CAS: 76155-79-8; (R)-1-(4-(Trifluoromethyl)Phenyl)Ethanol

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4-Trifluoromethylbenzaldehyde dimethyl zinc(II) 1-(4-trifluoromethylphenyl)ethanone 1-trifluoromethyl-4-vinyl-benzene [(1R)-1-[4-(trifluoromethyl)phenyl]ethyl] methanesulfonate triethyl (2S)-2-[4-(trifluoromethyl)phenyl]propane-1,1,1-tricarboxylate (S)-2-Methyl-1-[(S)-1-(4-trifluoromethyl-phenyl)-ethyl]-piperazine (S)-3-Methyl-4-[(R)-1-(4-trifluoromethyl-phenyl)-ethyl]-piperazine-1-carboxylic acid tert-butyl ester

(R)-1-(4-Trifluoromethylphenyl)Ethyl Acetate置于lithium Aluminium Tetrahydride体系中,用 乙醚 作为反应溶剂,化学反应 6.0H,反应生成 (R)-1-(4-三氟甲基苯基)乙醇
参考文献:Enantioselective Acylation Of Primary And Secondary Alcohols Catalyzed By Lipase Ql From Alcaligenes Sp.: A Predictive Active Site Model For Lipase Ql To Identify Which Enantiomer Of An Alcohol Reacts Faster In This Acylation
标题:Enantioselective Acylation Of Primary And Secondary Alcohols Catalyzed By Lipase Ql From Alcaligenes Sp.: A Predictive Active Site Model For Lipase Ql To Identify Which Enantiomer Of An Alcohol Reacts Faster In This Acylation
摘要:Lipase Ql (From Alcaligenes Sp.)-Catalyzed Acylation Of Alcohols Using Isopropenyl Acetate As The Acylating Agent In Diisopropyl Ether Converted Preferentially Primary Alcohols With An S Configuration And Secondary Alcohols With An R Configuration Into The Corresponding Homochiral Acetates. On The Basis Of Observed Enantiomer Selectivities,A Predictive Active Site Model For Lipase Ql Is Proposed For Identifying Which Enantiomer Of A Primary Or A Secondary Alcohol Reacts Faster In This Acylation. Copyright (C) 1996 Published By Elsevier Science Ltd
DOI:10.1016/0957-4166(96)00429-6