CAS: 808-57-1; 2,3,6,7,10,11-Hexamethoxytriphenylene

该化合物是一种多环芳烃衍生物,由六种甲基替代物对称地排列在三苯核心上,该化合物因其扩展的混凝和硬板结构而具有显著的电子和光学特性,使其在有机电子和材料科学中具有价值.它在普通有机溶剂中的高溶性提高了薄膜应用的可处理性.甲基氧化合物组有助于电子饱和特性,便利有机半导体的充电运输.此外,在环境条件下其稳定性和定义明确的分子几何学使其成为超分子化学和液体晶体研究的有前途的候选体.该化合物经常被用作高级功能材料的建筑块.

英文名称2,3,6,7,10,11-Hexamethoxytriphenylene
中文名称2,3,6,7,10,11-六甲氧基三亚苯
IUPAC名称2,3,6,7,10,11-hexamethoxytriphenylene
其它别名2,3,6,7,10,11-六甲氧基三亚苯基苯
CAS编号808-57-1
MFCD编号:MFCD00075571
分子式:C24H24O6
分子量:408.45
产品CID: 1803540
产品分类有机原料→分子砌块→芳环类化合物→菲类化合物

相似结构搜索
产品信息参考;;
InChIKey: TXROZCSFVVIBFI-UHFFFAOYSA-N
InChI=1S/C24H24O6/c1-25-19-7-13-14(8-20(19)26-2)16-10-22(28-4)24(30-6)12-18(16)17-11-23(29-5)21(27-3)9-15(13)17/h7-12H,1-6H3…
计算化学: 氢键受体数6.0氢键供体数0.0可旋转键数6.0

相似化合物

4877-80-9 865836-87-9 929103-42-4

MSDS等安全信息

GHS符号GHS07
警示词Warning
危险描述H302-H315-H319-H335
防范说明P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501
安全声明24/25

上下游产品

合成工艺路线路线简述

91-16-7 = 808-57-1
反应条件:1.1 Reagents: Iron Chloride (Fecl3) Solvents: Dichloromethane
标题:1,5,9-Triazacoronenes: A Family Of Polycyclic Heteroarenes Synthesized By A Threefold Pictet-Spengler Reaction
作者:Wei,Junfa; Et Al
参考文献:Angewandte Chemie 日期:2010 卷标:49(44) 页码:8209-8213]

91-16-7 = 808-57-1
反应条件:1.1 Reagents: Sulfuric Acid,Iron Chloride (Fecl3)
标题:A High Yield Easy Method For The Preparation Of Alkoxy-Substituted Triphenylenes
作者:Naarmann,Herbert; Et Al
参考文献:Synthesis 日期:1994 卷标:(5) 页码:477-8]

37895-73-1 = 808-57-1
反应条件:1.1 Reagents: Sodium Catalysts: Dibromo[1,2-Di(Methoxy-Ko)Ethane]Nickel,5,5′-Bis(Trifluoromethyl)-2,2′-Bipyridine Solvents: Dimethylacetamide; 10 Min,80 °C; 14 H,80 °C
标题:Nickel-Catalyzed Electroreductive Syntheses Of Triphenylenes Using Ortho-Dihalobenzene-Derived Benzynes
作者:Li,Zhao-Ming; Et Al
参考文献:Chinese Journal Of Chemistry 日期:2022 卷标:40(19) 页码:2335-2344]

= 808-57-1
反应条件:1.1 Reagents: Trifluoromethanesulfonic Acid,Oxygen Catalysts: Palladium Solvents: 2,2,2-Trifluoroethanol; 0.3 H,Rt
标题:Aerobic Oxidative Intramolecular Aromatic Coupling Via Heterogeneous Metal Catalysts
作者:Fujimoto,Shigenobu; Et Al
参考文献:Advanced Synthesis & Catalysis 日期:2016 卷标:358(19) 页码:3057-3061]

= 808-57-1
反应条件:1.1 Reagents: Methanesulfonic Acid Catalysts: Carbon Solvents: Toluene; 21 H,70 °C1.2 Reagents: Alumina
标题:Carbocatalytic Oxidative Dehydrogenative Couplings Of (Hetero)Aryls By Oxidized Multi-Walled Carbon Nanotubes In Liquid Phase
作者:Wirtanen,Tom; Et Al
参考文献:Chemistry - A European Journal 日期:2019 卷标:25(53) 页码:12288-12293]

= 808-57-1
反应条件:1.1 Reagents: Tetrabutylammonium Fluoride,Oxygen Solvents: Tetrahydrofuran; 2 H,Rt1.2 Reagents: Potassium Carbonate Solvents: Dimethylformamide; 5 Min,Rt1.3 Rt; Overnight,Rt
标题:Facile Cyclization Of Terphenyl To Triphenylene: A New Chemodosimeter For Fluoride Ions
作者:Bhalla,Vandana; Et Al
参考文献:Organic Letters 日期:2010 卷标:12(3) 页码:628-631]

