CAS: 6095-42-7; Trihexyl Phosphite

上下游产品

triethyl phosphite hexan-1-ol diethyl diethylphosphoramidite benzoic phosphorous trianhydride2-Dihexylphosphono-hexansaeure-hexylester 2-(bis-hexyloxy-phosphoryl)-°Ctanoic acid butyl ester Dihexyl methylphosphonate [1-(Benzo[1,3,2]dioxaphosphol-2-yloxy)-cyclohexyl]-phosphonic acid dihexyl ester

正己醇置于n,N-二乙基苯胺,三氯氧磷体系中,化学反应生成 亚磷酸三正己酯
参考文献:物理性质和化学组成.第xlix部分.某些有机磷化合物的折射率,密度和表面张力
标题:物理性质和化学组成.第xlix部分.某些有机磷化合物的折射率,密度和表面张力
摘要:亚磷酸三正烷基酯,正膦酸二正烷基酯,正烷基膦酸二正丙基酯,正磷酸三正烷基酯(丁基至庚基)的正膦酸二正烷基酯(甲基至辛基),亚磷酸三-2-正烷氧基乙基酯(甲氧基-己氧基),亚磷酸二-2-正烷氧基乙基酯(甲氧基-庚氧基-)和2-正烷氧基-4-甲基-1,3,2已经制备了-二氧杂膦酸酯(甲氧基-至己氧基-),并确定了它们在20°的折射率以及在一定温度范围内的密度和表面张力:详细测量了许多代表性化合物的红外光谱.键(p O),(p-o),(p-c),(p-h)和1,3,2-二氧杂膦环的抛物线,折射和分子折射系数已通过新的实验数据.
DOI:10.1039/j19660000249

专利信息

专利号:US-3644539-A
优先权日:1969-07-28
标题 :Synthesis of hindered alkenyl phenols
发明人：STARNES WILLIAM H JR
权利人:EXXON RESEARCH ENGINEERING CO
摘要:THE HINDERED ALKENYL PHENOLS HAVING THE FOLLOWING STRUCTURE ARE USEFUL AS ANTIOXIDANTS FOR HYDROCARBONS AND ESPECIALLY FOR POLYOLEFINS SUCH AS POLYPROPYLENE AND ARE PRODUCED BY THE REACTION OF A 2,6-DIALKYLQUINONE METHIDE WITH AN ALDEHYDE AND A PHOSPHORUS COMPOUND SELECTED FROM THE GROUP CONSISTING OF A TRIALKYLPHOSPHINE AND A TRIALKYLPHOSPHITE TO PRODUCE THE HINDERED ALKENYL PHENOL HAVING THE FOLLOWING STRUCTURE: 2-R1,4-(R3-CH=CH-),6-R2-PHENOL WHERE R1 AND R2 ARE ALKYLS HAVING 1 TO 8 CARBON ATOMS, AND R3 IS SELECTED FROM THE GROUP CONSISTING O ALKYL AND ARYL.

专利号:US-5278301-A
优先权日:1990-03-23
标 题:Route to glycals in the allal and gulal series
发明人：HALCOMB RANDALL L; DANISHEFSKY SAMUEL J; WITTMAN MARK D
权利人:UNIV YALE
摘要:Axial anomeric sulfoxides generated via thiophenol Ferrier rearrangement of glucal and galactal derivatives are used to synthesize glycals of the gulal and allal series. An application of the method led to the synthesis of the esperamicin thiosugar.