合成目标产物 Methylphenyldiethoxysilane 主要起始原料 Diethoxymethylsilane And Benzene
(文献来源)合成步骤主要原料 Diethoxymethylsilane 和 Benzene
甲基三乙氧基硅烷置于mg体系中,用 Not Given 作为反应溶剂,化学反应生成 二乙氧基甲基苯基硅烷 参考文献:Synthesis Of Methylphenyldisiloxanes 标题:Synthesis Of Methylphenyldisiloxanes 摘要: DOI:10.1021/ja01122A029
专利号:US-11033507-B2 优先权日:2013-12-19 标 题 :Method of synthesis of silica vesicles and use thereof 发明人:YU CHENGZHONG; MITTER NEENA; ZHANG JUN 权利人:UNIV QUEENSLAND 摘要:The invention relates, in part, to a method of producing silica vesicles including under controlled conditions to thereby heavily influence the morphology and characteristics of the vesicles. The vesicles are shown to be effective as delivery agents for chemical and biological agents. They are also shown to be useful in methods of treatment and as components of an immunogenic composition.
专利号:US-4777278-A 优先权日:1987-10-08 标题 :Synthesis of alkyl cycloalkyl dialkoxysilanes 发明人:BAND ELLIOT I; EBERHART SUZANNE T 权利人:AKZO AMERICA INC 摘要:Alkyl cycloalkyl dialkoxysilanes (e.g., methyl cyclohexyl dimethoxysilane) can be prepared by reaction of an alkyl trialkoxysilane (e.g., methyl trimethoxysilane) with a Grignard reagent containing the cycloalkyl moiety derived in the final end-product (e.g., a reagent formed by reacting cyclohexyl chloride and magnesium metal). The reaction is run in the absence of ether solvent, the Grignard reagent is preferably formed in situ by the reaction of magnesium metal and cyclohexyl halide, and agitation is used to promote the reaction. Advantageously, a catalyst, such as iodine, is used to promote the reaction.
专利号:US-2022355262-A1 优先权日:2019-07-22 标题 :System and method for manufacturing water-based hydrophobic aerogels and aerogel composites 发明人:SACHITHANADAM MAHESH; KHORASGANI SOGHRATI ELMIRA; NATARAJAN GAYATHRI 权利人:KROSSLINKER PTE LTD 摘要:Embodiments of the present invention provide users with a system and method for manufacturing water-based hydrophobic aerogels and aerogel composites. The system and method can be carried out in a manner which is more rapid than typical ways and can be readily scalable. The method of manufacture is useful for producing water based hydrophobic aerogels and aerogel composites on a large scale with good homogeneity and consistency. Advantageously, the method of manufacture also has the benefit of a shorter processing time due to the vacuum homogenizing and mixing processes, the use of microwave assisted vacuum freeze drying for ease of synthesis of water-based hydrophobic aerogels.
专利号:US-9884879-B2 优先权日:2011-06-14 标 题:Method of synthesizing siloxane monomers and use thereof 发明人:PAULASAARI JYRI 权利人:SILECS OY 摘要:A method for preparation and polymerization of siloxane monomers of Formula I is presented. The synthesis includes the selective reaction between silanol containing unit and alkoxy containing units in the presence of basic catalyst. The siloxane monomers of the invention can be used for preparation of siloxane polymers with good flexibility and cracking threshold, and functional sites, useful for applications requiring low metal content in semiconductor industry.
专利号:US-2018193278-A1 优先权日:2013-12-19 标题 :Method of synthesis of silica vesicles and use thereof
专利号:CA-2933910-A1 优先权日:2013-12-19 标 题 :Method of synthesis of silica vesicles and use thereof
参考标题:Synthesis Of Esters By Functionalisation Of Co2 摘要:The Invention Relates To A Method For (I) Producing A Carboxylic Ester Of Formula (I). Said Method Comprises The Steps Of: A) Bringing An Organosilane/borane Of Formula Si Or B Into Contact With Co 2 , In The Presence Of A Catalyst And An Electrophilic Compound Of Formula (III), The Groups R 1 , R 2 , R 3 , R 4 , R 5 , Y, And M′ Being As Defined In Claim 1; And Optionally B) Recovering The Compound Of Formula (I) Produced.
合成参考文献
参考文献:10.1007/978-1-4899-0112-5_56 摘要:Belleville P. Sol-Gel Technology for French Inertial Confinement Fusion Program. 1998. In: Science and Technology of Polymers and Advanced Materials. : Springer US; 1998. 参考文献:10.1007/bf00486334 摘要:Floch HG, Belleville PF. Damage-resistant sol-gel optical coatings for advanced lasers at CEL-V. Journal of Sol-Gel Science and Technology. 1994 Jan;2(1-3):695–705. doi: 10.1007/bf00486334. 参考文献:10.1007/bf00860013 摘要:Andrianov KA, Delazari NV, Volkova LM, Bogdanova OK. Synthesis and polymerization of 2,2,6-trimethyl-6-alkyl(aryl)-1-oxa-2,6-disilacyclohexanes. Russian Chemical Bulletin. 1971 Aug;20(8):1610–5. doi: 10.1007/bf00860013. 参考文献:10.1007/bf02516281 摘要:Csákvári B, Csákvári É, Gömöry P, Vértes A. Mössbauer study of the donor character of oxygen in Si−O bonds. Journal of Radioanalytical and Nuclear Chemistry. 1975 Sep;25(2):275–82. doi: 10.1007/bf02516281.