= 808-57-1
反应条件:1.1 Catalysts: Bis(Dibenzylideneacetone)Palladium,Bis[2-(Diphenylphosphino)Phenyl] Ether Solvents: Toluene; 1 Min,Rt1.2 Reagents: Potassium Tert-Butoxide; 16 H,100 °C
标题:Use Of 2-Bromophenylboronic Esters As Benzyne Precursors In The Pd-Catalyzed Synthesis Of Triphenylenes
作者:Garcia-Lopez,Jose-Antonio; Et Al
参考文献:Organic Letters 日期:2014 卷标:16(9) 页码:2338-2341]

110190-08-4 = 808-57-1
反应条件:1.1 Reagents: Zinc Catalysts: Bis(Triphenylphosphine) Nickel Dibromide Solvents: Tetrahydrofuran; Heated
标题:O-Dihaloarenes As Aryne Precursors For Nickel-Catalyzed [2 + 2 + 2] Cycloaddition With Alkynes And Nitriles
作者:Hsieh,Jen-Chieh; Et Al
参考文献:Chemical Communications (Cambridge 日期:2008 卷标:(26) 页码:2992-2994]

1820004-70-3 = 808-57-1
反应条件:1.1 Reagents: Molybdenum Pentachloride Solvents: Dichloromethane; Rt
标题:Over-Oxidation As The Key Step In The Mechanism Of The Mocl5-Mediated Dehydrogenative Coupling Of Arenes
作者:Schubert,Moritz; Et Al
参考文献:Angewandte Chemie 日期:2016 卷标:55(3) 页码:1156-1159

邻苯二甲醚置于iron(Iii) Chloride,硫酸体系中,用二氯甲烷作为反应溶剂,化学反应 3.25H,以89%的收率获得产物2,3,6,7,10,11-六甲氧基三亚苯
参考文献:纺织品自组织框架 (Soft):用于同时感测,捕获和过滤气体的导电织物
标题:纺织品自组织框架 (Soft):用于同时感测,捕获和过滤气体的导电织物
摘要:可穿戴电子产品具有推进个性化医疗保健,减轻残疾,加强沟通和改善国土安全的潜力.开发具有与当地环境相互作用能力的多功能电子纺织品(电子纺织品)是实现物理和化学信息电子转换的有前途的策略.本文描述了一种通过简单分子构建块的直接溶液相自组装将导电二维 (2D) 金属有机框架 (Mof) 集成到织物中来制造多功能电子纺织品的简单而快速的方法.这些电子纺织品显示出可靠的导电性,增强的孔隙率,柔韧性和洗涤稳定性.这些集成系统的功能效用在化学电阻气体传感的背景下得到证明,吸收和过滤.纺织品上的自组织框架 (Soft) 设备可检测和区分 Ppm 级的重要气态分析物(no,H2S 和 H2O),并在存在湿度(5000 Ppm,18% Rh)的情况下保持其化学电阻功能.具有亚 Ppm 理论检测限(no 的 Lod = 0.16 Ppm 和 H2S = 0.23 Ppm),这些构成了所报告的最佳纺织品支持的 H2S
DOI:10.1021/jacs.7B08840

海关参考信息

2902902000-精萘
2905110000-甲醇
2907210001-间苯二酚
2908199090-其他酚的卤化衍生物
💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
详情请参考：📖 海关编码查询和海关进出口税则

专利信息

专利号:WO-9429243-A1
优先权日:1993-06-11
标题 :Synthesis of substituted triphenylenes, useful as discotic liquid crystals
发明人：BUSHBY RICHARD JAMES; CAMMINDGE ANDREW NEIL; HEADDOCK GARETH; BORNER RUTH CAROL; BODEN NEVILLE
权利人:BRITISH TECH GROUP; BUSHBY RICHARD JAMES; CAMMINDGE ANDREW NEIL; HEADDOCK GARETH; BORNER RUTH CAROL; BODEN NEVILLE
摘要:Unsymmetrically substituted triphenylenes required in the synthesis of polymeric discotic liquid crystals are made using iron (III) chloride in organic solvent at room temperature to effect the oxidative coupling of 1,2-dialkoxybenzenes to 3,3',4,4'-tetraalkoxybiphenyls. This is followed by a reductive workup. The same oxidation-reduction protocol also proves effective in the trimerisation of 1,2-dialkoxybenzenes.

专利号:JP-H09502164-A
优先权日:1993-06-11
标题:Synthesis of substituted triphenylene useful as discotic liquid crystals

专利号:EP-0703885-A1
优先权日:1993-06-11
标题:Synthesis of substituted triphenylenes, useful as discotic liquid crystals

专利号:CN-118108938-A
优先权日:2022-11-30
标题:One-step synthesis method of linear polyhydroxy polyether

专利号:CN-119978387-A
优先权日:2025-02-28
标题 :Three-component synthesis method of polyphosphonate