CAS: 97600-39-0; Tetraethyl 2,2',2'',2'''-((15,35,55,75-Tetra-Tert-Butyl-1,3,5,7(1,3)-Tetrabenzenacyclooctaphane-12,32,52,72-Tetrayl)Tetrakis(Oxy))Tetraacetate

• 英文名称Tetraethyl 2,2',2'',2'''-((15,35,55,75-Tetra-Tert-Butyl-1,3,5,7(1,3)-Tetrabenzenacyclooctaphane-12,32,52,72-Tetrayl)Tetrakis(Oxy))Tetraacetate
• 中文名称叔丁基杯[4]芳基四乙酸四乙酯
• IUPAC名称tetraethyl 2,2',2'',2'''-((15,35,55,75-tetra-tert-butyl-1,3,5,7(1,3)-tetrabenzenacyclooctaphane-12,32,52,72-tetrayl)tetrakis(oxy))tetraacetate
• 其它别名Sodium Ionophore X, Selectophore(Tm), Function Tested; 4-Tert-Butylcalix[4]Arene-O,O',O'',O'''-Tetraacetic Acid Tetraethyl Ester; 5,11,17,23-P-Tert.Butyl-25,26,27,28-Tetrakis-[(Ethoxycarbonyl)Methoxy]-Calix[4]Arene; Ethyl 2-[[5,11,17,23-
• CAS编号97600-39-0
• MFCD编号:MFCD00145373
• EINECS号:619-280-6
• 分子式:C60H80O12
• 分子量:993.29
• 产品CID: 2507880
• 产品分类有机原料→材料科学→超分子材料→杯芳烃

• 相似结构搜索
• InChIKey: HZHADWCIBZZJNV-UHFFFAOYSA-N
• HZHADWCIBZZJNV-UHFFFAOYSA-N…
• 计算化学: 氢键受体数12.0氢键供体数0可旋转键数16

相似化合物

物理性质

• 熔点155-158 °C
• 沸点788.39 °C at 760 mmHg
• 闪点339.7±34.3 °C
• 密度1.1±0.1 g/cm3
• PSA:142.12
• LogP:11.3208
• 折射率1.529
• 蒸汽压0.0±0.3 mmHg at 25°C
• 敏感性遵照规定使用和储存则不会分解。
• 外观形态白色至几乎白色粉末至晶体
• 储存条件密闭于阴凉干燥环境环境中
• 产品应用该化合物用于对汗中的钠和钾进行电化学监测的皮肤微氟化分光测量装置.

MSDS等安全信息

• GHS符号GHS07
• 警示词Warning
• 危险描述H302-H315-H319-H335
• 防范说明P261-P264-P270-P271-P280-P302+P352-P304+P340-P330-P362+P364-P405-P501
• UN编号NONH for all modes of transport
• 安全声明22-24/25
• WGK Germany3

上下游产品

合成工艺路线路线简述

• 60705-62-6 + 105-36-2 = 97600-39-0
  反应条件:1.1 Reagents: Potassium Carbonate Solvents: Acetone
  标题:Synthesis,X-Ray Crystal Structures,And Cation-Binding Properties Of Alkyl Calixaryl Esters And Ketones,A New Family Of Macrocyclic Molecular Receptors
  作者:Arnaud-Neu,Francoise; Collins,Elizabeth M.; Deasy,Mary; Ferguson,George; Harris,Stephen J.; Et Al
  参考文献:Journal Of The American Chemical Society 日期:1989 卷标:111(23) 页码:8681-91]
  
  105-39-5 + 60705-62-6 = 97600-39-0
  反应条件:1.1 Catalysts: Potassium Carbonate,Potassium Iodide Solvents: Acetone; 0.5 H,Reflux1.2 4 D,Reflux
  标题:Improved Method Of Synthesis For Calixarene Ester Derivatives
  作者:Ge,Yun; Cal,Ya-Hua; Yan,Chao-Guo
  参考文献:Huaxue Shiji 日期:2005 卷标:27(2) 页码:111-112]
  
  105-39-5 + 60705-62-6 = 97600-39-0
  反应条件:1.1 Reagents: Potassium Carbonate,Potassium Iodide Solvents: Acetone1.2 Reagents: Thiosulfuric Acid (H2S35So3),Sodium Salt (1:2) Solvents: Water1.3 Solvents: Dichloromethane
  标题:A Convenient Approach Of Preparation Of Calix[4]Arenes Bearing Ester Pendants
  作者:Hu,Xu-Bo; Han,Xin-Xin; He,Jia-Qi; Huang,Hai; Cheng,Jin-Pei
  参考文献:Hecheng Huaxue 日期:2000 卷标:8(2) 页码:151-154]
  
