149-91-7 = 87-66-1 反应条件:1.1 48 H,30 - 35 °C 标题:Csj Acting As A Versatile Highly Efficient Greener Resource For Organic Transformations 作者:Maity,Himadri Sekhar; Et Al 参考文献:Rsc Advances 日期:2016 卷标:6(29) 页码:24446-24450]
91-10-1 = 87-66-1 反应条件:1.1 Reagents: Hydrogen Bromide Solvents: Water 标题:Manufacture Of Pyrogallol 参考文献:Japan]
634-36-6 = 87-66-1 反应条件:1.1 Reagents: Lithium Bromide,Hydrogen Bromide; 2 H,100 °C 标题:Cleavage Of Ethers And Demethylation Of Lignin In Acidic Concentrated Lithium Bromide (Aclb) Solution 作者:Li,Zheng; Et Al 参考文献:Green Chemistry 日期:2020 卷标:22(22) 页码:7989-8001]
24677-78-9 = 87-66-1 反应条件:1.1 Reagents: Hydrogen Peroxide Solvents: Water; 50 Min,Rt 标题:H2O2 In Web: A Highly Efficient Catalyst System For The Dakin Reaction 作者:Saikia,Bishwajit; Et Al 参考文献:Green Chemistry 日期:2015 卷标:17(9) 页码:4533-4536]
3776-30-5 = 87-66-1 反应条件:1.1 Reagents: Sodium Hydroxide,Sodium 1,2,3-Propanetricarboxylate Hydrate (4:2:3) Solvents: Water; 4 H,386 K1.2 Reagents: Sodium Hydroxide Solvents: Water; 30 Min 标题:Cyclic Reaction Process For Synthesis Of Pyrogallic Acid From 2,2,6,6-Tetrahalocyclohexanone 作者:Wang,Yanping; Et Al 参考文献:Huagong Jinzhan 日期:2015 卷标:34(1) 页码:224-228]
3776-30-5 = 87-66-1 反应条件:1.1 Reagents: γ-Butyrolactone,Potassium Hydroxide Solvents: Water 标题:Preparation Of Pyrogallol From 2,2,6,6-Tetrahalocyclohexanone 参考文献:Japan]
= 87-66-1 反应条件:1.1 Catalysts: Phenol 2-Monooxygenase (Nadph); 24 H 标题:Biological Valorization Of Poly(Ethylene Terephthalate) Monomers For Upcycling Waste Pet 作者:Kim,Hee Taek; Et Al 参考文献:Acs Sustainable Chemistry & Engineering 日期:2019 卷标:7(24) 页码:19396-19406]
149-91-7 = 87-66-1 [标题:Reaction Conditions 标题:Laws Holding For The Pyrolytic Degradation Of Some Cyclic Hydroxy Acids Of The Benzene Series. Iii 作者:Kunz-Krause,Hermann; Et Al 参考文献:Berichte Der Deutschen Chemischen Gesellschaft [abteilung] B: Abhandlungen 日期:1920 卷标:53 页码:190-201]
91-10-1 = 87-66-1 反应条件:1.1 Reagents: Hydrochloric Acid Solvents: Water 标题:Preparation Of Pyrogallol From Phenol 参考文献:Japan]
91-10-1 = 87-66-1 反应条件:1.1 Reagents: Lithium Bromide,Hydrogen Bromide; 2 H,100 °C 标题:Cleavage Of Ethers And Demethylation Of Lignin In Acidic Concentrated Lithium Bromide (Aclb) Solution 作者:Li,Zheng; Et Al 参考文献:Green Chemistry 日期:2020 卷标:22(22) 页码:7989-8001]
17864-23-2 = 87-66-1 反应条件:1.1 Catalysts: 1H-Imidazolium,1,3-Disulfo-,Sulfate (1:1) Solvents: Methanol; 8 Min,Rt 标题:Preparation,Characterization And Use Of 1,3-Disulfonic Acid Imidazolium Hydrogen Sulfate As An Efficient,Halogen-Free And Reusable Ionic Liquid Catalyst For The Trimethylsilyl Protection Of Hydroxyl Groups And Deprotection Of The Obtained Trimethylsilanes 作者:Shirini,Farhad; Et Al 参考文献:Journal Of Molecular Catalysis A: Chemical 日期:2012 卷标:365 页码:15-23]
