3-乙酰基吡咯置于三氟乙酸体系中,化学反应 7.0H,反应生成2-乙酰基吡咯 参考文献:Acid-Mediated Rearrangement Of Acylpyrroles 标题:Acid-Mediated Rearrangement Of Acylpyrroles 摘要: Doi:10.1021/jo00318A002
专利信息
专利号:US-5304568-A 优先权日:1992-04-14 标题:Ethyl-triazolyl derivatives 发明人:SCHERKENBECK JUERGEN; LINDEMANN MICHAEL; DUTZMANN STEFAN; DEHNE HEINZ-WILHELM 权利人:BAYER AG 摘要:New ethyl-triazolyl derivatives of the formula (I) in which R represents halogen, X1 represents fluorine, chlorine or bromine, X2 represents fluorine, chlorine or bromine, Z represents halogen, alkyl having 1 to 4 carbon atoms, alkoxy having 1 to 4 carbon atoms, ethyl having 1 or 2 carbon atoms and 1 to 5 halogen atoms, halogenoalkoxy having 1 or 2 carbon atoms and 1 to 5 halogen atoms, phenyl, phenoxy, nitro or alkoximinoalkyl having 1 to 4 carbon atoms in the alkoxy moiety and 1 to 4 carbon atoms in the alkyl moiety and m represents the numbers 0, 1, 2 or 3, and addition products thereof with acids or metal salts are very effective for combating fungi. Novel ethyl-triazolyl derivatives of the formula (II) in which R, Z and m have the abovementioned meanings, and addition products thereof with acids or metal salts are very effective for combating fungi. The ethyl-triazolyl derivatives of the formula (II) are also valuable intermediates for the synthesis of ethyl-triazolyl derivatives of the formula (I).
专利号:EP-0304552-A1 优先权日:1987-06-03 标题:Heterocyclic hydroxyazoles 发明人:JAUTELAT MANFRED DR; DUTZMANN STEFAN DR 权利人:BAYER AG 摘要:New heterocyclic hydroxyethyl azoles of the formula in which A represents a nitrogen atom or a CH group, Y represents the groups -CH2-CH2-, -CH = CH- or -C ^ C-, R¹ represents optionally substituted Alkyl, optionally substituted alkenyl, optionally substituted cycloalkyl or for optionally substituted aryl and Het stands for an optionally substituted and optionally benzanellated, five- or six-membered heterocyclic radical having up to 3 heteroatoms, and their acid addition salts and metal salt complexes, processes for the preparation of the new substances and their use as fungicides and plant growth regulators. New alkynols of the formula in which A and R¹ have the meaning given above, processes for their preparation and their use as intermediates for the synthesis of heterocyclic hydroxyethyl azoles of the formula (I).
专利号:US-2025074844-A1 优先权日:2023-08-28 标 题:Polyalphaolefins made from dimer olefins obtained from branched c10 monoolefins using solid acid catalyst 发明人:MALINSKI THOMAS; GEE JEFFREY C; BISCHOF STEVEN M; KERNS SPENCER A; HILLIER JAMES; WEBSTER-GARDINER MICHAEL S 权利人:CHEVRON PHILLIPS CHEMICAL CO LP 摘要:Synthesis of polyalphaolefins by oligomerization of one or more branched C 10 monoolefins with a solid acid catalyst to form an oligomer product, followed by hydrogenation of a C 20+ olefin portion of the oligomer product to form the polyalphaolefins. The solid acid catalyst is selective to C 20 olefin dimers.
专利号:US-2025075015-A1 优先权日:2023-08-28 标题 :Polyalphaolefins made from dimer olefins obtained from branched c10 monoolefins using alkyl aluminum catalyst 发明人:MALINSKI THOMAS; KERNS SPENCER A; LESEBERG JULIE A; GEE JEFFREY C; BISCHOF STEVEN M; HILLIER JAMES; WEBSTER-GARDINER MICHAEL S 权利人:CHEVRON PHILLIPS CHEMICAL CO LP 摘要:Synthesis of polyalphaolefins by oligomerization of one or more branched C 10 monoolefins with an alkyl aluminum catalyst to form an oligomer product, followed by hydrogenation of a C 20+ olefin portion of the oligomer product to form the polyalphaolefins. The alkyl aluminum catalyst is selective to C 20 olefin dimers.
专利号:CN-101289694-A 优先权日:2005-01-25 标 题 :Nucleic acid for enhancing synthesis of 2-acetyl-1-pyrrole of plant and fungus
专利号:EP-0436481-A1 优先权日:1990-01-04 标 题 :Process for preparing 2-acetyl-1-aza-1-cycloalkenes useful as flavor components for bread and rice 发明人:DE KIMPE NORBERT DR IR; STEVENS CHRIS; SCHAMP NICEAS PROF DR 权利人:RIJKSUNIVERSITEIT GENT FACULTE 摘要:Straightforvard and inexpensive syntheses of 2-acetyl-1-aza-1-cycloalkenes usefull as bread and rice flavor components, i.e. 2-acetyl-1,4,5,6-tetrahydropyridine and 2-acetyl-1-pyrroline, respectively, comprise the following steps :n oxidation of cyclic amines to cyclic imines; subsequent cyanation of cyclic amines to 2-cyano-1-azacycloalkanes ; oxidation of 2-cyano-1-azacycloalkanes to 2-cyano-1-aza-1-cycloalkenes; synthesis of 2-acetyl-1-aza-1-cycloalkenes by a Grignard reaction. n These syntheses give rise to the title compounds, free of side products, in a way easily amenable to industrial production.
参考标题:Autoxidation/aldol Tandem Reaction Of 2-Oxindoles With Ketones: A Green Approach For The Synthesis Of 3-Hydroxy-2-Oxindoles 作者:Qing-Bao Zhang,Wen-Liang Jia,Yong-Liang Ban,Yong Zheng,Qiang Liu,Li-Zhu Wu |发布日期:2016.2.18 摘要:In The Presence Of Tetrabutylammonium Fluoride And Molecular Sieves (Ms) 4 å In Dmf, An Efficient Autoxidation Reaction Of 2‐oxindoles With Ketones Under Air At Room Temperature Has Been Developed. This Approach May Provide A Green, Practical, And Metal‐free Protocol For A Wide Range Of Biologically Important 3‐hydroxy‐3‐(2‐oxo‐alkyl)‐2‐oxindoles.
合成参考文献
摘要:Lubell, W. D.; St-Cyr, D. J.; Dufour-Gallant, J.; Hopewell, R.; Boutard, N.; Kassem, T.; Dörr, A.; Zelli, R., Science of Synthesis Knowledge Updates, (2013) 1, 356. 摘要:Li, J. J., Science of Synthesis: Knowledge Updates, (2025) 2. 摘要:Wu, S.; Song, H.; Hu, M., Science of Synthesis: Modern Strategies in Organofluorine Chemistry , (2024) 1, 23. 参考文献:10.1007/s00449-006-0066-z 摘要:Soni P, Prasad GS, Banerjee UC. Optimization of physicochemical parameters for the enhancement of carbonyl reductase production by Candida viswanathii. Bioprocess and Biosystems Engineering. 2006 Jun 13;29(3):149–56. doi: 10.1007/s00449-006-0066-z. 参考文献:10.1007/bf01198410 摘要:Kroh L, Schrödter R, Mügge C, Westphal G, Baltes W, Schröder R. [Heat-induced decomposition of disaccharide Amadori compounds in quasi-water-free reaction conditions]. Z Lebensm Unters Forsch. 1992 Mar;194(3):216–21. doi: 10.1007/bf01198410.