CAS: 3012-37-1; Benzyl Thiocyanate

上下游产品

CAS号333-20-0 硫氰酸钾 | CAS号100-39-0 溴化苄 | CAS号540-72-7 硫氰酸钠 | CAS号100-44-7 氯化苄 | CAS号1024-41-5 benzyl 4-methyl... | CAS号100-51-6 苯甲醇 | CAS号14642-79-6 苄氧基三甲基硅烷 | CAS号53172-91-1 tert-butyl-dime... | CAS号36289-36-8 1-氰基咪唑 | CAS号351-60-0 苄基三氟甲基硫醚 | CAS号7677-24-9 三甲基氰硅烷 | CAS号43020-38-8 2,3,4-三甲氧基苯甲腈 | CAS号55-21-0 苯甲酰胺 | CAS号21722-85-0 苯稻瘟净 | CAS号1885-38-7 肉桂腈 | CAS号623-03-0 对氯苯腈 | CAS号140-11-4 乙酸苄酯 | CAS号150-60-7 二苄基二硫

氯化苄置于sodium Thiocyanide体系中,用 水 作为反应溶剂,化学反应 0.83H,以95.5%的收率获得产物硫氰酸苄酯
参考文献:离子液体刷作为水上亲核取代的高效和可重复使用的催化剂
标题:离子液体刷作为水上亲核取代的高效和可重复使用的催化剂
摘要:已经开发了一种非常有效且可重复使用的催化剂,用于卤代烷和甲苯磺酸盐与叠氮化物或硫氰酸盐的水上亲核取代,收率非常好.反应过程平稳,干净,无需任何有机助溶剂或其他加成物,刷子可重复使用至少 10 次,催化活性没有明显损失.产品和催化剂分离的高效率,简单性,出色的可回收性和无有机溶剂条件显示了该催化剂在实验室和工业中的应用前景.
DOI:10.1002/ejoc.201001227

专利信息

专利号:US-11718584-B2
优先权日:2019-02-22
标题 :Process for the synthesis anthranilic diamide compounds and intermediates thereof
发明人：KARRI PHANEENDRASAI; PABBA JAGADISH; SHINDE BHARAT UTTAMRAO; KALWAGHE AMOL DNYANESHWAR; MADHAVRAO KAMBLE MARUTI; KLAUSENER ALEXANDER G M; PANMAND DEEPAK SHANKAR
权利人:PI INDUSTRIES LTD
摘要:The present invention disclosed a process for the synthesis of anthranilic diamide compound of formula (I), n n n n n n n n n n wherein, R 1 , R 2 , R 3a , R 3b , R 3c , R 4 , R 5 , R 6 and Z are as defined in the detailed description. The process comprising the step of obtaining a mono- or dicyano substituted aniline compound of formula (IV) which is then converted to an anthranilic acid compound of formula (V) or an anthranilic amide compound of formula (Va). Further, the compound of formula (VI) can be optionally synthesized from compound of formula (IV or V or Va)

专利号:US-4857645-A
优先权日:1986-11-06
标 题:Process for introducing a thiocarboxylic ester group at the orthoposition of phenols or phenylamines
发明人：MAKOTO ADACHI; MATSUMURA HIROMU; SUGASAWA TSUTOMU
权利人:SHIONOGI & CO
摘要:A process for introducing thiocarboxylic ester at ortho-position of phenols or phenylamines which comprises reacting a phenyl compound having group or optionally substituted amino or cyclic amino group, of which at least one ortho-position is vacant, with C 1 -C 5 alkyl thiocyanate, C 7 -C 13 aralkyl thiocyanate or C 6 -C 12 aryl thiocyanate in the presence of a boron trihalide and hydrolyzing the resultant product under acidic conditions is provided, and said process is useful in the synthesis of medicinals, pesticides and dyes.

专利号:US-6770776-B2
优先权日:1995-02-28
标 题 :Synthesis of fluorocarbon compounds
发明人：JANIN ROBERT; SAINT-JALMES LAURENT
权利人:RHONE POULENC CHIMIE
摘要:Fluorocarbon compounds are synthesized by reacting a substrate hydrocarbyl compound containing at least one sp 3 -hybridized halophoric carbon atom bearing at least two halogen atom substituents, at least one of which is a halogen atom having an atomic number greater than that of fluorine and the at least one halophoric carbon atom being bonded to at least one chalcogen, with at least one reactant which comprises a complex of a Bronstedt base with a defined amount n of hydrofluoric acid, n being at least 3 and not greater than 20.

专利号:US-5629394-A
优先权日:1992-12-17
标 题 :Direct synthesis by living cationic polymerization of nitrogen-containing polymers
发明人：CHERADAME HERVE M; CHEN FRANK J; STANAT JON E R; NGUYEN HUNG A; TABAR BEHROOZ R
权利人:EXXON CHEMICAL PATENTS INC
摘要:A method is provided for the direct synthesis by living cationic polymerization of novel polymeric materials functionalized with desirable nitrogen-containing functional groups such as terminal azido, cyano, carbonylamino, cyanato, thiocyanato or thiocarbonylamino groups. Polymerization and functionalization occur in a substantially simultaneous manner. All necessary reactants for the functionalization are present when polymerization is initiated. The nitrogen-containing functional group is provided as a part of a molecule having a release moiety which is preferably resonance stabilized or a tertiary alkyl type and which acts to aid the nitrogen-containing species in functioning as a leaving group.

专利号:US-2002038061-A1
优先权日:1995-02-28
标题 :Synthesis of fluorocarbon compounds

专利号:US-6316636-B1
优先权日:1995-02-28
标题 :Synthesis of fluorocarbon compounds