CAS: 4766-57-8; Tetrabutyl Orthosilicate

该化合物是一种多用途前体,能够将硅基材料与受控孔隙和同质性合成.TBOS具有高纯度,稳定性和在温和条件下的抗反应性价值,适合涂层,粘合剂和薄膜沉积方面的应用.它的丁氧基组有利于水解和凝聚反应,产生具有定制特性的统一硅基质.TBOS还被用作聚合物中的交叉剂和催化剂支持.其低挥发性和与有机溶剂的兼容性提高了工业和研究环境中的可加工性.

结构式图片

相似化合物

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合成工艺路线路线简述

    乙酸丁酯置于tetrabutoxytitanium,硅酸四乙酯体系中,用96%的收率获得产物正硅酸丁酯
    参考文献:Khonina; Suvorov; Soldatova,Russian Journal Of General Chemistry,1997,Vol. 67,# 5,P. 729-732
    标题:Khonina; Suvorov; Soldatova,Russian Journal Of General Chemistry,1997,Vol. 67,# 5,P. 729-732

    海关参考信息

    专利信息


    专利号:US-6540970-B1
    优先权日:1999-11-18
    标题:Method for the synthesis of molecular sieves
    发明人:STROHMAIER KARL G; VAUGHAN DAVID E W
    权利人:EXXON MOBIL CHEM PATENTS INC
    摘要:The present invention provides a method for the synthesis of MeAPO molecular sieves which includes the following steps: providing a source of alumina, a source of phosphorus, water, and a template suitable for forming a MeAPO molecular sieve; providing a source of metal (Me) including metal particles, the metal particles measuring, in their largest dimension, equal to or less than five nanometers; providing a water soluble organic solvent capable of solubilizing the source of metal; forming a synthesis mixture from the source of alumina, the source of phosphorus, the water, the template, the source of metal, and the solvent; and forming a MeAPO molecular sieve from the synthesis mixture.

    专利号:US-10661239-B2
    优先权日:2016-04-29
    标 题 :Catalytic reactor configuration, preparation and method of direct synthesis of ethylene through oxygen-free catalysis of methane
    发明人:BAO XINHE; GUO XIAOGUANG; FANG GUANGZONG; PAN XIULIAN; MENG JINGHENG; YU QINQIN; TAN DALI
    权利人:DALIAN INST CHEM & PHYSICS CAS
    摘要:A reactor configuration comprises an inlet section I, a preheating section II, a transition section III, a reaction section IV and an outlet section V; except for the preheating section II and the reaction section IV, the existence of the inlet section I, the transition section III and the outlet section V depends on reaction conditions; and the process realizes no coke deposition synthesis of methane and high selectivity synthesis of ethylene. The methane conversion rate is 20-90%; ethylene selectivity is 65-95%; propylene and butylene selectivity is 5-25%; aromatic hydrocarbon selectivity is 0-30%; and coke deposition is zero.

    专利号:US-9714174-B2
    优先权日:2012-07-19
    标题:Methods of controlling polymorphism in organic-free synthesis of Na-zeolites and zeolite crystals formed therefrom
    发明人:RIMER JEFFREY D; MALDONADO MIGUEL; OLEKSIAK MATTHEW D
    权利人:RIMER JEFFREY D; MALDONADO MIGUEL; OLEKSIAK MATTHEW D; UNIV HOUSTON SYSTEM
    摘要:Methods of controlling crystal polymorphism in organic-free synthesis of Na-Zeolites and the zeolite crystals formed using those methods are provided. The methods disclosed herein create certain types of zeolite crystals more efficiently than other previously known methods. The methods also create certain types of zeolite crystals in a form and concentration not previously disclosed. The methods disclosed herein generally comprise using solutions with varying ratios of silicon (Si), aluminum (Al), hydroxide (OH), and water. Some implementations of the invention disclosed include efficient methods of producing nearly pure cancrinite (CAN), methods of obtaining sodalite in solutions with a high Si/Al ratio, and a method of forming thin, platelet-like ANA crystals with a width of less than about 1 μm and a length of at least about 3 μm.

    专利号:US-2010119736-A1
    优先权日:2008-10-07
    标题 :Ambient pressure synthesis of zeolite films and their application as corrosion resistant coatings
    发明人:YAN YUSHAN; CAI RUI; SUN MINWEI
    权利人:UNIV CALIFORNIA
    摘要:A method for producing zeolite films or membranes at essentially ambient pressure, which includes preparing a synthesis mixture comprising an ionic liquid solvent and an aluminum and/or silicon and/or phosphate source and converting the synthesis mixture to form a continuous zeolite layer. In addition, a method of synthesizing zeolite nanocrystals, which includes preparing a synthesis mixture, the synthesis mixture having a silica or a silica and alumina source, and a template; and synthesizing the synthesis mixture to form zeolite nanocrystals.

    专利号:US-11685663-B2
    优先权日:2021-06-14
    标 题 :Method for manufacture of mesoporous silica in the presence of water-soluble ODSO
    发明人:HODGKINS ROBERT PETER; KOSEOGLU OMER REFA
    权利人:SAUDI ARABIAN OIL CO
    摘要:Methods of synthesis of mesoporous silica are disclosed. The mesoporous silica synthesized herein, like SBA-15, possesses a two-dimensional, hexagonal, through-hole structure with a space group p6mm. An effective quantity of one or more water-soluble oxidized disulfide oil (ODSO) compounds are used during synthesis to impart distinct characteristics.

    专利号:US-12312244-B2
    优先权日:2021-06-14
    标题:Method for manufacture of mesoporous silica in the presence of thermally expandable microcells
    发明人:HODGKINS ROBERT PETER; KOSEOGLU OMER REFA
    权利人:SAUDI ARABIAN OIL CO
    摘要:Methods of synthesis of mesoporous silica are disclosed. The mesoporous silica synthesized herein, like SBA-15, possesses a two-dimensional, hexagonal, through-hole structure with a space group p6mm. An effective quantity of one or more thermally expandable microcells are used during synthesis to impart distinct characteristics.
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    ✅ COA系统入驻 | 共享模式

    主要参考文献

    参考标题:Synthesis Of Aryl Ethers From Aromatic Carboxylic Acids
    作者:Lukas Gooßen,Sukalyan Bhadra,Wojciech Dzik
    摘要:Meta-Substituted Carboxylates Are Converted Into Para-Substituted Alkoxyarenes And Vice Versa. The Combined Processes Provide A Convenient Synthetic Entry To The Important Class Of Aromatic Ethers From Widely Available Carboxylic Acids. A Silver/copper Bimetallic Catalyst System Promotes The Decarboxylative Chan-Evans-Lam Alkoxylation Of Ortho-Substituted Aromatic Carboxylate Salts With Tetraalkyl Orthosilicates

    合成参考文献


    摘要:Virieux, D.; Ayad, T.; Pirat, J.-L.; Volle, J.-N., Science of Synthesis Knowledge Updates, (2018) 1, 280.
    摘要:Cui, X.; Zhang, X. P., Science of Synthesis: Catalytic Transformations via CH Activation, (2015) 2, 82.
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