专利号:US-7652164-B2 优先权日:2005-09-13 标题:Process for the direct synthesis of trialkoxysilane 发明人:LEWIS KENRICK M; MEREIGH ABELLARD T; O'YOUNG CHI-LIN; CAMERON RUDOLPH A 权利人:MOMENTIVE PERFORMANCE MAT INC 摘要:The Direct Synthesis of trialkoxysilane is carried out by conducting the Direct Synthesis reaction of silicon and alcohol, optionally in solvent, in the presence of a catalytically effective amount of Direct Synthesis catalyst and an effective catalyst-promoting amount of Direct Synthesis catalyst promoter, said promoter being an organic or inorganic compound possessing at least one phosphorus-oxygen bond.
专利号:US-7429672-B2 优先权日:2006-06-09 标题 :Process for the direct synthesis of trialkoxysilane 发明人:LEWIS KENRICK M; CAMERON RUDOLPH A; RITSCHER LEGAL REPRESENTATIVE KAREN 权利人:MOMENTIVE PERFORMANCE MAT INC 摘要:This invention discloses a process to improve reaction stability in the Direct Synthesis of trialkoxysilanes. The process is particularly effective in the Direct Synthesis of triethoxysilane and its higher alkyl cognates providing improved triethoxysilane yields.
专利号:US-4284582-A 优先权日:1978-04-28 标 题 :Process for the preparation of cyclopropane derivatives, intermediates in the synthesis of pyrethroid insecticides 发明人:KAYE ALBERT E; TUCKER ALAN C 权利人:ICI LTD 摘要:Compounds of formula: wherein both groups X are chlorine, bromine or trifluoromethyl, or one X is chlorine or bromine and the other is trifluoromethyl, and Y is -CN or -COOR in which R is an alkyl group, are obtained by (A) reacting a compound of the formula: wherein X1 is chlorine or bromine, with a compound of the formula: X2C=CH-CH=C(CH3)2 in the presence of metallic copper or at least one copper salt and a base, or (B) reacting a compound of the formula: Y-CH2-CN with a compound of the formula: X2C=CH-CH=C(CH3)2 and chlorine or bromine, in the presence of at least one reducible copper salt and a base, or (C) reacting a compound of formula: X-CH2-CN with a compound of the formula: wherein X1 is chlorine or bromine, in the presence of at least one copper salt. The compounds are intermediates in the synthesis of pyrethroid insecticides.
专利号:US-4806516-A 优先权日:1986-07-24 标题 :Process for producing fluidized catalyst for synthesis of methanol 发明人:OSUGI MINORU; NAKAMURA TADASI; OBATA YORIKO 权利人:MITSUBISHI GAS CHEMICAL CO 摘要:A process for producing a fluidized catalyst for synthesis of methanol, which comprises molding a composition comprising n (A) 10 to 55% by weight of a mixture composed of water-insoluble copper, zinc and zirconium compounds convertible respectively to copper, zinc and zirconium oxides under calcination conditions, said mixture optionally containing a boron compound, n (B) 45 to 90% by weight of water, and n (C) 0.01 to 1% by weight of ammonia into fine particles, and calcining the fine particles.
专利号:US-4107089-A 优先权日:1977-03-14 标 题 :Catalyst for the synthesis of methanol and method for preparing same 发明人:BONDAR PETR GRIGORIEVICH; GOROSHKO OLEG NIKOLAEVICH; SUSCHAYA LARISA EMMANUILOVNA; LAVROVA VALENTINA VASILIEVNA; LELEKA VALENTINA EMMANUILOVNA; ILKO EDUARD GRIGORIEVICH 权利人:BONDAR PETR GRIGORIEVICH; GOROSHKO OLEG NIKOLAEVICH; SUSCHAYA LARISA EMMANUILOVNA; LAVROVA VALENTINA VASILIEVNA; LELEKA VALENTINA EMMANUILOVNA; ILKO EDUARD GRIGORIEVICH 摘要:A catalyst for the synthesis of methanol which contains an oxide of one or more metals of Group VI, chromium subgroup, of the periodic system, copper oxide, zinc oxide and an oxide of one or more hardly reducible metals of Group II-III of the periodic system.
专利号:US-7411080-B2 优先权日:2006-05-19 标题 :Direct synthesis of copper carbonate 发明人:ZHAO GANG 权利人:PHIBRO TECH INC 摘要:A basic copper salt selected from basic copper carbonate, basic copper sulfate, basic copper acetate, basic copper citrate, and basic copper nitrate is manufactured by contacting copper metal with an aqueous solution having ammonia; an acid selected from carbonic acid, sulfuric acid, acetic acid, nitric acid, or citric acid; and oxygen, under conditions where the copper metal is converted to the basic copper salt; and then recovering the basic copper salt. The most economical embodiment is where the ammonia is present in the aqueous solution is in an amount between about 6.7 g/l and about 15 g/l calculated as NH 3 , and the pH of the composition is between 8 and 10, and the temperature of the composition is between 25° C. and 100° C. The method is particularly useful if the basic copper salt is basic copper carbonate. The basic copper carbonate produced has the formula: (CuCO 3 ) x (Cu(OH 2 ) y , where y is 1 and x is between 0.1 to less than 1; or where y is 1 and x is 1, or where y is 1 and x is between 0.5 to less than about 0.95, or where y is 1 and x greater than 1.