专利号:US-2008214386-A1 优先权日:2004-03-01 标题:Catalyst for Cyclic Carbonate Synthesis 发明人:TAKAHASHI TOSHIKAZU; WATAHIKI TSUTOMU; YASUDA HIROYUKI; SAKAKURA TOSHIYASU 权利人:TAKAHASHI TOSHIKAZU; WATAHIKI TSUTOMU; YASUDA HIROYUKI; SAKAKURA TOSHIYASU 摘要:Provided are a solid catalyst which gives a cyclic carbonate at a high yield and a high selectivity, which is stable and which may be readily separated after reaction; and a method of industrially advantageous, inexpensive and safe production of a cyclic carbonate by the use of the catalyst. The catalyst contains an inorganic solid substance having a surface modified with an ionic substance containing a Group 15 element; or contains an ionic substance containing a Group 15 element, and an inorganic solid substance. The modifying group for surface modification of an inorganic solid substance is an ionic substance containing a Group 15 element. The ionic substance containing a Group 15 element is at least one substance selected from organic phosphonium salts, organic ammonium salts, organic arsonium salts and organic antimonium salts.
专利号:US-9738538-B2 优先权日:2013-12-09 标题 :Method for preparing NaY molecular sieve of high silica-alumina ratio and product thereof 发明人:YUAN DANHUA; DONG XINGLONG; XU YUNPENG; LIU ZHONGMIN; WANG KUNYUAN; HUANG WEI 权利人:DALIAN INST CHEMICAL PHYSICS CAS 摘要:A method for preparing a NaY molecular sieve having a high silica-to-alumina ratio, wherein deionized water, a silicon source, an aluminum source, an alkali source, and ILs as a template agent are mixed to obtain an initial gel mixture; the initial gel mixture is maintained at a proper temperature and aged, then fed into a high pressure synthesis kettle for crystallization; the solid product is separated and dried, to obtain the NaY molecular sieve having a high silica-to-alumina ratio, wherein the ILs is a short-chain alkylimidazolium ionic liquid, the template agent is less volatile, and the resultant high-silicon Y molecular sieve has a high crystallinity and a silica-to-alumina ratio of 6 or more.
参考文献:10.1007/s11356-022-19191-1 摘要:Zhang W, Hu Q, Jiang S, Wang L, Chai J, Mei J. Experimental study on coal dust wettability strengthened by surface active ionic liquids. Environmental Science and Pollution Research. 2022 Feb 15;29(30):46325–40. doi: 10.1007/s11356-022-19191-1.