  60705-62-6 + 105-36-2 = 97600-39-0
  反应条件:1.1 Reagents: Potassium Iodide Solvents: Acetonitrile; 1 H,Reflux1.2 10 H,Reflux
  标题:The Synthesis Of P-Tert-Butylcalix[4]Arene Derivative Of Pyridinethiol
  作者:Kong,Xiao-Wei; Jiang,Zhong-Liang; Li,Qian-Kun
  参考文献:Jingxi Yu Zhuanyong Huaxuepin 日期:2011 卷标:19(10) 页码:16-18]
  
  60705-62-6 + 105-36-2 = 97600-39-0
  反应条件:1.1 Reagents: Sodium Carbonate Solvents: Acetone; Reflux
  标题:Novel Anion Receptors Based On Thiacalix[4]Arene Derivatives
  作者:Zlatuskova,Petra; Stibor,Ivan; Tkadlecova,Marcela; Lhotak,Pavel
  参考文献:Tetrahedron 日期:2004 卷标:60(50) 页码:11383-11390]
  
  60705-62-6 + 105-36-2 = 97600-39-0
  反应条件:1.1 Reagents: Potassium Carbonate Solvents: Acetone; 5 D,Reflux
  标题:Solvent-Tunable Binding Of Hydrophilic And Hydrophobic Guests By Amphiphilic Molecular Baskets
  作者:Zhao,Yan; Ryu,Eui-Hyun
  参考文献:Journal Of Organic Chemistry 日期:2005 卷标:70(19) 页码:7585-7591]
  
  60705-62-6 + 105-36-2 = 97600-39-0
  反应条件:1.1 Reagents: Potassium Carbonate Solvents: Acetone; Rt -> Reflux; 5 D,Reflux
  标题:Efficient Synthesis Of Water-Soluble Calixarenes Using Click Chemistry
  作者:Ryu,Eui-Hyun; Zhao,Yan
  参考文献:Organic Letters 日期:2005 卷标:7(6) 页码:1035-1037]
  
  60705-62-6 + 105-36-2 = 97600-39-0
  反应条件:1.1 Reagents: Sodium Carbonate,Sodium Iodide Solvents: Acetone
  标题:Selective Extraction Of Ga(Iii) With P-T-Butylcalix[4]Arene Tetrahydroxamic Acid
  作者:Chetry,Anup Basnet; Adhikari,Birendra Babu; Morisada,Shintaro; Kawakita,Hidetaka; Ohto,Keisuke
  参考文献:Solvent Extraction Research And Development 日期:2015 卷标:(2015) 页码:25-35]
  
  60705-62-6 + 105-36-2 = 97600-39-0
  反应条件:1.1 Reagents: Sodium Hydride Solvents: Tetrahydrofuran; 1.5 H,67 °C
  标题:Electrografting Of Calix[4]Arenediazonium Salts To Form Versatile Robust Platforms For Spatially Controlled Surface Functionalization
  作者:Mattiuzzi,Alice; Jabin,Ivan; Mangeney,Claire; Roux,Clement; Reinaud,Olivia; Et Al
  参考文献:Nature Communications 日期:2012]
  
  60705-62-6 + 105-36-2 = 97600-39-0
  反应条件:1.1 Reagents: Potassium Carbonate Solvents: Acetone; 22 H,Reflux
  标题:Low-Generation Dendrimers With A Calixarene Core And Based On A Chiral C2-Symmetric Pyrrolidine As Imino Sugar Mimics
  作者:Marradi,Marco; Cicchi,Stefano; Sansone,Francesco; Casnati,Alessandro; Goti,Andrea
  参考文献:Beilstein Journal Of Organic Chemistry 日期:2012 卷标:8 页码:951-957]
  
  105-39-5 + 60705-62-6 + 105-36-2 = 97600-39-0
  反应条件:1.1 Reagents: Sodium Hydride Solvents: Tetrahydrofuran; Rt; Rt; Rt -> 60 °C; 5 - 6 H,60 °C
  标题:Preparation Of Calixarene Derivatives Having Ethoxycarbonylmethoxy Group
  参考文献:Japan]
  
  60705-62-6 + 105-36-2 = 97600-39-0
  反应条件:1.1 Reagents: Potassium Carbonate Solvents: Acetonitrile; 1 H,Rt1.2 16 H,Rt
  标题:N-Alkyl Calix[4]Azacrowns For The Selective Extraction Of Uranium
  作者:Wehbie,Moheddine; Arrachart,Guilhem; Le Goff,Xavier F.; Karame,Iyad; Pellet-Rostaing,Stephane
  参考文献:Dalton Transactions 日期:2018 卷标:47(41) 页码:14594-14603]
  
