CAS: 434-45-7; 2,2,2-Trifluoroacetophenone

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CAS号93-58-3 苯甲酸甲酯 | CAS号75-46-7 三氟甲烷 | CAS号353-85-5 三氟乙腈 | CAS号71-43-2 苯 | CAS号98-88-4 苯甲酰氯 | CAS号340-04-5 α-(三氟甲基)苄醇 | CAS号84452-37-9 N-cyclohexyl-1-... | CAS号354-32-5 三氟乙酰氯 | CAS号321-31-3 3'-氯-2,2,2-三氟苯乙酮 | CAS号321-37-9 4'-氯-2,2,2-三氟苯乙酮 | CAS号340-06-7 (S)-(+)-Α-三氟甲基苄醇 | CAS号10531-50-7 (R)-(-)-Α-三氟甲基苄醇 | CAS号687-47-8 (-)-乳酸乙酯 | CAS号7699-00-5 D-乳酸乙酯 | CAS号21210-43-5 (S)-(+)-扁桃酸甲酯 | CAS号20698-91-3 D-(-)-扁桃酸甲酯 | CAS号4652-27-1 4-甲氧基-3-丁烯-2-酮

三氟乙腈置于乙醚,苯基溴化镁体系中,化学反应生成 2,2,2-三氟苯乙酮
参考文献:The Reactions Of Perfluoronitriles With Grignard Reagents1
标题:The Reactions Of Perfluoronitriles With Grignard Reagents1
摘要:
DOI:10.1021/ja01609A035

专利信息

专利号:US-2025197202-A1
优先权日:2023-12-15
标题 :Synthesis of new polymers for the manufacture of solid hydrogen transfer agents
发明人：GÓMEZ EMILIO LEAL; MANCERA LEÓN PABLO TORRES; JUÃ?REZ JORGE ANCHEYTA; MARTÃ?NEZ FERNANDO ALONSO; VÃ?ZQUEZ LAURA OLIVIA ALEMÃ?N
权利人:MEXICANO INST PETROL
摘要:This disclosure refers to a method for the synthesis of polymers with weight average molecular weights greater than 50,000 g/mol, chemically inert, with a minimum decomposition temperature of 425° C., and a main chain composed only of carbon-carbon bonds, which contain structures of the type of naphthalene, phenanthrene, anthracene, pyrene, carbazole or any other where two or more aromatic rings of six carbon atoms of the benzene-type are fused, which may or may not contain aromatic heterocycles. In addition, the polymers obtained from the present disclosure may or may not contain fluorine atoms in their structure. The synthesis described here is carried out by means of polycondensation between a polycyclic aromatic compound and a compound with a carbonyl group in its structure in a strong acid medium.

专利号:US-8283502-B2
优先权日:2009-04-09
标题:Autocatalytic process for the synthesis of chiral propargylic alcohols
发明人：CHINKOV NICKA; WARM ALEKSANDER; CARREIRA ERICK
权利人:CHINKOV NICKA; WARM ALEKSANDER; CARREIRA ERICK; LONZA AG
摘要:An autocatalytic process for the synthesis of chiral propargylic alcohols.

专利号:US-5861540-A
优先权日:1986-10-29
标题:Substituted 1,1,1-triaryl-2,2,2-trifuoroethanes and processes for their synthesis
发明人：ALSTON WILLIAM B; GRATZ ROY F
权利人:NASA
摘要:Synthetic procedures to tetraalkyls, tetraacids and dianhydrides substituted 1,1,1-triaryl-2,2,2-trifluoroethanes which comprises: (1) 1,1-bis(dialkylaryl)-1-aryl-2,2,2 -trifluoroethane, (2) 1,1-bis(dicarboxyaryl)-1-aryl-2,2,2-trifluoroethane or (3) cyclic dianhydride or diamine of 1,1-bis(dialkylaryl)-1-aryl-2,2,2-trifluoroethanes. The synthesis of (1) is accomplished by the condensation reaction of an aryltrifluoromethyl ketone with a dialkylaryl compound. The synthesis of (2) is accomplished by oxidation of (1). The synthesis dianhydride of (3) is accomplished by the conversion of (2) to its corresponding cyclic dianhydride. The synthesis of the diamine is accomplished by the similar reaction of an aryltrifluoromethyl ketone with aniline or alkyl substituted or disubstituted anilines. Also, other derivatives of the above are formed by nucleophilic displacement reactions.