24677-78-9 = 87-66-1 反应条件:1.1 Catalysts: Formic Acid (Supported On Nitrogen-Doped Reduced Graphene Oxide),1H-Pyrrole (Supported On Nitrogen-Doped Reduced Graphene Oxide) Solvents: Acetonitrile,Water; 20 Min,Rt1.2 Reagents: Hydrogen Peroxide Solvents: Water; 12 H,35 °C; 12 H,35 °C; 35 °C -> Rt1.3 Reagents: Sodium Bisulfite Solvents: Water; Rt 标题:Heterogeneous Nitrogen-Doped Graphene Catalysed Hoo- Generation Via A Non-Radical Mechanism For Base-Free Dakin Reaction 作者:Sun,Wei; Et Al 参考文献:Advanced Synthesis & Catalysis 日期:2019 卷标:361(22) 页码:5210-5216]
87-66-1 = 87-66-1 反应条件:1.1 Reagents: 8-Hydroxyquinoline,Thorium Nitrate Solvents: Ethanol,Water; Rt1.2 Reagents: Sodium Hydroxide Solvents: Water; Ph 3 - 4.5,Rt 标题:Microbial Screening Of Thorium(Iv) And Dioxouranium(Vi) Chelates With Oxine And Phenols 作者:Kapadia,M. A.; Et Al 参考文献:Journal Of The Indian Chemical Society 日期:2007 卷标:84(7) 页码:637-639
木榴油置于双氧水体系中,化学反应 18.0H,以12.8%的收率获得产物邻苯三酚 参考文献:Selective Photocatalytic Conversion Of Guaiacol Using G-C3N4 Metal Free Nanosheets Photocatalyst To Add-Value Products 标题:Selective Photocatalytic Conversion Of Guaiacol Using G-C3N4 Metal Free Nanosheets Photocatalyst To Add-Value Products 摘要: DOI:10.1016/j.Jphotochem.2021.113513
专利号:WO-2024220674-A1 优先权日:2023-04-18 标题:Timescale-guided microfluidic synthesis of polyphenol-iron iii network nanocapsules of hydrophobic drugs 发明人:YEO YOON; HAN BUMSOO; SHEN YINGNAN 权利人:PURDUE RESEARCH FOUNDATION 摘要:A scalable method of continuous microfluidic synthesis of tannic acid-iron III (TA-FeIII) network (TFN) nanocapsules of a hydrophobic drug; a scalable method of continuous microfluidic synthesis of epigallocatechin-3-gallate iron III (EGCG-FeIII) network, (EFN) nanocapsules; hydrophobic drug nanocapsules synthesized in accordance with the method; and a method of administering a hydrophobic drug to a patient in need thereof by administering to the patient the hydrophobic drug nanocapsules.
专利号:US-2006128930-A1 优先权日:2004-12-03 标题 :Synthesis of sterically hindered phenol based macromolecular antioxidants 发明人:DHAWAN ASHISH; CHOLLI ASHOK L 权利人:DHAWAN ASHISH; CHOLLI ASHOK L 摘要:Disclosed is a method for the synthesis of sterically hindered polymeric antioxidants based on phenol type antioxidant monomers. The method includes polymerizing and alkylating a phenol containing monomer represented by the following structural formula: n n nto produce a sterically hindered polymeric macromolecular antioxidant. X, R 10 and q are as defined herein. The disclosed method is a simple, direct and economical process for the synthesis of sterically hindered polymeric macromolecular antioxidants.