  105-39-5 + 60705-62-6 = 97600-39-0
  反应条件:1.1 Catalysts: Potassium Iodide Solvents: Acetonitrile; 1 H,Reflux1.2 12 H,Reflux
  标题:The Synthesis Of P-Tert-Butylcalix[4]Arene Derivative Of Pyridinethiol
  作者:Jiang,Zhong-Liang; Chen,Mu; Liu,Ming; Jin,Guo-Hua
  参考文献:Huaxue Shiji 日期:2007 卷标:29(12) 页码:716-718]
  
  60705-62-6 + 105-36-2 = 97600-39-0
  反应条件:1.1 Reagents: Potassium Carbonate; 1 H,Reflux1.2 24 H,Reflux
  标题:Preparation Of Calixarene-Based Peptide Conformation Mimetics And Their Biological Activity
  参考文献:World Intellectual Property Organization]
  
  105-39-5 + 60705-62-6 = 97600-39-0
  反应条件:1.1 Reagents: Potassium Carbonate,Potassium Iodide Solvents: Acetone; Rt; 24 H,Reflux; 7 D,Reflux
  标题:Preparation And Investigation Of Temperature-Responsive Calix[4]Arene-Based Molecular Gels
  作者:Cai,Xiuqin; Xu,Yunhua; Yang,Rong; Yang,Hui
  参考文献:Rsc Advances 日期:2017 卷标:7(45) 页码:28476-28482]
  
  105-39-5 + 60705-62-6 = 97600-39-0
  反应条件:1.1 Reagents: Potassium Fluoride Solvents: Acetonitrile; 1 H,Reflux1.2 12 H,Reflux
  标题:Synthesis Of Sulfur Containing Calix[4]Arene Derivatives
  作者:Jiang,Zhong-Liang; Zhang,Li
  参考文献:Jingxi Yu Zhuanyong Huaxuepin 日期:2009 卷标:17(19) 页码:23-24]
  
  60705-62-6 + 105-36-2 = 97600-39-0
  反应条件:1.1 Reagents: Sodium Hydride Solvents: Tetrahydrofuran; 90 Min,67 °C
  标题:Materials Graft-Coated With Amino-Functionalized Calixarenes Directly Anchored To The Surface Of The Material
  参考文献:World Intellectual Property Organization]
  
  60705-62-6 + 105-36-2 = 97600-39-0
  反应条件:1.1 Reagents: Potassium Carbonate,Potassium Iodide Solvents: Acetone; 20 H,570 °C
  标题:Luminescent Behavior Of Pyrene-Allied Calix[4]Arene For The Highly Ph-Selective Recognition And Determination Of Zn2+,Hg2+ And I-Via The Chef-Pet Mechanism: Computational Experiment And Paper-Based Device
  作者:Sutariya,Pinkesh G.; Soni,Heni; Gandhi,Sahaj A.; Pandya,Alok
  参考文献:New Journal Of Chemistry 日期:2019 卷标:43(25) 页码:9855-9864]
  
  121702-02-1 + 105-36-2 = 97600-39-0
  反应条件:1.1 Reagents: Potassium Carbonate Catalysts: Potassium Iodide Solvents: Acetone; 20 H,57 °C
  标题:Design,Synthesis And Characterization Of Quinoline-Pyrimidine Linked Calix[4]Arene Scaffolds As Anti-Malarial Agents
  作者:Shah,Rahul B.; Valand,Nikunj N.; Sutariya,Pinkesh G.; Menon,Shobhana K.
  参考文献:Journal Of Inclusion Phenomena And Macrocyclic Chemistry 日期:2016 卷标:84(1-2) 页码:173-178]
  
  60705-62-6 + 105-36-2 = 97600-39-0
  反应条件:1.1 Reagents: Potassium Carbonate Solvents: Acetone
  标题:Calix[4]Arenes With Narrow Rim 2-Mercaptoethoxy Substituents As Potential Precursor Molecules For Metallacages And Sensors
  作者:Knoblauch,Stephan; Falana,O. Matthew; Nam,Jaewook; Roundhill,D. Max; Hennig,Horst; Et Al
  参考文献:Inorganica Chimica Acta 日期:2000 页码:300-302

专利信息

其他信息查阅

• ➥ 象形图和危险代码
• ➥ 防范代码详解
• ➥ 危险代码说明
• ➥ Globally Harmonized System
• ➥ REACH监管