专利号:US-4758380-A
优先权日:1986-10-29
标题 :Substituted 1,1,1-triaryl-2,2,2-trifluoroethanes and processes for their synthesis
发明人：ALSTON WILLIAM B; GRATZ ROY F
权利人:NASA
摘要:Synthetic procedures to tetraalkyls, tetraacids and dianhydrides substituted 1,1,1-triaryl-2,2,2-trifluoroethanes which comprises: (1) 1,1-bis(dialkylaryl)-1-aryl-2,2,2-trifluoroethane, (2) 1,1-bis(dicarboxyaryl)-1-aryl-2,2,2-trifluoroethane or (3) cyclic dianhydride or diamine of 1,1-bis(dialkylaryl)-1-aryl-2,2,2-trifluoroethanes. The synthesis of (1) is accomplished by the condensation reaction of an aryltrifluoromethyl ketone with a dialkylaryl compound. The synthesis of (2) is accomplished by oxidation of (1). The synthesis dianhydride of (3) is accomplished by the conversion of (2) to its corresponding cyclic dianhydride. The synthesis of the diamine is accomplished by the similar reaction of an aryltrifluoromethyl ketone with aniline or alkyl substituted or disubstituted anilines. Also, other derivatives of the above are formed by nucleophilic displacement reactions.

专利号:US-4912238-A
优先权日:1986-10-29
标 题:Substituted 1,1,1-triaryl-2,2,2-trifluoroethanes and processes for their synthesis
发明人：ALSTON WILLIAM B; GRATZ ROY F
权利人:NASA
摘要:Synthetic procedures to tetraalkyls, tetraacids and dianhydrides substituted 1,1,1-triaryl-2,2,2-trifluoroethanes which comprises: (1) 1,1-bis(dialkylaryl)-1-aryl-2,2,2-trifluoroethane, (2) 1,1-bis(dicarboxyaryl)-1-aryl-2,2,2-trifluoroethane or (3) cyclic dianhydride or diamine of 1,1-bis(dialkylaryl)-1-aryl-2,2,2-trifluoroethanes. The synthesis of (1) is accomplished by the condensation reaction of an aryltrifluoromethyl ketone with a dialkylaryl compound. The synthesis of (2) is accomplished by oxidation of (1). The synthesis dianhydride of (3) is accomplished by the conversion of (2) to its corresponding cyclic dianhydride. The synthesis of the diamine is accomplished by the similar reaction of an aryltrifluoromethyl ketone with aniline or alkyl substituted or disubstituted anilines. Also, other derivatives of the above are formed by nucleophilic displacement reactions.

专利号:US-4885116-A
优先权日:1986-10-29
标 题 :Substituted 1,1,1-triaryl-2,2,2-trifluoroethanes and processes for their synthesis
发明人：ALSTON WILLIAM B; GRATZ ROY F
权利人:NASA
摘要:Synthetic procedures to tetraalkyls, tetraacids and dianhydrides substituted 1,1,1-triaryl-2,2,2-trifluoroethanes which comprises: (1) 1,1-bis(dialkylaryl)-1-aryl-2,2,2-trifluoroethane, (2) 1,1-bis(dicarboxyaryl)-1-aryl-2,2,2-trifluoroethane or (3) cyclic dianhydride or diamine of 1,1-bis(dialkylaryl)-1-aryl-2,2,2-trifluoroethanes. The synthesis of (1) is accomplished by the condensation reaction of an aryltrifluoromethyl ketone with a dialkylaryl compound. The synthesis of (2) is accomplished by oxidation of (1). The synthesis dianhydride of (3) is accomplished by the conversion of (2) to its corresponding cyclic dianhydride. The synthesis of the diamine is accomplished by the similar reaction of an aryltrifluoromethyl ketone with aniline or alkyl substituted or disubstituted anilines. Also, other derivatives of the above are formed by nucleophilic displacement reactions.