合成目标产物 Di-P-Tolylamine 主要起始原料 4-Bromotoluene And P-Toluidine
(文献来源)合成步骤主要原料 4-Bromotoluene 和 P-Toluidine
4-甲基环己酮置于尿素体系中,用 二乙二醇二甲醚,水 作为反应溶剂,150.0 °C,101.33 Kpa 条件下,反应 24.0H,以84%的收率获得产物4,4'-二甲基二苯胺 参考文献:Formal Arylation Of Nh3 To Produce Diphenylamines Over Supported Pd Catalysts 标题:Formal Arylation Of Nh3 To Produce Diphenylamines Over Supported Pd Catalysts 摘要:在pd/al2O3存在下,可以通过以尿素为氮源,环己酮为芳基化源进行无受体形式芳基化合成各种二苯胺. DOI:10.1039/c7Cc06737B
专利号:WO-2018217538-A1 优先权日:2017-05-23 标题 :Synthesis of substituted acridines 发明人:FORT ERIC H; JAYE JOSEPH A; MCCORMICK GRANT M; BERGER KRISTEN E 权利人:UNIV OF ST THOMAS 摘要:Disclosed is a method of making substituted acridines. The method includes the step of reacting a bis(halophenyl) amine with an alkyne for a time and at a temperature to yield a substituted acridine.
专利号:US-2018361327-A1 优先权日:2016-02-26 标题 :Gas separation membrane, gas separation module, gas separator, gas separation method, composition for forming gas separation layer, method of producing gas separation membrane, polyimide compound, and diamine monomer 发明人:KODAMA KEISUKE; SAWADA MAKOTO; WADA KENJI 权利人:FUJIFILM CORP 摘要:A gas separation membrane including a gas separation layer contains a crosslinked polyimide compound. In the gas separation membrane, and a gas separation module, a gas separator, and a gas separation method obtained by using the gas separation membrane, the crosslinked polyimide compound has a specific structural portion. A composition for forming a gas separation layer suitable for forming a gas separation layer of the gas separation membrane; a method of producing a gas separation membrane obtained by using this composition; a polyimide compound suitable as a raw material of a gas separation layer of the gas separation membrane; and a diamine monomer suitable for synthesis of this polyimide compound are provided.
专利号:US-7408085-B2 优先权日:2006-11-28 标 题:Rapid cost effective method for the synthesis of TPD-type arylamines 发明人:BENDER TIMOTHY P; COGGAN JENNIFER A; MCGUIRE GREGORY; MURPHY LEANNE DAWN; TOTH ALAN EDWARD JOHN 权利人:XEROX CORP 摘要:A process for forming a tetra(aryl)-biphenyldiamine compound, including reacting a dibromobiphenyl compound and a diarylamine compound in the presence of a palladium ligated catalyst and a base.
专利号:US-11174213-B2 优先权日:2018-10-12 标题:Effects of catalyst concentration and solid activator on nickel-mediated olefin/carbon dioxide coupling to acrylates 发明人:Iacono Pasquale; HLAVINKA MARK L 权利人:CHEVRON PHILLIPS CHEMICAL CO LP 摘要:This disclosure provides for routes of synthesis of acrylic acid and other α,β-unsaturated carboxylic acids and their salts, including catalytic methods. For example, there is provided a process for producing an α,β-unsaturated carboxylic acid or a salt thereof, the process comprising: (1) contacting in any order, a group 8-11 transition metal precursor, an olefin, carbon dioxide, a diluent, and a metal-treated chemically-modified solid oxide such as a sulfur oxoacid anion-modified solid oxide, a phosphorus oxoacid anion-modified solid oxide, or a halide ion-modified solid oxide, to provide a reaction mixture; and (2) applying reaction conditions to the reaction mixture suitable to produce the α,β-unsaturated carboxylic acid or the salt thereof. Methods of regenerating the metal-treated chemically-modified solid oxide are described.
专利号:US-10207974-B1 优先权日:2017-12-05 标 题 :Synthesis of gamma dicarbonyl and pyrrole compounds 发明人:LASSEN KENNETH M 权利人:CHEVRON PHILLIPS CHEMICAL CO LP 摘要:The present invention discloses processes for producing γ-dicarbonyl compounds by contacting an aldehyde compound, an α,β-unsaturated carbonyl compound, and a catalyst composition in the presence of an amide diluent. The resultant γ-dicarbonyl compounds then can be used to synthesize pyrrole compounds, such as 2,5-dimethylpyrrole.
专利号:US-9663594-B2 优先权日:2014-05-15 标 题 :Synthesis of aryl coupled bis phenoxides and their use in olefin polymerization catalyst systems with activator-supports 发明人:HLAVINKA MARK L 权利人:CHEVRON PHILLIPS CHEMICAL CO LP; CHEVRON PHILIPS CHEMICAL COMPANY LP 摘要:Disclosed herein are methods of making bis(phenol) ligand compounds and transition metal bis(phenolate) compounds. The transition metal bis(phenolate) compounds can be used as components in catalyst systems for the polymerization of olefins.
摘要:Li, Y.; Xie, W.; Jiang, X., Science of Synthesis Knowledge Updates, (2016) 2, 8. 摘要:Silva, V. L. M.; Pinto, D. C. G. A.; Santos, C. M. M.; Rocha, D. H. A., Science of Synthesis Knowledge Updates, (2022) 3, 201. 摘要:Zhang, J.; Liu, D.; Chen, Y., Science of Synthesis, (2021) , 373. 摘要:Das, A.; Sarmah, B. K., Science of Synthesis: Knowledge Updates, (2024) 1, 343. 摘要:Wang, L.; Liu, M.; Cheng, J., Science of Synthesis: Knowledge Updates, (2024) 1, 190.