CAS: 10075-85-1; 9,10-Bis(Phenylethynyl)Anthracene

该化合物是属于多环芳烃类的有机化合物,在9和10个位置有两个苯乙烯基替代成分,具有中央炭疽芯,增强了其电子特性和溶性;该化合物的特点是其强大的荧光度,经常用于有机电子,特别是有机发光二极管(OLEDs)和各种应用中的荧光探测器;其结构有助于重要的欧元堆叠互动,可能影响其固态特性;此外,9,10-Bis(苯乙烯基)anthracene具有良好的热稳定性,适合高温应用;该化合物独特的光学和电子特征使其在材料科学和光学研究中引起兴趣;但与许多PAHs一样,它可能对环境和健康造成关切,需要实验室和工业环境中谨慎处理和评估.

结构式图片

欧盟法规

ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

CAS号523-27-3 9,10-二溴蒽 | CAS号536-74-3 苯乙炔 | CAS号14825-85-5 9,10-Anthracene... | CAS号1122-79-8 potassium pheny... | CAS号115198-11-3 10-bromo-9-(phe... | CAS号4440-01-1 苯乙酰锂 | CAS号3757-88-8 苯基乙炔三丁基锡 | CAS号6928-78-5 magnesium,ethyn... | CAS号3112-88-7 苄基苯基砜

合成工艺路线路线简述

    9,10-二溴蒽置于bis-Triphenylphosphine-Palladium(II) Chloride,Copper(L) Iodide,三乙胺体系中,用 四氢呋喃 用作溶剂,化学反应 6.0H,反应生成9,10-双苯乙炔基蒽
    参考文献:两亲性9,10-双(苯乙炔基)蒽衍生物胶体纳米粒子的单线态裂变
    标题:两亲性9,10-双(苯乙炔基)蒽衍生物胶体纳米粒子的单线态裂变
    摘要:合成了三种具有零个(Bpea),一个(Bpea-Cooh)和两个(Bpea-(Cooh) 2 )羧基的9,10-双(苯乙炔基)蒽衍生物,并在水溶液中制备成胶体纳米粒子.由于自组装过程的驱动力不同,扫描电子显微镜显示这三种纳米粒子的不同形态.稳态吸收和荧光光谱揭示了这三种纳米颗粒中相邻蒽单元之间存在强烈的分子间相互作用,以及bpea-Cooh和bpea-(Cooh) 2中的相互作用纳米颗粒比 Bpea 中的大.正如瞬态吸收实验所揭示的那样,可以在这三种纳米粒子中进行单线态裂变(sf),但效率不同.与 Bpea 纳米粒子 (122%) 相比,Bpea-Cooh (109%) 和 Bpea-(Cooh) 2 (98%) 纳米粒子的三重态产率大幅下降,这是由于 Bpea-Cooh 和 Bpea 中更吸热的 Sf 引起的-(Cooh) 2纳米粒子由于单重态能量降低.
    Doi:10.1016/j.Jphotochem.2022.113826

    专利信息


    专利号:US-12006540-B2
    优先权日:2015-09-28
    标题:Synthesis of novel disulfide linker based nucleotides as reversible terminators for DNA sequencing by synthesis
    发明人:JU JINGYUE; LI XIAOXU; CHEN XIN; LI ZENGMIN; KUMAR SHIV; SHI SHUNDI; GUO CHENG; REN JIANYI; HSIEH MIN-KANG; CHIEN MINCHEN; TAO CHUANJUAN; ERTURK ECE; KALACHIKOV SERGEY; RUSSO JAMES J
    权利人:UNIV COLUMBIA
    摘要:Disclosed herein, inter alia, are compounds, compositions, and methods of use thereof in the sequencing of a nucleic acid.

    专利号:US-6031014-A
    优先权日:1998-12-08
    标题:Initiator compositions and methods for their synthesis and use
    发明人:CRIVELLO JAMES V
    摘要:Cationic polymerization initiators of formula ##STR1## are disclosed. The acyl sulfonium salts of the present invention differ from known acyl sulfonium initiators in that the substituents R 2 and R 3 on the sulfur are larger and more complex than the lower alkyl and lower alkylene of known photoinitiators. Processes for the synthesis of the novel acyl sulfonium salts and prepolymer compositions containing them are also disclosed.

    专利号:US-2018150597-A1
    优先权日:2016-11-29
    标题 :Method for optimal design of polynucleotides sequences for analysis of specific events in any genetic region of interest
    发明人:BERTHOUMIEUX SARA; FOURNE YANNICK; KOMATSU JUN; FER FREDERIC; BENSIMON AARON
    权利人:GENOMIC VISION SA
    摘要:Methods including in-silico steps for design and synthesis of Genomic Morse Code (“GMCâ€?) probes including design of combinations of polynucleotide sequences and labelling colors for analysis of large rearrangements in targeted genetic regions as well as allele characterization of complex regions and localization of events such as replication, DNA reparation or epigenetics in particular regions. Color-encoded sets of probes that produce characteristic or unique color patterns when painted on a target nucleic acid sequence. Methods for using color-encoded sets of probes.

    专利号:US-11959137-B2
    优先权日:2015-09-28
    标题:Synthesis of novel disulfide linker based nucleotides as reversible terminators for DNA sequencing by synthesis

    专利号:US-2024376536-A1
    优先权日:2015-09-28
    标题 :Design and synthesis of novel disulfide linker based nucleotides as reversible terminators for dna sequencing by synthesis

    专利号:US-2023160000-A1
    优先权日:2015-09-28
    标 题:Synthesis of novel disulfide linker based nucleotides as reversible terminators for dna sequencing by synthesis
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    主要参考文献

    [参考文献]: Si-Hui Zhuang, Et Al. Quantum Dot-Based Luminescent Oxygen Channeling Assay For Potential Application In Homogeneous Bioassays. J Fluoresc. 2016 Jan;26(1):317-22.
    [参考文献]: Sukumaran Santhosh Babu, Et Al. Nonvolatile Liquid Anthracenes For Facile Full-Colour Luminescence Tuning At Single Blue-Light Excitation. Nat Commun. 2013:4:1969.

    合成参考文献


    摘要:Colobert, F.; Leroux, F. R., Science of Synthesis: Cross Coupling and Heck-Type Reactions, (2012) 1, 373.
    摘要:S109 | PARCEDC | List of 7074 potential endocrine disrupting compounds (EDCs) by PARC T4.2 | DOI:10.5281/zenodo.10944198
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