CAS: 5001-18-3; 1,3-Adamantanediol

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99181-50-7 768-95-6 707-37-9

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CAS号281-23-2 金刚烷 | CAS号768-95-6 1-金刚烷醇 | CAS号24569-89-9 1,3-Dehydroadam... | CAS号111-27-3 正己醇 | CAS号16104-50-0 1,3-二氯金刚烷 | CAS号876-53-9 1,3-二溴金刚烷 | CAS号64-19-7 冰醋酸 | CAS号74087-85-7 二甲基二环氧乙烷 | CAS号84868-17-7 p-Toluolsulfons... | CAS号84868-18-8 p-Toluolsulfons... | CAS号39269-10-8 1,3-金刚烷二甲酸 | CAS号281-23-2 金刚烷 | CAS号29681-64-9 spiro[bicyclo[3... | CAS号99181-50-7 1,3,5-金刚烷三醇 | CAS号115372-36-6 3-羟基-1-金刚烷基甲基丙烯酸酯 | CAS号17933-29-8 7-亚甲基双环[3.3.1]壬-3-酮 | CAS号872598-38-4 7-methylenebicy... | CAS号872598-44-2 1-Methyl-2-azaa...

金刚烷置于n-羟基邻苯二甲酰亚胺,氧气,Cobalt Acetylacetonate体系中,用 溶剂黄146 作为反应溶剂,75.0 °C,101.32 Kpa 条件下,反应 6.0H,以98%的收率获得产物1,3-金刚烷二醇
参考文献:N-羟基邻苯二甲酰亚胺(nhpi)结合过渡金属盐催化分子氧对多环烷烃的羟基化反应
标题:N-羟基邻苯二甲酰亚胺(nhpi)结合过渡金属盐催化分子氧对多环烷烃的羟基化反应
摘要:在n-羟基邻苯二甲酰亚胺(nhpi)和钴盐混合存在的条件下,将金刚烷成功地与分子氧转化为相应的单羟基和二羟基金刚烷.例如,金刚烷在nhpi(10 Mol%)和co(acac)2(0.5 Mol%)在乙酸中的氧气气氛下于75oc暴露于氧气中6小时,得到金刚烷-1-醇(43%)和金刚烷-1,3-二醇(40%)以及金刚烷-2-酮(8%)的转化率为93%.类似地,1,3-二甲基金刚烷产生3,5-二甲基金刚烷-1-醇(47%)和5,7-二甲基金刚烷-1,3-二醇(37%).
DOI:10.1016/0040-4039(96)00992-6

专利信息

专利号:US-2023279170-A1
优先权日:2022-03-02
标 题:Chiral-substituted poly-n-vinylpyrrolidinones and complexes with bimetallic nanoclusters and uses thereof
发明人：HUA DUY H
权利人:UNIV KANSAS STATE
摘要:Synthesis of chiral polyvinylpyrrolidinone (CSPVP) compounds, complexes of CSPVP with a core species, such as a bimetallic nanocluster catalyst, and selective C—H bond oxidation reactions utilizing such complexes are disclosed. These reaction products can be used as reagents in the synthesis of complex organic molecules, such as bioactive products, and C—H bond oxidation of complex molecules including various drugs and natural products.

专利号:US-8563590-B2
优先权日:2008-03-05
标 题 :Compounds, compositions and methods for the treatment of islet amyloid polypeptide (IAPP) accumulation in diabetes
发明人：LAKE THOMAS; SNOW ALAN D
权利人:LAKE THOMAS; SNOW ALAN D; PROTEOTECH INC
摘要:Dihydroxyaryl compounds and pharmaceutically acceptable esters, their synthesis, pharmaceutical compositions containing them, and their use in the treatment of IAPP or amylin fibril diseases, and the manufacture of medicaments for such treatment.

专利号:US-8043786-B2
优先权日:2003-03-05
标题 :Acid generators, sulfonic acids, sulfonyl halides, and radiation sensitive resin compositions
发明人：EBATA SATOSHI; WANG YONG; NISHIMURA ISAO
权利人:JSR CORP
摘要:The invention provides novel acid generators which are unproblematic in combustibility and accumulation inside the human body and can generate acids having high acidities and high boiling points and exhibiting properly short diffusion lengths in resist coating films and which permit the formation of resist patterns excellent smoothness with little dependence on the denseness of a mask pattern; sulfonic acids generated from the acid generators; sulfonyl halides useful as raw material in the synthesis of the acid generators; and radiation-sensitive resin compositions containing the acid generators. The acid generators have structures represented by the general formula (I), n nwherein R 1 is a monovalent substituent such as alkoxycarbonyl, alkylsulfonyl, or alkoxysulfonyl; R 2 to R 4 are each hydrogen or alkyl; k is an integer of 0 or above; and n is an integer of 0 to 5. Among the radiation-sensitive resin compositions, a positive one contains a resin having acid-dissociable groups in addition to the above acid generator, while a negative one contains an alkali-soluble resin and a crosslinking agent in addition to the acid generator.

专利号:US-8829198-B2
优先权日:2007-10-31
标 题:Compounds, compositions and methods for the treatment of beta-amyloid diseases and synucleinopathies
发明人：ESPOSITO LUKE A; HUDSON F MICHAEL; LAKE THOMAS; CUMMINGS JOEL; WEIGELE MANFRED; SNOW ALAN D; LARSEN LESLEY
权利人:ESPOSITO LUKE A; HUDSON F MICHAEL; LAKE THOMAS; CUMMINGS JOEL; WEIGELE MANFRED; SNOW ALAN D; LARSEN LESLEY; PROTEOTECH INC
摘要:Dihydroxyaryl compounds and pharmaceutically acceptable esters, their synthesis, pharmaceutical compositions containing them, and their use in the treatment of β-amyloid diseases, such as observed in Alzheimer's disease, and synucleinopathies, such as observed in Parkinson's disease, and the manufacture of medicaments for such treatment.

专利号:US-8916598-B2
优先权日:2003-05-30
标题 :Compounds, compositions, and methods for the treatment of β-amyloid diseases and synucleinopathies
发明人：ESPOSITO LUKE A; HUDSON F MICHAEL; LAKE THOMAS; CUMMINGS JOEL; WEIGELE MANFRED; SNOW ALAN D
权利人:ESPOSITO LUKE A; HUDSON F MICHAEL; LAKE THOMAS; CUMMINGS JOEL; WEIGELE MANFRED; SNOW ALAN D; PROTEOTECH INC
摘要:Dihydroxyaryl compounds and pharmaceutically acceptable esters, their synthesis, pharmaceutical compositions containing them, and their use in the treatment of synucleinopathies, such as observed in Parkinson's disease, and the manufacture of medicaments for such treatment.

专利号:CN-117756720-A
优先权日:2023-12-18
标 题 :Polymerizable quaternary ammonium salt antibacterial agent and its preparation and application in the synthesis of antibacterial polyester