CAS: 2670-68-0; Boron,N-Ethylethanamine

英文名称Boron,N-Ethylethanamine
中文名称硼烷二乙胺络合物
其它别名Diethylamine,compd. with BH3 (11) (7CI); Diethylamine, compd. with BH3 (6CI); Diethylamine,compd. with borane (11) (8CI); Ethanamine, N-ethyl-, compd. with borane (11); Borane, compd. with N-ethylethanamine (11); Ethanamine, N-ethyl-, boroncomplex; (Diethylamine)trihydroboron; Diethylamine borane
CAS编号2670-68-0
MFCD编号:MFCD07784479
分子式:C4H14BN
分子量:86.97
产品CID: 1245406
产品分类化学试剂 → 有机试剂 → 硼烷

相似结构搜索
产品信息参考
InChIKey: XVJFCWCVLJOKRP-UHFFFAOYSA-N
1S/C4H11N.B/c1-3-5-4-2;/h5H,3-4H2,1-2H3;…
计算化学: 氢键受体数1.0氢键供体数1.0可旋转键数2.0

MSDS等安全信息

上下游产品

合成工艺路线路线简述

二乙胺盐酸盐在 Sodium Tetrahydroborate体系中,用四氢呋喃作为反应溶剂,反应 2.75H,以60%的收率获得n,N-Diethylamine-Borane
参考文献:骨架镍催化剂对胺-硼烷加合物的异质脱氢偶联作用
标题:骨架镍催化剂对胺-硼烷加合物的异质脱氢偶联作用
摘要:由ni / Al合金中al的选择性浸出产生的骨架ni已成功用于各种胺-硼烷加合物的催化脱氢.低成本和简便的单步合成相结合,使该系统成为先前描述的贵金属和其他第一行金属催化剂的潜在有吸引力的替代品.催化剂的非均质性质有利于方便的产物纯化,这是第一个基于第一行过渡金属的此类系统.使用5 Mol%的骨架ni催化剂在20°C下证明了me 2 Nh.Bh 3(1)和et 2 Nh.Bh 3(5)的催化脱氢偶联并生成了[Me 2的n-Bh 2 ] 2(2)和[等2的n-Bh 2 ] 2 / Et 2 N═bh 2(6),分别.相关的加合物i Pr 2 Nh.Bh 3(7)也被脱氢得到i Pr 2 N = Bh 2(8),但催化剂明显失活.发现menh 2 .Bh 3(9)催化脱氢反应生成环状三氮杂硼烷[Menh-Bh 2 ] 3(10)为主要产物,而当使用化学计量的ni时,会形成高分子量聚(甲基氨基硼烷)[Menh-Bh
Doi:10.1021/Ic201809G

海关参考信息

2901100000-饱和无环烃
2921199090-其他无环单胺
💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
详情请参考：📖 海关编码查询和海关进出口税则

专利信息

专利号:US-9802934-B2
优先权日:2013-10-17
标题 :Process for the synthesis of (R)-praziquantel
发明人：QIAN MINGXIN
权利人:TONGLI BIOMEDICAL CO LTD
摘要:The present disclosure relates to a process and new intermediates for the synthesis of (R)-praziquantel, which is obtained through four steps in proper order, that is, condensation reaction, reduction reaction, acylation reaction and ring-closing reaction, using (1R)-2-substituted-1,2,3,4-tetrahydroisoquinoline-1-carboxylic acid as starting material. Overall, the present disclosure provides a (R)-praziquantel product with higher optical purity through a process route that is more cost effective and environmentally friendly.

专利号:US-4444685-A
优先权日:1981-04-27
标题 :Stereospecific synthesis of thienamycin from penicillin
发明人：AMATO JOSEPH S; KARADY SANDOR; WEINSTOCK LEONARD M
权利人:MERCK & CO INC
摘要:A stereospecific conversion of penicillin to thienamycin, using diisopropylamine borane and magnesium trifluoroacetate to prepare the hydroxyethyl side chain and acetoacetate dianion equivalent disilylethyl to prepare the Î²-ketoester side chain.

专利号:CN-101128469-B
优先权日:2005-02-25
标题:Synthesis of protease inhibitor precursors

专利号:US-2017121330-A1
优先权日:2013-10-17
标题 :Process and intermediates for the synthesis of (r)-praziquantel

专利号:CN-1730540-A
优先权日:2005-07-20
标题 :Synthesis method of metal nanoparticle and polysaccharide polymer composite material

专利号:CN-115636764-B
优先权日:2022-11-08
标题:A kind of synthesis method of benzamide compound