对苯二甲酸置于mil-88A,双氧水体系中,用 水 作为反应溶剂,化学反应 0.17H,反应生成 2-羟基对苯二甲酸 参考文献:Metal-organic Frameworks Mil-88A Hexagonal Microrods As A New Photocatalyst For Efficient Decolorization Of Methylene Blue Dye 标题:Metal-organic Frameworks Mil-88A Hexagonal Microrods As A New Photocatalyst For Efficient Decolorization Of Methylene Blue Dye 摘要:金属有机框架mil-88A展示出活性mb染料降解性能. DOI:10.1039/c3Dt52574K
专利号:US-2022297083-A1 优先权日:2019-08-27 标 题 :Continuous Synthesis Of Porous Coordination Polymers In Supercritical Carbon Dioxide 发明人:RASMUSSEN ELIZABETH G; KRAMLICH JOHN C; NOVOSSELOV IGOR V 权利人:UNIV WASHINGTON 摘要:This disclosure relates generally relates to methods and systems useful for continuous synthesis of materials in super-critical carbon dioxide (sCO 2 ). More particularly, this disclosure relates to methods and systems useful for continuous synthesis of coordination polymers, such as metal-organic frameworks (MOFs) and/or covalent organic frameworks (COFs), in sCO 2 .
专利号:US-2014364795-A1 优先权日:2011-12-19 标题 :Synthesis of upconversion nanocomposites for photodynamic therapy 发明人:TAN THATT YANG TIMOTHY; XU QING-CHI 权利人:UNIV NANYANG TECH 摘要:The present invention refers to a composite material including at least one upconversion particulate material that under near infrared (NIR) irradiation emits visible light of a wavelength between 380 and 740 nm, and at least one semiconductor particulate material that can absorb the visible light emitted by the at least one upconversion particulate material and upon absorbance generates reactive species, wherein the at least one upconversion particulate material and the at least one semiconductor particulate material are physiologically acceptable. The upconversion particulate material can comprises NaYF4 doped with a one rare earth metal. The bright fluorescence emitted from rare earth-doped NaYF4 upconversion particles is in the visible region of the electromagnetic spectrum and may be absorbed by a biocompatible photocatalysts such as TiO 2 to produce reactive species. This allows the composite to be used for in vivo applications.
专利号:US-12371444-B2 优先权日:2018-07-19 标 题:Methods of making MOFs, systems for synthesizing MOFs, and methods of coating textiles with MOFs 发明人:GIRI GAURAV; HUELSENBECK LUKE 权利人:UNIV VIRGINIA PATENT FOUNDATION 摘要:A method of synthesis of metal organic frameworks (“MOFsâ€?) includes preparing a metal solution by dissolving at least one metal salt in an aqueous solution and buffering the metal solution with a base to achieve a first pH, the metal solution optionally comprising an organic co-solvent, preparing a linker solution by adding at least one organic acid linker and at least one base to an aqueous solution, and mixing the metal solution and the linker solution to produce the MOFs. The at least one organic acid linker has an ability to be protonated or deprotonated in response to a second pH, and the mixture of the metal solution and the linker solution has a third pH value, where the third pH value is greater than a highest pKa of the organic acid linker. The MOFs may be applied to a textile.
专利号:US-2022333011-A1 优先权日:2019-08-29 标 题:Process for preparing multicolor, fluorescent carbon quantum dot nanoparticles from coal under mild oxidation conditions 发明人:Tian Hanjing; DAI SHENG; HU JIANLI 权利人:WEST VIRGINIA UNIV BOARD OF GOVERNORS ON BEHALF OF WEST VIRGINIA UNIV; GEORGIA TECH RES INST 摘要:In one aspect, the disclosure relates to multicolored carbon quantum dot nanoparticles (Cdots), “one-potâ€? methods of making same starting from coal and using mild reaction conditions, and applications of the same. The disclosed methods are safe and environmentally benign as well as inexpensive. Additionally, the disclosed carbon quantum dot nanoparticles are stable and have tunable properties based on reaction conditions used for their synthesis.
专利号:US-7585999-B2 优先权日:2006-11-28 标题:Process for the synthesis of 2, 5-dihydroxyterephthalic acid 发明人:RITTER JOACHIM C 权利人:DU PONT 摘要:2,5-dihydroxyterephthalic acid is produced in high yields and high purity from 2,5-dihaloterephthalic acid by contact with a copper source and a ligand that coordinates to copper under basic conditions.
专利号:US-7335791-B1 优先权日:2006-11-28 标题 :Process for the synthesis of hydroxy aromatic acids
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合成参考文献
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