专利号:US-3956184-A 优先权日:1974-04-24 标题:Method of preparing silver catalyst for synthesis of formaldehyde by oxidizing methyl alcohol 发明人:KRUGLIKOV ANATOLY ABRAMOVICH; YAKOVENKO ZEMFIRA IVANOVNA; ROZNINA MARINA IVANOVNA; ROGACHEVA ANNA MALOFEEVNA; BELOUSOV GERMAN IVANOVICH 权利人:KRUGLIKOV ANATOLY ABRAMOVICH; YAKOVENKO ZEMFIRA IVANOVNA; ROZNINA MARINA IVANOVNA; ROGACHEVA ANNA MALOFEEVNA; BELOUSOV GERMAN IVANOVICH 摘要:The method of preparing a silver catalyst for synthesis of formaldehyde by oxidizing methyl alcohol which consists in that a carrier is impregnated with an aqueous or an aqueous-alcohol solution containing complex ions of silver having the general formula [Ag(X) n ] + or [Ag(Y) 2 ] - , where X is ammonia, ethylenediamine, triethylenetetramine or triaminotriethylamine, Y is a thiocyanate, cyanide, acetate, or hydroxyl ion, and n is 1 or 2. The impregnated carrier is processed, at a temperature of from 10° - 100°C, with a reducing agent taken in the quantity sufficient to reduce the silver completely from said ion. The thus-prepared catalyst is dried at a temperature of from 80° to 400°C. It is recommended that the catalyst be washed with water before drying. The thus-prepared catalyst has a highly developed active surface with a small content of silver (the specific surface of the catalyst is 0.7 - 7 square meters per gram, with the metal silver content of the catalyst being from 5 - 10 per cent by weight). The catalyst is highly active and has good selectivity in the process of formaldehyde synthesis from methyl alcohol. The yield of formaldehyde with the proposed catalyst is from 75 - 80 per cent, calculating with reference to the passed methyl alcohol, with the selectivity of the process being from 89 - 95 per cent.
专利号:US-4459420-A 优先权日:1982-05-17 标题 :Pyrogallol synthesis of anti-atherogenic furochromones 发明人:GAMMILL RONALD B 权利人:UPJOHN CO 摘要:The present invention provides a total synthesis of known intermediates useful in the synthesis of khellin and antiatherosclerotic analogs thereof from pyrogallol. Pyrogallol is converted to 3,6,7-benzofurantriol triacetate using zinc chloride and chloracetanitrile, then catalytically reduced and deactoxylated at the 3 position to yield the corresponding 2,3-dihydrofuran. This substance is subjected to a Fries rearrangement to the corresponding diol, the phenolic hydroxyl group of which is then selectively alkylated. This yields 6-hydroxy-7-alkoxy-5-benzofuranyl methyl ketone, a known intermediate for the production of 4-desmethoxy khellin and analogs thereof. This compound is then selectively alkoxylated at the 4 position using lead tetraacetate or thallium (III) nitrate in an alkanol solvent to yield known chemical intermediates in the preparation of khellin and analogs thereof.
专利号:EP-0443532-B1 优先权日:1990-02-20 标题:Temporary minimal protection synthesis of LH-RH analogs 发明人:NESTOR JOHN J JR; MCCLURE NATALIE L 权利人:SYNTEX INC 摘要:A solid phase synthesis of LH-RH analogs in which the amino acids serine and histidine, if present, are side chain protected during the synthesis with groups labile to selected alpha -amino or deprotecting agents.
专利号:US-7678877-B2 优先权日:2004-12-03 标题 :Process for the synthesis of polyalkylphenol antioxidants 发明人:YANG SUIZHOU; CHOLLI ASHOK L 权利人:POLNOX CORP 摘要:Disclosed is a method for the synthesis of sterically hindered polymeric antioxidants based on phenol type antioxidant monomers. The method includes partially etherifying, polymerizing and thermally rearranging a phenol containing monomer represented by the following structural formula: n nto produce a sterically hindered polymeric macromolecular antioxidant. X, R 10 and q are as defined herein. The disclosed method is a simple, direct and economical process for the synthesis of sterically hindered polymeric macromolecular antioxidants.
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