专利号:US-2010191010-A1 优先权日:2007-07-02 标题 :Process for the synthesis of carbamates using co2 发明人:BOSMAN JORIS KAREL PETER; CARR ROBERT HENRY 权利人:HUNTSMAN INT LLC 摘要:Process for the synthesis of non cyclic carbamate derivatives from amine compounds, alcohols and CO 2 in the presence of ionic liquids and optionally in the presence of a base.
专利号:US-12392085-B2 优先权日:2020-04-28 标题 :Use of in-situ ionic liquid (IL) and deep eutectic solvent (DES) synthesis using chemically synthesized or biomass-derived ions in the pretreatment of biomass 发明人:MAGURUDENIYA HARSHA D; ACHINIVU EZINNE; SIMMONS BLAKE A; GLADDEN JOHN M 权利人:UNIV CALIFORNIA; NATIONAL TECH AND ENGINEERING SOLUTIONS OF SANDIA LLC; NAT TECH & ENG SOLUTIONS SANDIA LLC 摘要:The present invention provides for a method to deconstruct a biomass comprising: (a) introducing one or more individual components of an ionic liquid (IL) or deep eutectic solvent (DES) to a biomass, wherein the one or more individual components, and optionally any components already present in the biomass, form an IL or DES, or mixture thereof, which solubilizes the biomass to form a solubilized biomass mixture, wherein at least one individual component is introduced to the biomass separately from any other individual component; (b) optionally introducing an enzyme and/or a microbe to the solubilized biomass mixture such that the enzyme and/or microbe produces a sugar from the solubilized biomass mixture; and, (c) optionally separating the sugar from the solubilized biomass mixture.
专利号:US-2014001420-A1 优先权日:2011-09-30 标题 :Method of preparing metal nanoparticles 发明人:DRZAL LAWRENCE T; DO IN-HWAN 权利人:DRZAL LAWRENCE T; DO IN-HWAN 摘要:A method for the synthesis of new metal based metal nanoparticles by the combination of conducting polymers and room temperature ionic liquids to produce nanoparticle electro-catalysts with very high catalytic activity and controllable size and high surface area to volume ratios.
专利号:US-9765044-B2 优先权日:2013-03-15 标 题 :Synthesis of novel ionic liquids from lignin-derived compounds 发明人:SOCHA AARON; SINGH SEEMA; SIMMONS BLAKE A; BERGERON MAXIME 权利人:UNIV CALIFORNIA; SANDIA CORP 摘要:Methods and compositions are provided for synthesizing ionic liquids from lignin derived compounds comprising: contacting a starting material comprising lignin with a depolymerization agent to depolymerize the lignin and form a mixture of aldehyde containing compounds; contacting the mixture of aldehyde containing compounds with an amine under conditions suitable to convert the mixture of aldehyde containing compounds to a mixture of amine containing compounds; and contacting the mixture of amine containing compounds with an acid under conditions suitable to form an ammonium salt, thereby preparing the ionic liquid.
专利号:US-9199956-B2 优先权日:2012-01-03 标题:Process for chemical conversion of cellulose isolated from aromatic spent biomass to hydroxymethyl furfural 发明人:ROUT PRASANTA KUMAR; NANNAWARE ASHWEEN DEEPAK; RAJASEKHARAN RAM 权利人:COUNCIL SCIENT IND RES 摘要:The present invention relates to a process for chemical conversion of cellulose isolated from aromatic spent biomass to hydroxymethyl furfural using an eco-friendly and economical liquids system with recoverable and reusable solid Indion catalysts and zeolite-phosphomolybdic acid hybrid catalysts. The present invention further relates to the preparation of an effective hybrid catalyst i.e. zeolite-phosphomolybdic acid catalyst for synthesis of HMF. The selectivity and yield of HMF is nearly doubled in zeolite-phosphomolybdic acid hybrid catalyst compared to the individual catalysts (zeolite or phosphomolybdic acid) or combination of catalysts viz. zeolite and phosphomolybdic acid.
专利号:US-6939974-B2 优先权日:2000-04-07 标 题:Imidazole carbenes 发明人:EARLE JOHN MARTYN; SEDDON RICHARD KENNETH 权利人:UNIV BELFAST 摘要:The disclosure herein relates to imidazole carbenes and imidazole carbene salts. The disclosure also relates to the synthesis of imidazole carbenes and imidazole carbene salts. The imidazole carbenes disclosed include those synthesized by reacting an imidazole halide with a base under reduced pressure. The imidazole carbene salts disclosed include those synthesized by reaction of imidazole carbenes with an acid or alcohol suitable for creation of a salt. The disclosure also relates to the use of imidazole carbenes and imidazole carbene salts for the synthesis of organic liquids.
参考文献:10.1007/s41061-017-0108-9 摘要:Liu X, He LN. Synthesis of Lactones and Other Heterocycles. Top Curr Chem (Cham). 2017 Apr;375(2):21. doi: 10.1007/s41061-017-0108-9. 参考文献:10.1007/s41061-017-0110-2 摘要:Schröder C. Proteins in Ionic Liquids: Current Status of Experiments and Simulations. Topics in Current Chemistry. 2017 Feb 07;375(2):25. doi: 10.1007/s41061-017-0110-2.