专利号:US-10421873-B2 优先权日:2015-05-25 标 题 :Method for in-site synthesis of transparent conductive coating of poly(3,4-ethylenedioxythiophene)/nano silver 发明人:LI JIANXIONG; MA YAXIAO; LIU ANHUA 权利人:UNIV SOUTH CHINA TECH 摘要:A method for in-site synthesis of transparent conductive coating of poly(3,4-ethylenedioxythiophene)/nano silver hybrid on transparent substrate is provided. Transparent substrate with oxidant coating containing silver salt is immersed into 3,4-ethylenedioxythiophene (EDOT) solution. The oxidant turns EDOT monomer to poly(3,4-ethylenedioxythiophene) (PEDOT) coating on the transparent substrate; meanwhile, the silver salt itself is reduced to nano silver by the EDOT monomer, resulting in a nano silver-doped PEDOT coating. Thereby, a transparent conductive film made of PEDOT/nano silver coating on transparent substrate is obtained. The transparent conductive film with PEDOT/nano silver coating prepared in the present invention possesses the advantages of high electrical conductivity, optical transparency and environmental stability.
专利号:US-7320813-B2 优先权日:2003-12-15 标题:Synthesis of highly conducting and transparent thin polymer films 发明人:POLLACK STEVE; MARTIN BRETT D; SHASHIDHAR RANGANATHAN; HA YUNG-HOON; NIKOLOY NIKOLAY 权利人:US NAVY 摘要:A polymerization process is provided using a mixture of a solvent, a monomer, an oxidizing agent, and a moderator. The mixture is coated on a substrate and heated to initiate oxidative polymerization. At least one of three process conditions is used: the solvent having a boiling point in excess of about 120° C.; the total concentration of the monomer, the oxidizing agent, and the moderator being at least about 40% by weight; and the molar concentration of the moderator being greater than the molar concentration of the monomer.
专利号:US-8815343-B2 优先权日:2007-07-09 标 题 :Highly conductive and stable transparent conducting polymer films 发明人:CHEN LICHUN; BRADLEY DONAL DONAT CONOR 权利人:CHEN LICHUN; BRADLEY DONAL DONAT CONOR; IMP INNOVATION LTD 摘要:The invention relates to a process for the synthesis of conducting polymer films by vapor phase polymerization. The invention relates particularly to the synthesis of polymerized thiophene films, for example poly(3,4-ethylenedioxythiophene) (PEDOT) films.
专利号:US-2004232390-A1 优先权日:2003-04-07 标 题 :Highly conductive carbon/inherently conductive polymer composites 发明人:VISWANATHAN TITO 摘要:This invention relates to composites of a highly conductive form of carbon, preferably graphite, and an inherently conducting polymer that exhibits higher conductivity than the conductivities of the individual components and the synthesis of these composites.
专利号:US-2015176198-A1 优先权日:2010-03-12 标题 :Particle-interconnects on non-planar substrates 发明人:STRICKLAND AARON D 权利人:STRICKLAND AARON D; IFYBER LLC 摘要:Disclosed in this specification is a composition and method for controlled synthesis of interconnects to crosslink nanoparticles, wherein the said particles conformally coat the surface of non-planar substrates. A method is provided for crosslinking nanoparticles that are conformally coated on fibrous materials, wherein the presence of initiator units on the surface of the particles guide the formation of interconnects. A second method uses preformed interconnects to crosslink nanoparticles that are conformally coated on fibrous materials. The nanoparticles on the coating are crosslinked in order to impart new and/or enhanced properties to the particle-coated non-planar substrates.
专利号:WO-2016083887-A1 优先权日:2014-11-27 标 题 :A method for obtaining nanoparticles of conducting polymers and conducting polymer nanoparticles obtained by the method 发明人:MICHALSKA-MAKSYMIUK AGATA; MAKSYMIUK KRZYSZTOF; KLUCINSKA KATARZYNA; JAWORSKA EWA; GRYCZAN PIOTR 权利人:UNIV WARSZAWSKI 摘要:The invention reveals a new method of obtaining conducting polymer nanoparticles in course of polymerization in solution containing an oxidant, wherein the monomer of the conducting polymer is introduced into the polymeric particulates and the said monomer is gradually and spontaneously released to the aqueous solution containing the oxidant and thus undergoes polymerization reaction at the interface: lipophilic medium, which are microstructures in the form of said polymeric particulates / said aqueous solution containing the oxidant, and the nanostructures of conducting polymer formed in course of reaction with the oxidant are after synthesis mechanically separated from the reaction medium as the first fraction of nanoparticles and which can be next subject to further treatment leading to change of their properties, and in subsequent step the nanoparticles decorating the surface of polymeric particulates are possibly released from the surface of said polymeric particulates by introduction of a surfactant into the reaction medium and which are separated as the second fraction of nanoparticles of electrochemical properties - due to the presence of surfactant at the their surface, different from those of nanoparticles of the first fraction. According to the invention in the process of polymerization of conducting polymer also additives leading to the desired properties of nanoparticles can be included in the nanoparticles structure. The invention relates also to nanoparticles of conducting polymer separated as the first fraction of nanoparticles according to the method of current invention, with the surface free from the presence of substance limiting charge and/or ion exchange between the nanoparticle and solution, as especially free from surfactants.
摘要:Fowler, L. S.; Sutherland, A., Science of Synthesis Knowledge Updates, (2010) 3, 126. 摘要:Acute Toxicity Data. Journal of the American College of Toxicology, Part B., 15(Suppl 摘要:Kwiecień, H. U., Science of Synthesis: Knowledge Updates, (2024) 3, 43.