DIECK KAREN; SCHLENZ KATHRIN; VIETZKE JENS-PETER 权利人:BEIERSDORF AF 摘要:The invention relates to agents for use on skin or hair, particularly for increasing skin tanning and the synthesis of melanin in skin or hair. The invention contains, in particular, cosmetic or dermatological preparations containing quadruply substituted cyclohexene compounds. The use of the preparations leads to the induction and intensification of the tanning mechanisms of skin, the intensification of hair color and thus also to an intensification of the skin's and hair's intrinsic protection.
专利号:US-2011230343-A1 优先权日:2008-10-24 标题 :Method for the Manufacture of Microparticles Comprising an Effect Substance 发明人:SCHROERS MICHAEL; DYLLICK-BRENZINGER RAINER; MERK MICHAEL; BARG HEIKO 权利人:BASF SE 摘要:A subject matter of the present invention is a process for the preparation of effect compound-comprising microparticles M comprising A) the formation of a crude suspension of microparticles A by means of enzymatic polyester synthesis in an inverse miniemulsion comprising enzyme, effect compound and polyester monomers; and B) the polymerization of wall monomers from the group consisting of ethylenically unsaturated monomers, polyisocyanates and polyepoxides in the crude suspension of microparticles A. Furthermore, the present invention relates to microparticles M which can be obtained by means of the process according to the invention and also to an agrochemical formulation comprising microparticles M. In addition, the present invention relates to the use of microparticles M prepared according to the invention as component in colorants, cosmetics, drugs, biocides, plant protection agents, fertilizers, additives for food or animal fodder, or auxiliaries for polymers, paper, textiles, leather, detergents or cleaners. Finally, the invention also relates to a method for combating undesirable plant growth, to a method for combating undesirable insect or acarid infestation on plants and/or for combating phytopathogenic fungi, and to seeds treated with the agrochemical formulation.
参考标题:Organophotocatalytic Aerobic Oxygenation Of Phenols In A Visible‐light Continuous‐flow Photoreactor 作者:Joël Wellauer,Dragan Miladinov,Thomas Buchholz,Jan Schütz,René T. Stemmler,Jonathan A. Medlock,Werner Bonrath,Christof Sparr |发布日期:2021.7.7 摘要:A Mild Photocatalytic Phenol Oxygenation Enabled By A Continuous-Flow Photoreactor Using Visible Light And Pressurized Air Is Described Herein. Products For Wide-Ranging Applications, Including The Synthesis Of Vitamins, Were Obtained In High Yields By Precisely Controlling Principal Process Parameters. The Reactor Design Permits Low Organophotocatalyst Loadings To Generate Singlet Oxygen. It Is Anticipated
合成参考文献
参考文献:10.1038/nchembio.2285 摘要:Elshahawi SI, Cao H, Shaaban KA, Ponomareva LV, Subramanian T, Farman ML, Spielmann HP, Phillips GN, Thorson JS, Singh S. Structure and specificity of a permissive bacterial C-prenyltransferase. Nature Chemical Biology. 2017 Feb 06;13(4):366–8. doi: 10.1038/nchembio.2285.